深部碳循环的锌同位素示踪研究进展

王照雪; 刘盛遨; 李孟伦; 李曙光

doi:10.3799/dqkx.2020.159

深部碳循环的锌同位素示踪研究进展

doi: 10.3799/dqkx.2020.159

中国地质大学地质过程与矿产资源国家重点实验室, 北京 100083

基金项目:

国家自然科学基金重点项目 41730214

优秀青年基金项目 41622303

详细信息

作者简介:
王照雪(1996-), 女, 硕士研究生, 主要从事锌同位素地球化学研究

通讯作者:
刘盛遨

中图分类号: P597.2
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- 被引次数: 0
出版历程
- 收稿日期: 2020-01-15
- 刊出日期: 2020-06-15

Advances on Application of Zinc Isotope as a Tracer for Deep Carbon Cycles

State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China

摘要

摘要: 深部碳循环和地球表层的碳循环一起构成了全球的碳循环.因为地球超过90%的碳都位于深部，深部碳循环研究对于理解地球长期的气候变化具有重要的科学意义.深部碳循环研究涉及多个科学问题，其中最重要的科学问题之一是如何准确识别地幔中的碳是再循环的地表碳.锌作为亲石元素，广泛存在于岩浆岩、地幔和碳酸盐岩中.地幔和地表沉积碳酸盐岩之间锌同位素组成存在显著的差异，而板块俯冲脱水、地幔部分熔融和岩浆结晶分异等过程导致的锌同位素分馏较为有限，因此锌同位素具有示踪深部碳循环的潜力.系统阐述了锌同位素示踪深部碳循环的原理，回顾了目前应用锌同位素示踪深部碳循环取得的阶段性成果，并指出锌、镁同位素联合示踪有望成为未来深部碳循环研究的主流.
- 深部碳循环 /
- 锌同位素 /
- 地幔 /
- 碳酸盐岩 /
- 地球化学
Abstract: The deep carbon cycle and surface's carbon cycle together constitute the global carbon cycle. Research on deep carbon cycles is of significance for understanding the long-term climate change of the Earth given that >90% of Earth's carbon is stored in the deep Earth. Research on deep carbon cycles involves many aspects, among which one of the most important scientific issues is how to accurately identify recycled surface carbon in the mantle. Zinc (Zn) is a lithophile element and widely distributed in igneous rocks, mantle and sedimentary carbonates. There is a large Zn isotope difference between marine carbonates and the terrestrial mantle. Also, subduction-related dehydration, partial melting and magmatic differentiation only result in limited Zn isotope fractionation. Thus, Zn isotope has the potential as a novel tracer for deep carbon cycles. In this paper, the principle and potentiality of Zn isotope utilized as a tracer for deep carbon cycle are reviewed and the advances of using Zn isotope to trace deep carbon cycles in previous studies are presented. In addition, the combination between Zn and magnesium (Mg) isotopes is expect to the essential aspect of the deep carbon cycles in the future.
- deep carbon cycle /
- Zn isotope /
- mantle /
- carbonate /
- geochemistry

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图 1 地幔橄榄岩、碳酸盐岩和中国东部 < 110 Ma玄武岩的锌同位素组成

数据来源：碳酸盐岩(Pichat et al., 2003；Liu et al., 2017b；Sweere et al., 2018；Wang et al., 2018a)；中国东部玄武岩(Liu et al., 2016；Wang et al., 2017)；地幔(Wang et al., 2017；Sossi et al., 2018)；大洋玄武岩(Chen et al., 2013；Wang et al., 2017)

Fig. 1. The zinc isotope compositions of mantle peridotites, carbonatites, and basalts of eastern China (< 110 Ma)

下载: 全尺寸图片幻灯片

参考文献(63)

