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    新疆天山北麓中段孔隙水水化学特征及苏打水的成因

    雷米 周金龙 梁杏 周殷竹 曾妍妍 孙英

    雷米, 周金龙, 梁杏, 周殷竹, 曾妍妍, 孙英, 2022. 新疆天山北麓中段孔隙水水化学特征及苏打水的成因. 地球科学, 47(2): 674-688. doi: 10.3799/dqkx.2021.027
    引用本文: 雷米, 周金龙, 梁杏, 周殷竹, 曾妍妍, 孙英, 2022. 新疆天山北麓中段孔隙水水化学特征及苏打水的成因. 地球科学, 47(2): 674-688. doi: 10.3799/dqkx.2021.027
    Lei Mi, Zhou Jinlong, Liang Xing, Zhou Yinzhu, Zeng Yanyan, Sun Ying, 2022. Hydrochemical Characteristics of Pore Water and Genesis of Soda Water in the Middle of the Northern Piedmont of Tianshan Mountain, Xinjiang. Earth Science, 47(2): 674-688. doi: 10.3799/dqkx.2021.027
    Citation: Lei Mi, Zhou Jinlong, Liang Xing, Zhou Yinzhu, Zeng Yanyan, Sun Ying, 2022. Hydrochemical Characteristics of Pore Water and Genesis of Soda Water in the Middle of the Northern Piedmont of Tianshan Mountain, Xinjiang. Earth Science, 47(2): 674-688. doi: 10.3799/dqkx.2021.027

    新疆天山北麓中段孔隙水水化学特征及苏打水的成因

    doi: 10.3799/dqkx.2021.027
    基金项目: 

    国家自然科学基金青年项目 42007161

    详细信息
      作者简介:

      雷米(1992-), 男, 博士研究生, 主要从事地下水水质演化与地下水超采区评价.ORCID: 0000-0003-0546-5678.E-mail: 178445085@qq.com

      通讯作者:

      周金龙, ORCID: 0000-0001-5055-0252.E-mail: zjzhoujl@163.com

    • 中图分类号: P641

    Hydrochemical Characteristics of Pore Water and Genesis of Soda Water in the Middle of the Northern Piedmont of Tianshan Mountain, Xinjiang

    • 摘要: 天山北麓中段受构造控制,水文地质条件较为复杂.研究孔隙水水化学特征及苏打水(NaHCO3型)形成机制对了解天山北麓中段地下水水文地球化学过程与地质条件之间的联系具有重要意义.基于新疆天山北麓中段平原区209组地下水水样,结合地质条件,采用半变异函数模型、绝对主成分得分多元线性回归模型(PCA/APCS-MLR)剖析了潜水和承压水中水化学类型空间分布特征、地下水化学组分源贡献率、苏打水形成的地质条件控制因素以及水文地球化学作用.结果表明:山前倾斜平原潜水、冲积平原潜水和承压水分别以Na2SO4、NaHCO3和Na2SO4型水为主,其中苏打水分别占总水样的7.18%、14.83%、6.22%.承压水中Na+、HCO3-、TDS空间自相关性较强,潜水中Na+、HCO3-、TDS空间自相关性较弱,当水中TDS < 1 000 mg/L时更有利于NaHCO3型水的形成.溶滤-富集因子(F1)、外界输入因子(F2)、原生地质因子(F3)和地质环境因子(F4)对地下水中水化学指标的平均贡献率分别为29.44%、15.99%、7.70%和6.71%.苏打水形成过程不仅受控于矿物溶滤、阳离子交换、混合作用和脱硫酸作用等多种水文地球化学作用,还受到地质环境、地质构造及水文地质条件的影响.

       

    • 图  1  研究区水文地质平面图(a);水文地质剖面图(b)(改自Wang et al., 2019

      Fig.  1.  Hydrogeological map(a); hydrogeological profiles(b) of the study area (modified from Wang et al., 2019)

      图  2  潜水(a, b, c)、承压水(d, e, f)中Na+、HCO3-、TDS及水化学类型水平分布特征(改自Mi et al., 2018

      Ⅰ. 北天山山前冲断带;Ⅱ. 中央凹陷;Ⅲ. 西部隆起;Ⅳ. 陆梁隆起;Ⅰ1. 柴窝堡盆地;Ⅰ2. 阜康断裂带;Ⅰ3. 齐古断裂带;Ⅰ4. 霍玛吐背斜带;Ⅰ5. 四棵树凹陷;Ⅱ1. 阜康凹陷;Ⅱ2. 莫南凸起;Ⅱ3. 沙湾凹陷;Ⅱ4. 白家海凸起;Ⅱ5. 东道海子凹陷;Ⅱ6. 莫索湾凸起;Ⅱ7. 莫北凸起;Ⅱ8. 盆1井西凹陷;Ⅱ9.达巴松凸起;Ⅱ10.玛湖凹陷;Ⅲ1.中拐凸起;Ⅲ2.红车断裂带;Ⅲ3.车牌子凸起;Ⅲ4.克百断裂带

