2012—2013年重庆雪玉洞洞穴系统碳循环特征

任坤; 沈立成; 袁道先; 王晓晓; 徐尚全

doi:10.3799/dqkx.2016.113

Volume 41 Issue 8

Aug. 2016

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Ren Kun, Shen Licheng, Yuan Daoxian, Wang Xiaoxiao, Xu Shangquan, 2016. Carbon Cycle Characteristics in Karst Cave System of Xueyu Cave from 2012 to 2013. Earth Science, 41(8): 1424-1434. doi: 10.3799/dqkx.2016.113

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Ren Kun, Shen Licheng, Yuan Daoxian, Wang Xiaoxiao, Xu Shangquan, 2016. Carbon Cycle Characteristics in Karst Cave System of Xueyu Cave from 2012 to 2013. Earth Science, 41(8): 1424-1434. doi: 10.3799/dqkx.2016.113

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Carbon Cycle Characteristics in Karst Cave System of Xueyu Cave from 2012 to 2013

doi: 10.3799/dqkx.2016.113

1.
Institute of Karst Geology, Chinese Academy of Geological Sciences, Karst Dynamics Laboratory of Ministry of Land and Resources & Guangxi, Guilin 541004, China
2.
International Research Center on Karst under the Auspices of UNESCO, Guilin 541004, China
3.
School of Geographical Sciences, Southwest University, Chongqing 400715, China
4.
Institute of Mountain Hazards and Environment, CAS, Chengdu 610041, China

Received Date: 2016-01-29
Publish Date: 2016-08-15

Abstract

Abstract

The high CO₂ concentration in Xueyue cave, Chongqing, is rare at home and abroad. However, the circulation characteristics of carbon and its controlling factors in this cave system remain unknown. P_{CO_2^-soil}, P_{CO_2^-cave}, P_{CO_2^-eq}, SIc, and δ¹³C_DIC of subterranean stream were analyzed to investigate the laws of CO₂ concentration variations in Xueyu cave and its contolling factors, as well as the impact on carbon cycle in this cave by subterranean stream. It is found that soil P_CO₂ mainly controlled by precipitation in subtropical areas was higher in rainy season than that of dry season. Cave air P_CO₂ exhibited seasonal variations, high cave air P_CO₂ typically occurred during warm periods, and low cave air P_CO₂ were typical of cold periods. It was ventilation driven by the temperature difference between cave and outside air that resulted in a sharp transition of cave air P_CO₂. Meanwhile, cave air P_CO₂ could rise to high level in a short period of time because of CO₂ degassing from subterranean stream. Due to soil CO₂ effect, groundwater became more mineralized water with low SIc and high water P_{CO_2^-eq}, and dissolution in some months in rainy season. With the reduction of soil CO₂ and precipitation, groundwater had low degree of mineralization with high SIc and low water P_{CO_2^-eq} in dry season.
- karst cave system,
- carbon cycle,
- CO₂ partial pressure,
- calcite saturation index,
- Xueyu cave,
- climate change

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References(53)

References

Amundson, R., Kelly, E., 1987.The Chemistry and Mineralogy of a CO₂-Rich Travertine Depositing Spring in the California Coast Range.Geochimica et Cosmochimica Acta, 51(11):2883-2890.doi: 10.1016/0016-7037(87)90364-4

Appelo, C.A.J., Postma, D., 2005.Geochemistry, Groundwater and Pollution.Taylor & Francis Press, London, 29-50.

Baldini, J.U.L., McDermott, F., Hoffmann, D.L., et al., 2008.Very High-Frequency and Seasonal Cave Atmosphere P_CO₂ Variability:Implications for Stalagmite Growth and Oxygen Isotope-Based Paleoclimate Records.Earth and Planetary Science Letters, 272(1):118-129.doi: 10.1016/j.epsl.2008.04.031

Boucot, A.J., Gray, J., 2001.A Critique of Phanerozoic Climatic Models Involving Changes in the CO₂ Content of the Atmosphere.Earth-Science Reviews, 56(1-4):1-159.doi: 10.1016/S0012-8252(01)00066-6

Bourges, F., Genthon, P., Mangin, A., et al., 2006.Microclimates of l'Aven d'Orgnac and other French Limestone Caves (Chauvet, Esparros, Marsoulas).International Journal Climatology, 26(12):1651-1670.doi: 10.1002/joc.1327