[1]	Aubaud, C., Pineau, F., Hékinian, R., et al., 2005.Degassing of CO₂ and H₂O in Submarine Lavas from the Society Hotspot.Earth and Planetary Science Letters, 235(3-4):511-527. https://doi.org/10.1016/j.epsl.2005.04.047
[2]	Beunon, H., Mattielli, N., Doucet, L.S., et al., 2020.Mantle Heterogeneity through Zn Systematics in Oceanic Basalts:Evidence for a Deep Carbon Cycling.Earth-Science Reviews, 103174. https://doi.org/10.1016/j.earscirev.2020.103174
[3]	Caroff, M., Maury, R.C., Guille, G., et al., 1997.Partial Melting below Tubuai (Austral Islands, French Polynesia).Contributions to Mineralogy and Petrology, 127(4):369-382. https://doi.org/10.1007/s004100050286
[4]	Chen, C.F., Liu, Y.S., Feng, L.P., et al., 2018.Calcium Isotope Evidence for Subduction-Enriched Lithospheric Mantle under the Northern North China Craton.Geochimica et Cosmochimica Acta, 238:55-67. https://doi.org/10.1016/j.gca.2018.06.038
[5]	Chen, H., Savage, P.S., Teng, F.Z., et al., 2013.Zinc Isotope Fractionation during Magmatic Differentiation and the Isotopic Composition of the Bulk Earth.Earth and Planetary Science Letters, 369-370:34-42. https://doi.org/10.1016/j.epsl.2013.02.037
[6]	Dasgupta, R., Hirschmann, M.M., 2010.The Deep Carbon Cycle and Melting in Earth's Interior.Earth and Planetary Science Letters, 298(1-2):1-13. https://doi.org/10.1016/j.epsl.2010.06.039
[7]	Dasgupta, R., Hirschmann, M.M., Smith, N.D., 2007.Partial Melting Experiments of Peridotite + CO₂ at 3 GPa and Genesis of Alkalic Ocean Island Basalts.Journal of Petrology, 48(11):2093-2124. https://doi.org/10.1093/petrology/egm053
[8]	Deines, P., 2002.The Carbon Isotope Geochemistry of Mantle Xenoliths.Earth-Science Reviews, 58(3-4):247-278. https://doi.org/10.1016/s0012-8252(02)00064-8
[9]	Dong, S.F., Wasylenki, L.E., 2016.Zinc Isotope Fractionation during Adsorption to Calcite at High and Low Ionic Strength.Chemical Geology, 447:70-78. https://doi.org/10.1016/j.chemgeo.2016.10.031
[10]	Doucet, L.S., Mattielli, N., Ionov, D.A., et al., 2016.Zn Isotopic Heterogeneity in the Mantle:A Melting Control? Earth and Planetary Science Letters, 451:232-240. https://doi.org/10.1016/j.epsl.2016.06.040
[11]	Frey, F.A., Green, D.H., Roy, S.D., 1978.Integrated Models of Basalt Petrogenesis:A Study of Quartz Tholeiites to Olivine Melilitites from South Eastern Australia Utilizing Geochemical and Experimental Petrological Data.Journal of Petrology, 19(3):463-13. https://doi.org/10.1093/petrology/19.3.463
[12]	Fujii, T., Moynier, F., Pons, M.L., et al., 2011.The Origin of Zn Isotope Fractionation in Sulfides.Geochimica et Cosmochimica Acta, 75(23):7632-7643. https://doi.org/10.1016/j.gca.2011.09.036
[13]	Hazen, R.M., Schiffries, C.M., 2013.Why Deep Carbon? Reviews in Mineralogy and Geochemistry, 75(1):1-6. https://doi.org/10.2138/rmg.2013.75.1
[14]	Helz, R.T., 1987.Differentiation Behaviour of Kilauea Iki Lava Lake, Kilauea Volcano, Hawaii:An Overview of Past and Current Work.Magmatic Processes:Physicochemical Principles, (1):241-258.
[15]	Huang, J., Li, S.G., Xiao, Y.L., et al., 2015.Origin of Low δ²⁶Mg Cenozoic Basalts from South China Block and Their Geodynamic Implications.Geochimica et Cosmochimica Acta, 164:298-317. https://doi.org/10.1016/j.gca.2015.04.054
[16]	Huang, J., Zhang, X.C., Chen, S., et al., 2018.Zinc Isotopic Systematics of Kamchatka-Aleutian Arc Magmas Controlled by Mantle Melting.Geochimica et Cosmochimica Acta, 238:85-101. https://doi.org/10.1016/j.gca.2018.07.012
