Age and Tectonic Significance of Volcanic Rocks in Cretaceous Red Beds in Fujian
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摘要: 为了研究福建省白垩纪红层形成的时代及构造背景,在政和-大埔断裂以西选取典型红层盆地,对不同盆地内火山岩夹层进行LA-ICP-MS锆石同位素定年和岩石地球化学分析.同位素U-Pb测年结果显示:沙县组的时限较长,为127~87 Ma,其总体时代应大致相当于晚白垩世早期,下部层段跨入早白垩世晚期;崇安组年龄为100.0±1.2 Ma,形成时代为晚白垩世早期.岩石地球化学结果表明,白垩纪红层中的火山岩为壳源成因,是处伸展环境下,为构造活动引起区域断陷拉张作用形成的一套钙碱性系列流纹岩.Abstract: In order to research the age and tectonic setting of the Cretaceous red beds in Fujian Province, typical red bed basins were selected on the west of the Zhenghe-Dapu fault, LA-ICP-MS zircon isotopic dating and rock geochemical analysis were performed on volcanic rocks in different basins. The results of zircon U-Pb isotopic dating show that the Shaxian Formation has a longer duration, which is 127-87 Ma, and its overall age should be roughly in early Late Cretaceous, and the lower part will enter the late Early Cretaceous. The age of the Chong'an Formation is 100.0±1.2 Ma, which is early Late Cretaceous. The results of petrochemical chemistry indicate that the volcanic rocks in the Cretaceous red beds are crust-originated and are a set of calcareous series rhyolites, which is in the extensional environment and formed by regional fault depression of tectonic activity.
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Key words:
- Cretaceous /
- red bed /
- volcanic rocks /
- Shaxian Formation /
- tectonics
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图 2 福建白垩纪红层火山岩野外及镜下照片
a.建瓯流纹质晶屑岩屑凝灰岩;b.建瓯流纹质晶屑岩屑凝灰岩镜下特征;c.白沙沉凝灰岩;d.白沙沉凝灰岩镜下特征;e.泰宁风洞流纹质晶屑弱熔结凝灰岩;f.风洞流纹质晶屑弱熔结凝灰岩镜下特征;g. 泰宁大金湖流纹质晶屑凝灰岩;h. 大金湖流纹质晶屑凝灰岩镜下特征;i.上杭流纹质角砾岩屑凝灰岩;j.上杭流纹质角砾岩屑凝灰岩镜下特征;k.武平流纹质晶屑凝灰岩;l.武平流纹质晶屑凝灰岩镜下特征
Fig. 2. Field photos and photomicrographs of the Cretaceous red bed volcanic rocks in Fujian Province
图 10 微量元素构造背景判别图
a. Nb-Y图解;b. Rb-(Y+Nb)图解;WPG.板内花岗岩;VAG.火山弧花岗岩;syn-COLG.同碰撞花岗岩;ORG.洋脊花岗岩;图a中断线是产于异常洋脊的ORG的边界线;LCC.下陆壳;AFC.地壳混染与分离结晶作用; 据Pearce(1984, 1996)
Fig. 10. Discrimination diagrams of tectonic settings by trace elements
图 11 R1-R2构造环境判别图
1.地幔分异产物;2.板块碰撞前;3.碰撞后隆起;4.造山晚期;5.非造山;6.同碰撞;7.造山后;据Batchelor and Bowden(1985)
Fig. 11. Diagrams of tectonic settings by R1-R2
图 12 戈蒂尼-里特曼指数图
A区.板内稳定区;B区.造山带区(岛弧及活动大陆边缘);C区. A及B区演化的碱性火山岩; 据Rittmann(1973)
Fig. 12. Index diagram of lgδ-lgτ
表 1 建瓯盆地JOTW样品LA-ICP-MS锆石U-Pb数据
Table 1. LA-ICP-MS U-Pb abundance of zircons from sample JOTW in Jianou basin