Cuezva, S., Fernandez-Cortes, A., Benavente, D., et al., 2011.Short-Term CO₂ (g) Exchange between a Shallow Karstic Cavity and the External Atmosphere during Summer:Role of the Surface Soil Layer.Atmospheric Environment, 45(7):1418-1427.doi: 10.1016/j.atmosenv.2010.12.023

Davidson, E.A., Janssens, I.A., 2006.Temperature Sensitivity of Soil Carbon Decomposition and Feedbacks to Climate Change.Nature, 440(7081):165-173.doi: 10.1038/nature04514

Dreybrodt, W., Scholz, D., 2011.Climatic Dependence of Stable Carbon and Oxygen Isotope Signals Recorded in Speleothems:From Soil Water to Speleothem Calcite.Geochimica et Cosmochimica Acta, 75(3):734-752.doi: 10.1016/j.gca.2010.11.002

Faimon, J., Štelcl, J., Sas, D., 2006.Anthropogenic CO₂-Flux into Cave Atmosphere and Its Environmental Impact:A Case Study in the Cíšarská Cave (Moravian Karst, Czech Republic).Science of the Total Environment, 369(1-3):231-245.doi: 10.1016/j.scitotenv.2006.04.006

Feng, W., Banner, J.L., Guilfoyle, A.L., et al., 2012.Oxygen Isotopic Fractionation between Drip Water and Speleothem Calcite:A 10-Year Monitoring Study, Central Texas, USA.Chemical Geology, 304-305(3):53-67.doi: 10.1016/j.chemgeo.2012.02.004

Ford, D., Williams, P., 2007.Karst Hydrogeology and Geomorphology.John Wiley & Sons Inc Press, New York, 103-144.

Friend, A.D., Arneth, A., Kiang, N.Y., et al., 2007.Fluxnet and Modelling the Global Carbon Cycle.Global Change Biology, 13(3):610-633.doi: 10.1111/j.1365-2486.2006.01223.x

Frisia, S., Fairchild, I.J., Fohlmeister, J., et al., 2011.Carbon Mass-Balance Modelling and Carbon Isotope Exchange Processes in Dynamic Caves.Geochimica et Cosmochimica Acta, 75(2):380-400.doi: 10.1016/j.gca.2010.10.021

Hess, J.W., White, W.B., 1993.Groundwater Geochemistry of the Carbonate Karst Aquifer, Southcentral Kentucky, USA.Applied Geochemistry, 8(2):189-204.doi: 10.1016/0883-2927(93)90034-E

Huang, Q.B., Qing, X.Q., Liu, P.Y., et al., 2015.Impact of Acid Rainto δ¹³C_DIC of Karst Groundwater and Carbon Sink in Dry Season in Guilin.China.Earth Science, 40(7):1237-1247 (in Chinese with English abstract).

Knorr.W., Prentice, I.C., House, J.I., et al., 2005.Long-Term Sensitivity of Soil Carbon Turnover to Warming.Nature, 433(7023):298-301.doi: 10.1038/nature03226

Kowalczk, A.J., Froelich, P.N., 2010.Cave Air Ventilation and CO₂ Outgassing by Radon-222 Modeling:How Fast Do Caves Breathe?Earth and Planetary Science Letters, 289(1-2):209-219.doi: 10.1016/j.epsl.2009.11.010

Liu, Z.H., Dreybrodt, D., Han, J., et al., 2005.Equilibrium Chemistry of the CaCO₃-CO₂-H₂O System and Discussions.Carsologica Sinica, 24(1):1-14 (in Chinese with English abstract). http://en.cnki.com.cn/article_en/cjfdtotal-zgyr200501001.htm

Liu, Z.H., Yuan, D.X., 2000.Features of Geochemical Variation in Typical Systems of China and Their Environment Significance.Geological Review, 46(3):324-327 (in Chinese with English abstract). http://en.cnki.com.cn/article_en/cjfdtotal-dzlp200003017.htm

Liu, Z., Dreybrodt, W., 2015.Significance of Carbon Sink Produced by H₂O-Carbonate-CO₂-Aquatic Phototroph Interaction on Land.Science Bulletin, 60(2):182-191.doi: 10.1007/s11434-014-0682-y