[17]	Huang, S.C., Farkaš, J., Jacobsen, S.B., 2011.Stable Calcium Isotopic Compositions of Hawaiian Shield Lavas:Evidence for Recycling of Ancient Marine Carbonates into the Mantle.Geochimica et Cosmochimica Acta, 75(17):4987-4997. https://doi.org/10.1016/j.gca.2011.06.010
[18]	Inglis, E.C., Debret, B., Burton, K.W., et al., 2017.The Behavior of Iron and Zinc Stable Isotopes Accompanying the Subduction of Mafic Oceanic Crust:A Case Study from Western Alpine Ophiolites.Geochemistry, Geophysics, Geosystems, 18(7):2562-2579. https://doi.org/10.1002/2016gc006735
[19]	John, S.G., Rouxel, O.J., Craddock, P.R., et al., 2008.Zinc Stable Isotopes in Seafloor Hydrothermal Vent Fluids and Chimneys.Earth and Planetary Science Letters, 269(1):17-28. https://doi.org/10.1016/j.epsl.2007.12.011
[20]	Le Roux, V., Lee, C.T.A., Turner, S.J., 2010.Zn/Fe Systematics in Mafic and Ultramafic Systems:Implications for Detecting Major Element Heterogeneities in the Earth's Mantle.Geochimica et Cosmochimica Acta, 74(9):2779-2796. https://doi.org/10.1016/j.gca.2010.02.004
[21]	Lee, C.A., Shen, B., Slotnick, B.S., et al., 2013.Continental Arc-Island Arc Fluctuations, Growth of Crustal Carbonates, and Long-Term Climate Change.Geosphere, 9(1):21-36. https://doi.org/10.1130/ges00822.1
[22]	Li, J.L., Klemd, R., Gao, J., et al., 2014.Compositional Zoning in Dolomite from Lawsonite-Bearing Eclogite (SW Tianshan, China):Evidence for Prograde Metamorphism during Subduction of Oceanic Crust.American Mineralogist, 99(1):206-217. https://doi.org/10.2138/am.2014.4507
[23]	Li, S.G., Wang, Y., 2018.Formation Time of the Big Mantle Wedge beneath Eastern China and a New Lithospheric Thinning Mechanism of the North China Craton:Geodynamic Effects of Deep Recycled Carbon.Science China Earth Sciences, 61(7):853-868. https://doi.org/10.1007/s11430-017-9217-7
[24]	Li, S.G., Yang, W., Ke, S., et al., 2017.Deep Carbon Cycles Constrained by a Large-Scale Mantle Mg Isotope Anomaly in Eastern China.National Science Review, 4(1):111-120. https://doi.org/10.1093/nsr/nww070
[25]	Liu, D., Zhao, Z.D., Zhu, D.C., et al., 2015.Identifying Mantle Carbonatite Metasomatism through Os-Sr-Mg Isotopes in Tibetan Ultrapotassic Rocks.Earth and Planetary Science Letters, 430:458-469. https://doi.org/10.1016/j.epsl.2015.09.005
[26]	Liu, F., Li, X., Wang, G.Q., et al., 2017a.Marine Carbonate Component in the Mantle beneath the Southeastern Tibetan Plateau:Evidence from Magnesium and Calcium Isotopes.Journal of Geophysical Research:Solid Earth, 122(12):9729-9744. https://doi.org/10.1002/2017jb014206
[27]	Liu, S.A., Wu, H., Shen, S., et al., 2017b.Zinc Isotope Evidence for Intensive Magmatism Immediately before the End-Permian Mass Extinction.Geology, 45(4):343-346. https://doi.org/10.1130/g38644.1
[28]	Liu, S.A., Li, S.G., 2019.Tracing the Deep Carbon Cycle Using Metal Stable Isotopes:Opportunities and Challenges.Engineering, 5(3):448-457. https://doi.org/10.1016/j.eng.2019.03.007
[29]	Liu, S.A., Liu, P.P., Lü, Y., et al., 2019.Cu and Zn Isotope Fractionation during Oceanic Alteration:Implications for Oceanic Cu and Zn Cycles.Geochimica et Cosmochimica Acta, 257:191-205. https://doi.org/10.1016/j.gca.2019.04.026
[30]	Liu, S.A., Wang, Z.Z., Li, S.G., et al., 2016.Zinc Isotope Evidence for a Large-Scale Carbonated Mantle beneath Eastern China.Earth and Planetary Science Letters, 444:169-178. https://doi.org/10.1016/j.epsl.2016.03.051
[31]	Lundstrom, C.C., 2000.Rapid Diffusive Infiltration of Sodium into Partially Molten Peridotite.Nature, 403(6769):527. https://doi.org/10.1038/35000546