测点 (10-6) Th/U 同位素比值 同位素年龄(Ma) Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 2 491.44 264.83 1.86 0.047 7 0.002 8 0.120 4 0.006 5 0.018 5 0.000 4 87 133 115 6 118 2 4 205.05 281.76 0.73 0.053 0 0.003 5 0.140 7 0.008 3 0.019 7 0.000 4 328 150 134 7 126 3 5 1 055.23 675.42 1.56 0.051 4 0.002 3 0.141 3 0.006 6 0.019 7 0.000 3 257 108 134 6 126 2 6 448.27 477.47 0.94 0.047 5 0.0030 0.120 3 0.006 4 0.018 5 0.000 4 72 144 115 6 118 2 7 108.62 119.91 0.91 0.057 5 0.008 7 0.146 7 0.019 2 0.019 3 0.001 0 522 335 139 17 123 6 8 1 200.21 812.79 1.48 0.047 6 0.002 4 0.123 0 0.005 3 0.018 8 0.000 3 76 115 118 5 120 2 9 296.24 351.40 0.84 0.056 5 0.004 4 0.149 5 0.009 8 0.019 6 0.000 5 472 169 141 9 125 3 11 463.03 397.40 1.17 0.053 0 0.003 5 0.144 6 0.009 2 0.019 9 0.000 4 328 153 137 8 127 2 12 380.58 462.79 0.82 0.050 3 0.002 7 0.124 5 0.006 4 0.018 2 0.000 4 206 122 119 6 116 2 13 535.76 302.40 1.77 0.052 5 0.005 0 0.126 7 0.011 4 0.017 9 0.000 5 306 217 121 10 115 3 14 325.74 285.01 1.14 0.051 5 0.003 6 0.131 4 0.008 5 0.018 8 0.000 4 261 158 125 8 120 2 15 393.87 438.88 0.90 0.050 8 0.002 9 0.128 3 0.007 4 0.018 5 0.000 4 235 131 123 7 118 2 16 349.09 262.30 1.33 0.050 0 0.004 0 0.124 2 0.007 8 0.018 7 0.000 5 195 174 119 7 120 3 18 459.63 410.12 1.12 0.051 0 0.003 6 0.135 3 0.008 5 0.019 6 0.000 4 243 163 129 8 125 2 19 323.01 312.96 1.03 0.055 4 0.003 7 0.135 0 0.008 3 0.018 1 0.000 4 428 150 129 7 115 3 21 967.26 828.83 1.17 0.046 4 0.0028 0.117 0 0.006 6 0.018 3 0.000 3 20 146 112 6 117 2 22 393.58 497.70 0.79 0.047 5 0.002 6 0.123 5 0.006 4 0.018 7 0.000 3 72 126 118 6 120 2 23 210.09 229.60 0.92 0.049 4 0.003 8 0.124 6 0.008 5 0.018 9 0.000 5 169 170 119 8 121 3 24 168.68 245.10 0.69 0.052 3 0.003 5 0.136 6 0.008 2 0.019 3 0.000 4 302 156 130 7 123 3 25 206.58 240.15 0.86 0.046 8 0.003 5 0.122 3 0.008 1 0.018 9 0.000 4 39 170 117 7 121 3 26 183.89 163.26 1.13 0.052 9 0.004 2 0.125 2 0.007 4 0.018 4 0.000 5 324 181 120 7 118 3 27 192.29 271.53 0.71 0.047 8 0.004 0 0.123 8 0.010 2 0.018 7 0.000 7 100 180 118 9 120 4 29 189.35 152.62 1.24 0.049 9 0.004 8 0.125 3 0.009 5 0.019 7 0.000 7 191 207 120 9 126 4 表 2 白沙盆地BsTW样品LA-ICP-MS锆石U-Pb数据
Table 2. LA-ICP-MS U-Pb abundance of zircons from sample BsTW in Baisha basin
测点 (10-6) Th/U 同位素比值 同位素年龄(Ma) Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 3 138.12 393.06 0.35 0.050 9 0.001 8 0.127 5 0.002 8 0.018 2 0.000 3 236 80 122 3 116 2 4 232.13 396.70 0.59 0.051 9 0.001 8 0.136 5 0.003 0 0.019 1 0.000 3 280 79 130 3 122 2 5 233.64 455.61 0.51 0.049 3 0.001 9 0.126 3 0.003 3 0.018 6 0.000 3 161 87 121 3 119 2 7 133.70 217.41 0.61 0.050 4 0.002 1 0.132 9 0.004 1 0.019 1 0.000 3 214 94 127 4 122 2 9 172.86 294.62 0.59 0.048 8 0.001 8 0.128 1 0.003 1 0.019 1 0.000 3 137 85 122 3 122 2 10 293.04 602.21 0.49 0.048 0 0.001 6 0.125 6 0.002 5 0.019 0 0.000 3 101 79 120 2 121 2 14 221.74 474.93 0.47 0.048 6 0.002 0 0.126 3 0.003 8 0.018 9 