Liu, Z., Li, Q., Sun, H., et al., 2007.Seasonal, Diurnal and Storm-Scale Hydrochemical Variations of Typical Epikarst Springs in Subtropical Karst Areas of SW China:Soil CO₂ and Dilution Effects.Journal of Hydrology, 337(1-2):207-223.doi: 10.1016/j.jhydrol.2007.01.034

Mandić, M., Mihevc, A., Leis, A., et al., 2013.Concentration and Stable Carbon Isotopic Composition of CO₂ in Cave Air of Postojnska Jama, Slovenia.International Journal of Speleology, 42(3):279-287.doi: 10.5038/1827-806X.42.3.11

Milanolo, S., Gabrovšek, F., 2009.Analysis of Carbon Dioxide Variations in the Atmosphere of Srednja Bijambarska Cave, Bosnia and Herzegovina.Boundary-Layer Meteorology, 131(3):479-493.doi: 10.1007/s10546-009-9375-5

Perşoiu, A., Onac, B.P., Perşoiu, I., 2011.The Interplay between Air Temperature and Ice Mass Balance Changes in Scǎrişoara Ice Cave, Romania.Acta Carsologica, 40(3):445-456.doi: 10.3986/ac.v40i3.4

Peyraube, N., Lastennet, R., Denis, A., 2012.Geochemical Evolution of Groundwater in the Unsaturated Zone of a Karstic Massif, Using the P_CO₂-SIc Relationship.Journal of Hydrology, 430-431(14):13-24.doi: 10.1016/j.jhydrol.2012.01.003

Pu, J., Yuan, D, Zhao, H., et al., 2014.Hydrochemical and P_CO₂ Variations of a Cave Stream in a Subtropical Karst Area, Chongqing, SW China:Piston Effects, Dilution Effects, Soil CO₂ and Buffer Effects.Environmental Earth Sciences, 71(9):4039-4049.doi: 10.1007/s12665-013-2787-z

Schimel, D.S., 1995.Terrestrial Ecosystems and the Carbon Cycle.Global Change Biology, 1(1):77-91.doi: 10.1111/j.1365-2486.1995.tb00008.x

Sherwin, C.M., Baldini, J.U.L., 2011.Cave Air and Hydrological Controls on Prior Calcite Precipitation and Stalagmite Growth Rates:Implications for Palaeoclimate Reconstructions Using Speleothems.Geochimica et Cosmochimica Acta, 75(14):3915-3929.doi: 10.1016/j.gca.2011.04.020

Wang, A.Y., 2010.Study on Operation Regularity and Environment Information Reservation of Cave Karst Dynamic System (Dissertation).Southwest University, Chongqing, 15-17(in Chinese with English abstract).

Wang, A.Y., Pu, J.B., Shen, L.C., et al., 2010.Natural and Human Factors of CO₂ Concentration Variations in Xueyu Cave, Chongqing.Tropical Geography, 30(3):272-277 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-RDDD201003011.htm

Wang, X.X., 2014.The Character of Carbon Variation and Source of CO₂ in Xueyu Cave (Dissertation).Southwest University, Chongqing, 17-36 (in Chinese with English abstract).

Wang, X.X., Yin, J.J., Xu, S.Q., et al., 2013.The Variations of Soil CO₂ and Hydrochemistry of Epikarst Spring above Xueyu Cave.Journal of Water and Soil Conservation, 27(2):85-89 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-TRQS201302018.htm

Were, A., Serrano-Ortiz, P., Moreno de Jong, C., et al., 2010.Ventilation of Subterranean CO₂ and Eddy Covariance Incongruities over Carbonate Ecosystems.Biogeosciences, 7(3):859-867.doi: 10.5194/bg-7-859-2010

Wu, K.Y., Shen, L.C., Zhang, T., et al., 2015.Links between Host Rock, Water, and Speleothems of Xueyu Cave in Southwestern China:Lithology, Hydrochemistry, and Carbonate Geochemistry.Arabian Journal of Geosciences, 8(11):8999-9013.doi: 10.1007/s12517-015-1876-6

Xu, S.Q., Yang, P.H., Jin, J.J., et al., 2013.Research on the Sensitivity of Geochemical of Underground River in Chongqing Xueyu Cave.Environment Science, 34(1):77-83 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-HJKZ201301014.htm

Xu, S.Q., Yin, J.J., Yang, P.H., et al., 2012.Impacts of Tourism Activities on Cave Environments and Self-Purification Ability of the Cave:A Case Study of Xueyu Cave, Chongqing.Tropical Geography, 32(3):286-292 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-RDDD201203015.htm

Yuan, D.X., 1999.Progress in the Study on Karst Processes and Carbon Cycle.Advance in Earth Sciences, 14(5):425-432 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-DXJZ199905000.htm

Yuan, D.X., Cai, G.H., 1988.Karst Enviroment.Chongqing Press, Chongqing, 23-126 (in Chinese).