[32]	Mavromatis, V., González, A.G., Dietzel, M., et al., 2019.Zinc Isotope Fractionation during the Inorganic Precipitation of Calcite-Towards a New pH Proxy.Geochimica et Cosmochimica Acta, 244:99-112. https://doi.org/10.1016/j.gca.2018.09.005
[33]	McCoy-West, A.J., Fitton, J.G., Pons, M.L., et al., 2018.The Fe and Zn Isotope Composition of Deep Mantle Source Regions:Insights from Baffin Island Picrites.Geochimica et Cosmochimica Acta, 238:542-562. https://doi.org/10.1016/j.gca.2018.07.021
[34]	McDonough, W.F., Sun, S.S., 1995.The Composition of the Earth.Chemical Geology, 120(3-4):223-253. https://doi.org/10.1016/0009-2541(94)00140-4
[35]	Moynier, F., Vance, D., Fujii, T., et al., 2017.The Isotope Geochemistry of Zinc and Copper.Reviews in Mineralogy and Geochemistry, 82(1):543-600. https://doi.org/10.2138/rmg.2017.82.13
[36]	O'Hara, M.J., Yoder, H.S., 1967.Formation and Fractionation of Basic Magmas at High Pressures.Scottish Journal of Geology, 3(1):67-117. https://doi.org/10.1144/sjg03010067
[37]	Pichat, S., Douchet, C., Albarède, F., 2003.Zinc Isotope Variations in Deep-Sea Carbonates from the Eastern Equatorial Pacific over the Last 175 ka.Earth and Planetary Science Letters, 210(1-2):167-178. https://doi.org/10.1016/s0012-821x(03)00106-7
[38]	Pilet, S., Baker, M.B., Stolper, E.M., 2008.Metasomatized Lithosphere and the Origin of Alkaline Lavas.Science, 320(5878):916-919. https://doi.org/10.1126/science.1156563
[39]	Pons, M.L., Debret, B., Bouilhol, P., et al., 2016.Zinc Isotope Evidence for Sulfate-Rich Fluid Transfer across Subduction Zones.Nature Communications, 7:13794. https://doi.org/10.1038/ncomms13794
[40]	Reeder, R.J., Lamble, G.M., Northrup, P.A., 1999.XAFS Study of the Coordination and Local Relaxation around Co²⁺, Zn²⁺, Pb²⁺, and Ba²⁺ Trace Elements in Calcite.American Mineralogist, 84(7-8):1049-1060. https://doi.org/10.2138/am-1999-7-807
[41]	Richter, F.M., Watson, E.B., Mendybaev, R.A., et al., 2008.Magnesium Isotope Fractionation in Silicate Melts by Chemical and Thermal Diffusion.Geochimica et Cosmochimica Acta, 72(1):206-220. https://doi.org/10.1016/j.gca.2007.10.016
[42]	Shen, J., Li, W.Y., Li, S.G., et al., 2019.Crust-Mantle Interactions at Different Depths in the Subduction Channel:Magnesium Isotope Records of Ultramafic Rocks from the Mantle Wedges.Earth Science, 44(12):4102-4111(in Chinese with English abstract).
[43]	Shields, W.R., Murphy, T.J., Garner, E.L., 1964.Absolute Isotopic Abundance Ratio and the Atomic Weight of a Reference Sample of Copper.Journal of Research of the National Bureau of Standards Section A:Physics and Chemistry, 68A:589-592. https://doi.org/10.6028/jres.068a.056
[44]	Sossi, P.A., Nebel, O., O'Neill, H.S.C., et al., 2018.Zinc Isotope Composition of the Earth and Its Behaviour during Planetary Accretion.Chemical Geology, 477:73-84. https://doi.org/10.1016/j.chemgeo.2017.12.006
[45]	Sun, Y., Teng, F.Z., Ying, J.F., et al., 2017.Magnesium Isotopic Evidence for Ancient Subducted Oceanic Crust in LOMU-Like Potassium-Rich Volcanic Rocks.Journal of Geophysical Research:Solid Earth, 122(10):7562-7572. https://doi.org/10.1002/2017jb014560
[46]	Sweere, T.C., Dickson, A.J., Jenkyns, H.C., et al., 2018.Isotopic Evidence for Changes in the Zinc Cycle during Oceanic Anoxic Event 2 (Late Cretaceous).Geology, 46(5):463-466. https://doi.org/10.1130/g40226.1
[47]	Tang, Y.J., Zhang, H.F., Ying, J.F., 2006.Asthenosphere-Lithospheric Mantle Interaction in an Extensional Regime:Implication from the Geochemistry of Cenozoic Basalts from Taihang Mountains, North China Craton.Chemical Geology, 233(3-4):309-327. https://doi.org/10.1016/j.chemgeo.2006.03.013
