华北房山景儿峪组顶部古风化壳常量元素地球化学特征及其古气候意义

马晓晨; 王家生; 陈粲; 王舟

doi:10.3799/dqkx.2018.235

华北房山景儿峪组顶部古风化壳常量元素地球化学特征及其古气候意义

doi: 10.3799/dqkx.2018.235

马晓晨^1,2,,
王家生^1,2, ,,
陈粲^1,2,
王舟^1,2

1.
生物地质与环境地质国家重点实验室, 中国地质大学地球科学学院, 湖北武汉 430074
2.
中国地质大学海洋学院, 湖北武汉 430074

基金项目:

国家水合物专项 DD20160211

国家自然科学基金项目 41472085

国家自然科学基金项目 41772091

国家重点研发计划课题 2016YFA0601102

详细信息

作者简介:
马晓晨(1992-), 男, 博士研究生, 主要从事地史重大转折期古气侯和古海洋等研究

通讯作者:
王家生

中图分类号: P595
计量
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- 被引次数: 0
出版历程
- 收稿日期: 2018-07-09
- 刊出日期: 2018-11-15

Major Element Compositions and Paleoclimatic Implications of Paleo-Regolith on Top Jingeryu Formation in Fangshan, North China

Ma Xiaochen^{1,2
,},
Wang Jiasheng^{1,2
, ,},
Chen Can^1,2,
Wang Zhou^1,2

1.
State Key Laboratory of Biogeology and Environmental Geology, School of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2.
College of Marine Science and Technology, China University of Geosciences, Wuhan 430074, China

摘要

摘要: 风化壳的元素地球化学组成可以反映风化壳的发育类型及其气候特征，地史时期形成的古风化壳的元素地球化学组成可以揭示古风化壳的类型及其古气候特征.华北地区新元古代晚期（景儿峪组）至寒武纪（府君山组）期间的地层记录缺乏连续性，广泛发育一套典型的古风化壳，该古风化壳的发育过程可能记录了晚新元古代至早寒武纪期间的古气候特点.针对华北房山地区景儿峪组顶部保存的古风化壳中常量元素的组成、元素迁移富集特征和风化系数等分布规律开展了较系统分析，结果表明：（1）SiO₂、Al₂O₃、TFe₂O₃、CaO是景儿峪组顶部古风化壳的主要组分，Al₂O₃、TFe₂O₃、TiO₂、K₂O在风化壳的中上部相对富集，SiO₂则轻微亏损，CaO、Na₂O、MgO、P₂O₅被迁移淋失；（2）硅铝系数、硅铝铁系数、化学蚀变指数（CIA）、残积系数、风化淋溶系数（BA）等地球化学指标的垂向变化特征指示该古风化壳形成于温暖湿润条件下中等强度的化学风化作用，其风化过程可能经历了由较弱至较强再逐渐减弱的演变过程；（3）与现代发育于湖南、贵州、云南等地碳酸盐岩类基岩之上的风化壳元素地球化学特征对比，发现景儿峪组顶部古风化壳的Si淋失度和Fe、Al富集度均较低.综合研究区古风化壳的常量元素地球化学特征，同时结合新元古代晚期至寒武纪的华北板块古纬度迁移特征，认为房山地区景儿峪组顶部发育的古风化壳形成于温暖湿润的亚热带-热带气候，为脱硅富铝化程度较低的硅铝粘土型风化壳.
- 地球化学 /
- 古风化壳 /
- 古气候 /
- 房山 /
- 景儿峪组
Abstract: The geochemical composition of regolith can reflect its development processes and the background climatic characteristics of weathering processes, and geochemical compositions of the paleo-regolith formed in earth history can reveal the type of paleo-regolith and record paleoclimatic changes. The record between the Late Neoproterozoic (the Jingeryu Formation) and the Cambrian (the Fujunshan Formation) in North China is a stratigraphic hiatus due to the tectonic uplift and erosion. A typical paleo-regolith widely occurs and is supposed to have recorded paleoclimate changes during the Late Neoproterozoic to Early Cambrian. According to the compositions of major elements, enrichment in elemental migrations and coefficient of weathering distribution of paleo-regolith on the topmost Jingeryu Formation in the Fangshan area, North China, this study suggests that:(1) The major element compositions of the paleo-regolith on the topmost Jingeryu Formation are dominated by the elements of SiO₂, Al₂O₃, TFe₂O₃, CaO. And the elements of Al₂O₃, TFe₂O₃, TiO₂, K₂O are relatively concentrated in the middle-to-upper parts of the regolith while the SiO₂ is slightly lost. (2) The vertical variations of geochemical proxies such as SiO₂/Al₂O₃, SiO₂/(Al₂O₃+TFe₂O₃), chemical index of alteration (CIA), residual coefficient and BA value indicate that the paleo-regolith should have been formed under a warm and humid condition with moderate chemical weathering. The chemical weathering might have gone through an evolution from weak to strong and again to weak in degree. (3) Compared to the element geochemical characteristics of modern regolith on the topmost carbonate settings from Hunan, Guizhou and Yunnan, it is inferred that the paleo-regolith on the topmost Jingeryu Formation has relatively lower deficiency in Si and enrichment in Fe and Al. Consequently, by comprehensive analysis of the geochemical characteristics of paleo-regolith on the topmost Jingeryu Formation and changes in paleo-latitude of the North China block from the Late Neoproterozoic to the Cambria, it is proposed that the paleo-regolith on the topmost Jingeryu Formation might have been formed under conditions of a warm and humid tropical to subtropical climate siallite-clay regolith.
- geochemistry /
- paleo-regolith /
- paleoclimate /
- Fangshan /
- Jingeryu Formation