Zhang, C., 2011.Carbonate Rock Dissolution Rates in Different Landuses and Their Carbon Sink Effect.Chinese Science Bulletin, 56(26):2174-2180 (in Chinese). http://kns.cnki.net/KCMS/detail/detail.aspx?filename=jxtw201135005&dbname=CJFD&dbcode=CJFQ

Zhou, X.P., Lan, J.C., Zhang, X.W., et al., 2013.CO₂ Outgassing and Precipitation of Calcium Carbonate in Karst Stream:A Case Study in Baishuwan Spring in Nanchuan, Chongqing.Acta Sedimentologica Sinica, 31(6):1014-1021 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-CJXB201306008.htm

黄奇波, 覃小群, 刘朋雨, 等, 2015.酸雨对桂林枯水期岩溶地下水δ¹³C_DIC及碳汇效应的影响.地球科学, 40(7):1237-1247. http://earth-science.net/WebPage/Article.aspx?id=3114

刘再华, Dreybrodt, W., 韩军, 等, 2005.CaCO₃-CO₂-H₂O岩溶系统的平衡化学及其分析.中国岩溶, 24(1):1-14. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=zgyr200501001&dbname=CJFD&dbcode=CJFQ

刘再华, 袁道先, 2000.中国典型表层岩溶系统的地球化学动态特征及其环境意义.地质论评, 46(3): 324-327. http://www.cnki.com.cn/Article/CJFDTOTAL-DZLP200003017.htm

王翱宇, 2010. 洞穴岩溶动力系统运行规律与环境信息保存的研究(硕士学位论文). 重庆: 西南大学, 15-17. http://cdmd.cnki.com.cn/article/cdmd-10635-2010095370.htm

王翱宇, 蒲俊兵, 沈立成, 等, 2010.重庆雪玉洞CO₂浓度变化的自然与人为因素探讨.热带地理, 30(3): 272-277. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=rddd201003011&dbname=CJFD&dbcode=CJFQ

王晓晓, 2014. 雪玉洞洞穴系统碳的变化特征及洞内CO₂来源研究(硕士学位论文). 重庆: 西南大学, 17-36. http://cdmd.cnki.com.cn/Article/CDMD-10635-1014264654.htm

王晓晓, 殷建军, 徐尚全, 等, 2013.雪玉洞上覆土壤CO₂变化及对表层岩溶泉水化学特征的影响.水土保持学报, 27(2): 85-89. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=trqs201302018&dbname=CJFD&dbcode=CJFQ

徐尚全, 杨平恒, 殷建军, 等, 2013.重庆雪玉洞岩溶地下河地球化学敏感性研究.环境科学, 34(1): 77-83. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201301014.htm

徐尚全, 殷建军, 杨平恒, 等, 2012.旅游活动对洞穴环境的影响及洞穴的自净能力研究——以重庆雪玉洞为例.热带地理, 32(3): 286-292. http://www.cnki.com.cn/Article/CJFDTOTAL-RDDD201203015.htm

袁道先, 1999."岩溶作用与碳循环"研究进展.地球科学进展, 14(5): 425-432. http://www.cnki.com.cn/Article/CJFDTOTAL-SWDG200001015.htm

袁道先, 蔡桂鸿, 1988.岩溶环境学.重庆:重庆出版社, 23-126.

章程, 2011.不同土地利用下的岩溶作用强度及其碳汇效应.科学通报, 56(26): 2174-2180. http://cdmd.cnki.com.cn/Article/CDMD-10635-1012342332.htm

周小萍, 蓝家程, 张笑微, 等, 2013.岩溶溪流的脱气作用及碳酸钙沉积——以重庆市南川区柏树湾泉溪流为例.沉积学报, 31(6): 1014-1021. http://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201306008.htm

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Carbon Cycle Characteristics in Karst Cave System of Xueyu Cave from 2012 to 2013

doi: 10.3799/dqkx.2016.113

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