0.000 3 128 94 121 3 120 2 15 998.71 755.95 1.32 0.049 0 0.001 7 0.125 5 0.002 6 0.018 6 0.000 3 148 79 120 2 119 2 18 131.46 141.49 0.93 0.048 7 0.002 3 0.122 3 0.004 6 0.018 2 0.000 3 136 107 117 4 116 2 19 274.94 358.98 0.77 0.048 1 0.001 8 0.124 8 0.003 0 0.018 8 0.000 3 104 84 119 3 120 2 20 203.19 260.87 0.78 0.050 4 0.002 1 0.131 3 0.004 2 0.018 9 0.000 3 214 95 125 4 121 2 21 222.66 258.82 0.86 0.048 9 0.001 9 0.126 2 0.003 5 0.018 7 0.000 3 145 90 121 3 119 2 24 267.44 396.11 0.68 0.048 8 0.001 8 0.127 5 0.003 2 0.018 9 0.000 3 140 86 122 3 121 2 表 3 泰宁盆地风洞14611TW样品LA-ICP-MS锆石U-Pb数据
Table 3. LA-ICP-MS U-Pb abundance of zircons from sample 14611TW in Fengdong of Taining basin
测点 (10-6) Th/U 同位素比值 同位素年龄(Ma) Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 2 120.4 186.76 0.64 0.0481 0.002 2 0.103 1 0.003 7 0.015 5 0.000 2 105 104 100 3 99 1 3 112.6 133.85 0.84 0.0489 0.003 1 0.112 5 0.006 3 0.016 7 0.000 3 143 142 108 6 107 2 4 148.9 217.33 0.69 0.050 9 0.002 2 0.114 2 0.003 6 0.016 3 0.000 2 238 95 110 3 104 1 5 284.9 648.43 0.44 0.047 5 0.001 7 0.108 1 0.002 3 0.016 5 0.000 2 74 82 104 2 106 1 6 118.1 202.25 0.58 0.048 7 0.003 6 0.107 1 0.007 2 0.015 9 0.000 3 135 164 103 7 102 2 7 249.9 454.79 0.55 0.048 5 0.001 8 0.103 5 0.002 4 0.015 5 0.000 2 123 83 100 2 99 1 8 232.3 493.45 0.47 0.050 0 0.001 8 0.109 6 0.002 5 0.015 9 0.000 2 197 82 106 2 102 1 9 290.4 616.31 0.47 0.048 4 0.001 7 0.101 6 0.002 1 0.015 2 0.000 2 120 80 98 2 97 1 10 104.3 180.26 0.58 0.052 4 0.002 4 0.116 2 0.004 0 0.016 1 0.000 2 302 99 112 4 103 2 11 555.5 836.37 0.66 0.051 9 0.002 1 0.113 7 0.003 3 0.015 9 0.000 2 280 90 109 3 102 1 12 133.6 174.96 0.76 0.049 9 0.002 2 0.111 5 0.003 8 0.016 2 0.000 2 192 100 107 4 104 2 15 93.21 142.06 0.66 0.048 0 0.003 8 0.100 7 0.007 4 0.015 2 0.000 3 97 180 97 7 97 2 16 138.8 362.02 0.38 0.050 8 0.002 0 0.112 5 0.003 2 0.016 1 0.000 2 231 89 108 3 103 1 17 298.4 683.01 0.44 0.051 3 0.002 0 0.112 9 0.003 2 0.016 0 0.000 2 256 88 109 3 102 1 18 458.2 931.71 0.49 0.050 6 0.001 7 0.112 7 0.002 1 0.016 2 0.000 2 222 75 109 2 103 1 20 207.3 456.18 0.45 0.049 6 0.001 8 0.107 4 0.002 7 0.015 7 0.000 2 174 84 104 2 101 1 21 169.7 347.64 0.49 0.048 8 0.001 8 0.109 5 0.002 7 0.016 3 0.000 2 139 84 106 2 104 1 23 411.5 942.11 0.44 0.050 4 0.001 7 0.110 0 0.002 0 0.015 8 0.000 2 212 74 106 2 101 1 24 140.5 276.71 0.51 0.052 5 0.002 1 0.117 6 0.003 3 0.016 3 0.000 2 306 87 113 3 104 1 表 4 泰宁盆地大金湖TNTW样品LA-ICP-MS锆石U-Pb数据
Table 4. LA-ICP-MS U-Pb abundance of zircons from sample TNTW in Fengdong of Taining basin