[48]	Tian, H.C., Yang, W., Li, S.G., et al., 2016.Origin of Low δ²⁶Mg Basalts with EM-I Component:Evidence for Interaction between Enriched Lithosphere and Carbonated Asthenosphere.Geochimica et Cosmochimica Acta, 188:93-105. https://doi.org/10.1016/j.gca.2016.05.021
[49]	Tian, H.C., Yang, W., Li, S.G., et al., 2018.Low δ²⁶Mg Volcanic Rocks of Tengchong in Southwestern China:A Deep Carbon Cycle Induced by Supercritical Liquids.Geochimica et Cosmochimica Acta, 240:191-219. https://doi.org/10.1016/j.gca.2018.08.032
[50]	Turekian, K.K., Wedepohl, K.H., 1961.Distribution of the Elements in Some Major Units of the Earth's Crust.Geological Society of America Bulletin, 72(2):175-192. doi: 10.1130/0016-7606(1961)72[175:DOTEIS]2.0.CO;2
[51]	Walter, M.J., Bulanova, G.P., Armstrong, L.S., et al., 2008.Primary Carbonatite Melt from Deeply Subducted Oceanic Crust.Nature, 454(7204):622-625. https://doi.org/10.1038/nature07132
[52]	Wang, X., Liu, S.A., Wang, Z.R., et al., 2018a.Zinc and Strontium Isotope Evidence for Climate Cooling and Constraints on the Frasnian-Famennian (~372 Ma) Mass Extinction.Palaeogeography, Palaeoclimatology, Palaeoecology, 498:68-82. https://doi.org/10.1016/j.palaeo.2018.03.002
[53]	Wang, Z.Z., Liu, S.A., Chen, L.H., et al., 2018b.Compositional Transition in Natural Alkaline Lavas through Silica-Undersaturated Melt-Lithosphere Interaction.Geology, 46(9):771-774. https://doi.org/10.1130/g45145.1
[54]	Wang, Z.Z., Liu, S.A., Liu, J.G., et al., 2017.Zinc Isotope Fractionation during Mantle Melting and Constraints on the Zn Isotope Composition of Earth's Upper Mantle.Geochimica et Cosmochimica Acta, 198:151-167. https://doi.org/10.1016/j.gca.2016.11.014
[55]	Wang, Z.Z., Liu, S.A., Liu, Z.C., et al., 2020.Extreme Mg and Zn Isotope Fractionation Recorded in the Himalayan Leucogranites.Geochimica et Cosmochimica Acta, 278:305-321. https://doi.org/10.1016/j.gca.2019.09.026
[56]	Yang, C., Liu, S.A., 2019.Zinc Isotope Constraints on Recycled Oceanic Crust in the Mantle Sources of the Emeishan Large Igneous Province.Journal of Geophysical Research:Solid Earth, 124(12):12537-12555. https://doi.org/10.1029/2019jb017405
[57]	Yang, W., Li, S.G., 2008.Geochronology and Geochemistry of the Mesozoic Volcanic Rocks in Western Liaoning:Implications for Lithospheric Thinning of the North China Craton.Lithos, 102(1-2):88-117. https://doi.org/10.1016/j.lithos.2007.09.018
[58]	Yang, W., Teng, F.Z., Zhang, H.F., et al., 2012.Magnesium Isotopic Systematics of Continental Basalts from the North China Craton:Implications for Tracing Subducted Carbonate in the Mantle.Chemical Geology, 328:185-194. https://doi.org/10.1016/j.chemgeo.2012.05.018
[59]	Zhang, G.L., Chen, L.H., Jackson, M.G., et al., 2017.Evolution of Carbonated Melt to Alkali Basalt in the South China Sea.Nature Geoscience, 10(3):229-235. https://doi.org/10.1038/ngeo2877
[60]	Zhang, H.M., Li, S.G., 2012.Deep Carbon Recycling and Isotope Tracing:Review and Prospect.Science China:Earth Sciences, 42(10):1459-1472(in Chinese).
[61]	Zhu, H.L., Liu, F., Li, X., et al., 2020.Significant δ^44/40Ca Variations between Carbonate-and Clay-Rich Marine Sediments from the Lesser Antilles Forearc and Implications for Mantle Heterogeneity.Geochimica et Cosmochimica Acta, 276:239-257. https://doi.org/10.1016/j.gca.2020.02.033
[62]	沈骥, 李王晔, 李曙光, 等, 2019.俯冲隧道内不同深度的壳幔相互作用:地幔楔超镁铁质岩的镁同位素记录.地球科学, 44(12):4102-4111. doi: 10.3799/dqkx.2019.286
[63]	张洪铭, 李曙光, 2012.深部碳循环及同位素示踪:回顾与展望.中国科学:地球科学, 42(10):1459-1472.