      Fig.  2.  Horizontal distribution characteristics of Na+, HCO3-, TDS and hydrochemical types in unconfined groundwater (a, b, c) and confined groundwater (d, e, f)(modified from Mi et al., 2018)

      图  3  冲积平原潜水和承压水中Na+(水化学类型)、HCO3-(水化学类型)、TDS(水化学类型)

      垂向分布特征

      Fig.  3.  Vertical distribution characteristics of Na+(hydrochemical types), HCO3-(hydrochemical types), TDS(hydrochemical types)in unconfined groundwater and confined groundwater of alluvial plain

      图  4  天山北麓中段山前过渡带构造剖面

      1.第四系;2.中部上新统;3.下部上新统;4.中新统;5.古近系;6.白垩系;7.侏罗系;8.三叠系;9.二叠系;10.石炭系;11.断层; 改自漆家福等(2008)

      Fig.  4.  Structural profiles of the piedmont transition belts in the middle of the northern piedmont of Tianshan Mountain

      图  5  山前倾斜平原潜水(a)、冲积平原潜水(b)、冲积平原承压水(c)中各矿物相的饱和指数(SI)以及PCO2与TDS关系(d)

      Fig.  5.  Saturation index(SI) of mineral phases and the relationship between PCO2 and TDS(d) in piedmont inclined plain unconfined groundwater(a), alluvial plain unconfined groundwater(b) and alluvial plain confined groundwater(c)

      图  6  地下水Na+-H+-SiO2(a)、K+-H+-SiO2(b)、Ca2+-H+-SiO2(c)和Mg2+-H+-SiO2(d)矿物稳定场图

      Fig.  6.  Stability field diagram for the Na+-H+-SiO2(a), K+-H+-SiO2(b), Ca2+-H+-SiO2(c) and Mg2+-H+-SiO2(d) in groundwater

      图  7  地下水中γ(Na+-Cl-)/γ[(Ca2++Mg2+)-(HCO3-+SO42-)]以及CAI1CAI2关系

      Fig.  7.  The relationship of γ(Na+-Cl-)/γ[(Ca2++Mg2+)-(HCO3-+SO42-)], CAI1 with CAI2 in groundwater

      图  8  A-A'剖面水样点Schoeller图

      Fig.  8.  Schoeller diagram of water sample points at A-A' sections

      图  9  研究区地下水水化学组分和类型沿地下水径流方向变化过程

      Fig.  9.  The change process of groundwater chemical components and types along groundwater runoff direction in study area

      表  1  天山北麓中段地下水水化学指标统计

      Table  1.   Statistics of groundwater hydrochemical indexes in the middle of the northern piedmont of Tianshan Mountain

      水化学指标/类型 山前倾斜平原潜水(n=99) 冲积平原潜水(n=50) 冲积平原承压水(n=60)
      最大值 最小值 平均值/个数 最大值 最小值 平均值/个数 最大值 最小值 平均值/个数
      pH 8.98 6.36 7.69 9.68 7.45 8.35 9.13 6.90 8.01
      TDS 2 367.80 114.00 465.40 13 250.00 112.00 1 065.00 2 914.50 135.91 749.90
      TH 1 050.80 30.87 243.97 2 489.74 5.98 297.29 2 101.70 18.10 270.56
      K+ 6.40 0.11 2.28 5.70 0.09 1.21 4.40 0.25 1.45
      Na+ 385.90 0.87 58.07 3 549.30 12.20 252.54 802.80 2.87 153.26
      Ca2+ 316.60 7.98 68.44 378.46 1.20 60.76 565.10 4.03 66.68
      Mg2+ 86.20 0.49 17.70 418.29 0.44 35.35 167.70 1.20 25.14
      Cl- 302.00 5.50 58.96 3 742.44 3.52 243.32 1 797.30 5.50 186.76
      SO42- 1 224.80 19.70 146.92 4 780.37 7.65 362.61 1 171.90 13.06 211.47
      HCO3- 408.80 61.80 157.81 504.60 71.81 154.08 547.30 32.53 149.35
      CO32- 6.20 0.00 0.14 25.08 0.00 4.19 21.32 0.00 1.69
      SiO2 17.40 4.00 12.04 19.16 7.54 11.92 17.37 5.56 11.98
      NO3-(以N计) 18.55 ND 3.77 1.88 ND 0.52 13.70 ND 1.07
      F- 1.00 ND 0.33 10.06 ND 1.54 6.41 ND 0.97
      Na2SO4 - - 59 - - 19 - - 31
      NaHCO3 - - 15 - - 31 - - 15
      MgCl2 - - 18 - - 0 - - 13
      CaCl2 - - 7 - - 0 - - 1
      注:水化学指标中pH为无量量纲,其余为mg/L;ND表示未检出.
      下载: 导出CSV