测点 (10-6) Th/U 同位素比值 同位素年龄(Ma) Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 1 45.3 72.9 0.62 0.057 6 0.008 4 0.112 6 0.011 8 0.015 9 0.000 7 517 320 108 11 101 4 3 159.0 291.0 0.55 0.050 5 0.003 9 0.103 5 0.006 9 0.015 3 0.000 4 220 178 100 6 98 2 4 53.9 65.9 0.82 0.048 5 0.011 2 0.078 9 0.012 9 0.015 5 0.000 9 124 470 77 12 99 6 5 52.8 75.0 0.70 0.048 5 0.005 7 0.090 6 0.008 3 0.015 9 0.000 5 124 252 88 8 102 3 6 74.4 137.8 0.54 0.054 2 0.007 4 0.097 3 0.008 9 0.013 6 0.000 4 389 311 94 8 87 3 7 217.0 447.0 0.48 0.045 9 0.002 9 0.096 0 0.005 1 0.015 5 0.000 3 23 222 78 93 5 99 2 8 148.0 246.0 0.60 0.050 3 0.004 1 0.100 5 0.007 3 0.015 2 0.000 4 209 189 97 7 97 2 9 118.0 212.0 0.56 0.051 5 0.004 2 0.105 8 0.007 8 0.015 5 0.000 4 265 189 102 7 99 3 10 37.3 48.8 0.76 0.058 3 0.011 4 0.105 2 0.012 3 0.015 9 0.001 0 543 431 102 11 102 7 12 118.0 109.0 1.08 0.058 1 0.009 4 0.102 4 0.012 2 0.015 0 0.000 8 600 361 99 11 96 5 13 42.6 67.6 0.63 0.042 2 0.008 6 0.093 8 0.015 9 0.015 1 0.000 9 348 99 91 15 97 6 14 119.0 178.0 0.67 0.053 0 0.005 7 0.100 2 0.007 0 0.015 1 0.000 4 328 244 97 6 97 3 16 271.0 286.0 0.95 0.048 6 0.004 6 0.097 7 0.008 2 0.014 9 0.000 6 132 207 95 8 95 4 17 71.8 139.0 0.51 0.056 4 0.006 3 0.105 6 0.009 0 0.015 5 0.000 5 478 250 102 8 99 3 18 58.0 97.9 0.59 0.051 1 0.006 8 0.096 8 0.008 9 0.015 4 0.000 6 243 285 94 8 99 4 19 75.2 101.0 0.74 0.045 8 0.007 6 0.086 6 0.009 8 0.015 8 0.000 7 347 82 84 9 101 4 20 71.2 82.5 0.86 0.067 8 0.013 8 0.103 1 0.012 7 0.015 2 0.000 6 865 432 100 12 97 4 21 142 234.0 0.61 0.045 3 0.003 7 0.102 4 0.007 5 0.016 4 0.000 4 272 44 99 7 105 3 22 56.5 63.4 0.89 0.055 7 0.006 5 0.103 0 0.009 1 0.015 3 0.000 6 443 258 99 8 98 4 23 87.0 83.3 1.04 0.046 2 0.006 0 0.092 6 0.008 8 0.016 2 0.000 6 249 285 90 8 104 4 25 40.6 61.8 0.66 0.064 1 0.015 9 0.111 2 0.016 9 0.015 9 0.001 0 746 544 107 15 102 6 26 198.0 408.0 0.49 0.049 7 0.002 9 0.109 2 0.005 4 0.016 3 0.000 3 189 142 105 5 104 2 27 178.0 213.0 0.83 0.049 1 0.005 8 0.102 3 0.010 9 0.015 5 0.000 5 150 259 99 10 99 3 28 320.0 443.0 0.72 0.048 2 0.003 1 0.104 1 0.005 8 0.015 9 0.000 4 109 148 101 5 101 2 29 196.0 274.0 0.72 0.044 4 0.003 7 0.097 9 0.007 0 0.016 1 0.000 4 272 94 95 6 103 2 30 63.6 76.8 0.83 0.062 2 0.014 1 0.107 8 0.010 1 0.016 1 0.000 6 680 500 104 9 103 4 表 5 上杭盆地ShTW样品LA-ICP-MS锆石U-Pb数据
Table 5. LA-ICP-MS U-Pb abundance of zircons from sample ShTW in Shanghang basin