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图 1 房山地区地质简图

据吕金波等(2016)修改.a.黄院Ⅰ剖面；b.黄院Ⅱ剖面；c.龙宝峪剖面；d.北沟剖面

Fig. 1. Simplified geological map of the Fangshan area

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图 2 房山地区景儿峪组与府君山组之间古风化壳剖面顶部露头特征

Fig. 2. The outcrop characteristics of paleo-regolith on the top Jingeryu and Fujunshan formations in Fangshan area

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图 3 房山地区景儿峪组与府君山之间古风化壳剖面野外露头

Fig. 3. The outcrops of the paleo-regolith between Jingeryu and Fujunshan formations in Fangshan area

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图 4 房山地区景儿峪组-府君山组之间古风化壳剖面常量元素质量百分含量变化曲线

Fig. 4. The variations of major element contents in the paleo-regolith between Jingeryu and Fujunshan formations in Fangshan area

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图 5 景儿峪组与府君山组之间古风化壳中常量元素迁移因子示意图

Fig. 5. The diagram of the major element mobility factors in paleo-regolith between Jingeryu and Fujunshan formations

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图 6 房山地区景儿峪组与府君山组之间古风化壳剖面风化强度特征变化

Fig. 6. Changes in weathering intensity of the paleo-regoUth between Jingeryu and Fujunshan formations in Fangshan area

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图 7 房山地区景儿峪组-府君山组之间古风化壳与中国南方现代风化壳SiO₂-Al₂O₃-Fe₂O₃图

Fig. 7. The diagram of SiO₂-Al₂O₃-Fe₂O₃ compositions within the paleo-regolith between Jingeryu and Fujunshan in Fangshan area and the modern regolith sections from South China

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表 1 黄院Ⅰ剖面常量元素含量及风化系数(%)

Table 1. Major element contents and weathering parameters of Huangyuan Ⅰ profile (%)