      表  2  地下水采样情况与离子组合特征参数

      Table  2.   Groundwater sampling and ion combination characteristic parameters

      地下水类型 采样井类型 地下水温度(℃) 水井深度(m) 钠氯系数γNa/γCl 脱硫酸系数100×γSO4/γCl 变质系数(γCl-γNa)/γMg
      山前倾斜平原潜水 民用手压井、农田灌溉机井 $ \frac{24.1\sim 11.2}{16.8} $ $ \frac{330.0\sim 20.0}{130.6} $ $ \frac{8.02\sim 0.13}{1.92} $ $ \frac{536.67\sim 55.11}{211.21} $ $ \frac{8.37\sim -16.47}{-0.82} $
      冲积平原潜水 民用手压井、农田灌溉机井、敞口井 $ \frac{19.8\sim 13.0}{15.8} $ $ \frac{180.0\sim 18.0}{59.8} $ $ \frac{19.11\sim 1.03}{4.30} $ $ \frac{783.96\sim 41.90}{213.47} $ $ \frac{-0.12\sim -83.77}{-8.04} $
      冲积平原承压水 农田灌溉机井、自流井 $ \frac{25.0\sim 13.0}{17.8} $ $ \frac{360.0\sim 63.2}{167.1} $ $ \frac{6.33\sim 0.19}{2.03} $ $ \frac{611.84\sim 3.95}{150.63} $ $ \frac{2.94\sim -19.75}{-2.44} $
      注:表中数据的格式为: $ \frac{最大值\sim 最小值}{平均值} $.
      下载: 导出CSV

      表  3  地下水中Na+、HCO3-、TDS的半变异函数理论模型及参数

      Table  3.   Semi-variation theoretical model and parameters of Na+, HCO3- and TDS in groundwater

      地下水类型 化学组分 理论模型 块金值C0 基台值C0+C 块金系数C0/(C0+C)(%) 变程(km) R2 RSS
      潜水 Na+ 高斯模型 0.62 1.24 49.96 0.54 0.58 0.26
      HCO3- 线性模型 5.27e-06 6.81e-06 77.42 2.17 0.41 4.19e-12
      TDS 线性模型 0.55 0.74 73.95 2.17 0.38 0.08
      承压水 Na+ 指数模型 0.02 0.14 10.64 0.01 0.70 2.92e-03
      HCO3- 球状模型 7.95e-04 2.23e-03 35.65 0.58 0.58 6.95e-07
      TDS 线性模型 1.32e-03 1.89e-03 69.84 2.07 0.79 3.48e-07
      下载: 导出CSV

      表  4  成分矩阵及主成分贡献率

      Table  4.   Component matrix and principal component contribution rate

      化学指标 公因子 贡献率(%) 实测平均浓度M 预测平均浓度P 比值(M/P) R2
      F1 F2 F3 F4 F1 F2 F3 F4 其他
      PH -0.18 0.54 0.19 0.56 4.63 11.53 2.37 18.96 62.51 7.94 7.97 0.996 0.73
      TDS 0.96 0.23 0.00 -0.01 46.43 11.34 0.25 0.35 41.63 688.48 693.77 0.992 0.98
      TH 0.95 -0.10 -0.03 0.02 69.04 7.23 2.43 0.59 20.71 263.70 265.60 0.993 0.91
      K+ 0.42 -0.70 -0.03 0.32 18.97 41.46 1.38 4.14 34.05 1.42 1.43 0.993 0.78
      Na+ 0.89 0.36 0.02 -0.03 38.00 15.68 1.05 0.72 44.55 131.02 132.12 0.992 0.92
      Ca2+ 0.78 -0.30 -0.01 0.07 51.98 24.55 1.72 13.66 8.09 66.02 66.41 0.994 0.71
      Mg2+ 0.94 0.15 -0.04 -0.03 58.93 9.32 2.53 2.07 27.15 23.95 24.17 0.991 0.91
      Cl- 0.91 0.31 -0.04 -0.07 49.38 16.72 1.87 3.42 28.61 139.11 140.41 0.991 0.93
      SO42- 0.93 0.19 0.03 0.00 43.02 9.12 1.62 0.61 45.63 216.38 218.07 0.992 0.90
      HCO3- 0.43 -0.41 0.25 0.21 16.63 16.27 9.40 7.35 50.35 154.33 155.21 0.994 0.45
      CO32- -0.21 0.49 0.18 0.63 2.59 7.01 3.33 14.16 72.91 1.54 1.55 0.994 0.83
      F- -0.01 0.25 0.78 -0.16 0.29 8.18 24.76 3.83 62.94 0.46 0.46 1.000 0.70
      NO3- 0.19 -0.71 0.16 0.38 5.79 26.04 5.27 7.67 55.23 1.46 1.48 0.986 0.71
      SiO2 0.02 -0.27 0.73 -0.27 6.50 19.36 49.88 16.38 7.88 7.60 7.64 0.995 0.68
      注:平均浓度中pH为无量量纲,其余单位为mg/L.
      下载: 导出CSV
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