测点 (10-6) Th/U 同位素比值 同位素年龄(Ma) Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 1 600.36 412.67 1.45 0.047 3 0.003 2 0.096 0 0.0063 0.0147 0.000 2 62 153 93 6 94 2 2 212.37 115.46 1.84 0.050 1 0.019 1 0.100 6 0.037 6 0.014 6 0.001 2 199 706 97 35 93 8 3 475.00 465.15 1.02 0.052 8 0.003 1 0.103 0 0.005 9 0.014 1 0.000 2 322 128 100 5 91 1 4 477.34 416.10 1.15 0.049 0 0.003 1 0.099 0 0.006 2 0.014 7 0.000 2 147 144 96 6 94 1 5 1 011.51 704.36 1.44 0.046 9 0.002 4 0.093 5 0.004 6 0.014 5 0.000 2 42 118 91 4 93 1 6 454.99 472.90 0.96 0.048 9 0.003 0 0.096 9 0.005 7 0.014 4 0.000 2 142 137 94 5 92 1 7 951.05 403.43 2.36 0.050 6 0.004 4 0.098 3 0.008 4 0.014 1 0.000 3 223 190 95 8 90 2 8 513.29 472.52 1.09 0.047 1 0.003 1 0.098 1 0.006 4 0.015 1 0.000 2 56 152 95 6 97 2 9 765.05 482.08 1.59 0.049 6 0.003 8 0.102 9 0.007 8 0.015 0 0.000 3 178 171 99 7 96 2 10 551.34 479.21 1.10 0.051 6 0.003 9 0.105 2 0.007 7 0.014 8 0.000 3 266 163 102 7 95 2 11 1 116.74 525.37 2.13 0.047 6 0.004 4 0.099 8 0.009 0 0.015 2 0.000 3 80 206 97 8 97 2 12 229.68 109.03 2.11 0.049 0 0.007 3 0.097 6 0.014 2 0.014 4 0.000 5 149 316 95 13 92 3 13 536.86 474.44 1.13 0.052 0 0.005 1 0.101 3 0.009 6 0.014 1 0.000 3 287 209 98 9 90 2 14 465.70 439.72 1.06 0.048 9 0.003 0 0.100 5 0.006 1 0.014 9 0.000 2 141 139 97 6 95 1 15 2 406.64 529.16 4.55 0.052 0 0.002 9 0.105 8 0.005 7 0.014 8 0.000 2 284 122 102 5 94 1 16 650.03 510.54 1.27 0.049 9 0.002 9 0.100 7 0.005 7 0.014 6 0.000 2 189 131 97 5 94 1 17 596.32 317.25 1.88 0.050 9 0.009 9 0.105 3 0.019 9 0.015 0 0.000 7 237 395 102 18 96 4 18 360.64 219.61 1.64 0.053 2 0.005 8 0.109 3 0.011 6 0.014 9 0.000 4 338 229 105 11 95 2 19 571.81 466.22 1.23 0.051 3 0.007 5 0.100 8 0.014 4 0.014 2 0.000 5 256 305 98 13 91 3 20 1 294.90 861.69 1.50 0.049 2 0.002 1 0.098 2 0.004 1 0.014 5 0.000 2 156 98 95 4 93 1 21 847.18 558.48 1.52 0.050 8 0.003 3 0.103 4 0.006 5 0.014 8 0.000 2 232 142 100 6 94 1 22 2 487.35 744.17 3.43 0.048 1 0.002 6 0.095 5 0.005 0 0.014 4 0.000 2 103 124 93 5 92 1 23 628.40 473.44 1.33 0.047 7 0.002 8 0.099 5 0.005 6 0.015 1 0.000 2 83 133 96 5 97 1 24 498.85 377.03 1.32 0.053 1 0.003 5 0.108 4 0.007 0 0.014 8 0.000 2 334 144 105 6 95 1 表 6 武平盆地WPTW样品LA-ICP-MS锆石U-Pb数据
Table 6. LA-ICP-MS U-Pb abundance of zircons from sample WPTW in Wuping basin
测点 (10-6) Th/U 同位素比值 同位素年龄(Ma) Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 4 562.19 1 583.39 0.36 0.050 0 0.002 5 0.101 5 0.004 8 0.014 7 0.000 2 196 111 98 4 94 1 5 324.18 374.19 0.87 0.047 0 0.003 4 0.097 5 0.006 8 0.015 0 0.000 3 50 164 95 6 96 2 9 1 217.35 522.16 2.33 0.047 1 0.002 7 0.096 9 0.005 4 0.014 9 0.000 2 55 131 94 5 95 1 11 126.21 241.26 0.52 0.048 2 0.008 7 0.100 0 0.017 6 0.015 1 0.000 6 107 377 97 16 96 4 13 457.46 498.01 0.92 0.048 4 0.003 1 0.098 8 0.006 2 0.014 8 0.000 2 119 144 96 6 95 1 17 374.88 413.99 0.91 0.048 3 0.004 0 0.096 8 0.007 7 0.014 5 0.000 3 114 183 94 7 93 2 -
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