	样品号	厚度(cm)	SiO₂	Al₂O₃	TFe₂O₃	MgO	CaO	Na₂O	K₂O	TiO₂	P₂O₅	MnO	S/A	S/R	A/(NK)	A/(CNK)	CIA	残积系数	BA
豹皮灰岩	HY-19-1	152.50	4.28	0.14	0.10	6.05	46.61	0.022	0.051	0.014	0.002	0.034	51.97	35.71	1.53	0.00	-	-	-
	HY-18-1	125.00	0.61	0.11	0.10	4.81	50.29	0.019	0.038	0.014	0.002	0.035	9.43	5.97	1.52	0.00	-	-	-
	HY-17-1	82.00	1.05	0.14	0.20	17.04	35.51	0.016	0.043	0.014	0.005	0.073	12.75	6.67	1.92	0.00	-	-	-
	HY-16-1	74.00	17.48	0.29	0.45	15.49	27.75	0.018	0.130	0.016	0.009	0.058	102.47	51.51	1.70	0.01	-	-	-
	HY-15-1	70.50	7.66	0.73	0.86	10.50	38.32	0.023	0.260	0.038	0.04	0.099	17.84	10.19	2.28	0.01	-	-	-
风化板岩	HY-14-1	65.00	42.63	6.14	2.37	0.77	24.76	0.07	2.140	0.270	0.420	0.051	11.80	9.47	2.52	0.13	70.64	0.16	0.74
	HY-13-1	65.00	42.65	3.95	1.97	0.50	27.23	0.047	1.280	0.170	0.310	0.060	18.36	13.93	2.69	0.08	71.90	0.10	0.71
	HY-12-1	61.50	38.87	5.77	3.67	0.65	26.47	0.063	1.920	0.220	0.240	0.058	11.45	8.15	2.64	0.11	71.58	0.16	0.68
	HY-11-1	58.75	46.34	10.44	1.91	0.96	19.05	0.099	3.550	0.470	0.770	0.043	7.55	6.76	2.60	0.27	71.42	0.31	0.63
	HY-10-1	55.00	69.95	12.24	0.91	1.18	4.72	0.110	4.220	0.630	0.710	0.011	9.72	9.28	2.57	0.92	71.24	1.09	0.65
	HY-9-1	52.25	33.04	3.73	1.02	0.70	32.96	0.044	1.190	0.150	0.260	0.072	15.06	12.82	2.74	0.06	72.20	0.07	0.86
	HY-8-1	50.50	32.90	5.52	1.15	0.87	31.33	0.06	1.770	0.250	0.290	0.069	10.13	8.94	2.73	0.09	72.27	0.11	0.79
钙质板岩	HY-7-1	47.25	34.46	4.20	1.91	1.13	30.69	0.048	1.340	0.330	0.280	0.065	13.95	10.81	2.74	0.07	72.26	0.09	1.07
	HY-6-1	42.75	36.51	4.98	2.06	1.06	28.97	0.051	1.570	0.190	0.340	0.065	12.46	9.86	2.79	0.09	72.69	0.11	0.92
	HY-5-1	38.25	32.65	3.89	1.63	0.96	32.32	0.043	1.210	0.160	0.250	0.076	14.27	11.26	2.81	0.06	72.79	0.08	1.00
	HY-4-2	34.25	33.55	2.72	1.47	0.73	33.06	0.037	0.880	0.092	0.240	0.083	20.97	15.60	2.68	0.04	71.64	0.06	1.08
	HY-4-1	30.75	29.11	2.67	1.42	0.67	35.52	0.036	0.890	0.110	0.310	0.084	18.53	13.84	2.60	0.04	71.12	0.05	1.05
	HY-3-1	22.50	38.42	4.85	1.91	1.28	27.82	0.049	1.470	0.210	0.300	0.069	13.47	10.76	2.89	0.09	73.41	0.11	1.04
	HY-2-1	10.25	39.14	7.10	2.40	1.29	25.30	0.064	2.240	0.320	0.480	0.056	9.37	7.71	2.80	0.15	72.89	0.17	0.84
	HY-1-2	3.75	37.54	5.88	1.66	1.16	27.85	0.060	2.040	0.240	0.390	0.064	10.85	9.20	2.54	0.11	70.92	0.13	0.91
	HY-1-1	1.25	37.48	6.55	1.37	1.13	27.34	0.065	2.220	0.280	0.480	0.066	9.73	8.58	2.60	0.13	71.41	0.14	0.84

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表 2 黄院Ⅱ剖面常量元素含量及风化系数(%)

Table 2. Major element contents and weathering parameters of Huangyuan Ⅱ profile (%)

	样品号	厚度(cm)	SiO₂	Al₂O₃	TFe₂O₃	MgO	CaO	Na₂O	K₂O	TiO₂	P₂O₅	MnO	S/A	S/R	A/(NK)	A/(CNK)	CIA	残积系数	BA
豹皮灰岩	HY2-23-1	141.50	1.01	0.071	0.072	8.21	46.11	0.042	0.036	0.016	0.005	0.037	24.18	14.69	0.66	0.00	-	-	-
	HY2-22-1	125.50	0.71	0.095	0.130	11.10	42.65	0.029	0.048	0.014	0.005	0.048	12.71	6.79	0.95	0.00	-	-	-
	HY2-21-1	114.50	0.98	0.110	0.100	9.73	44.00	0.025	0.059	0.016	0.005	0.045	15.15	9.59	1.05	0.00	-	-	-
	HY2-20-3	107.00	12.86	0.270	0.190	3.52	44.54	0.021	0.090	0.016	0.014	0.031	80.97	55.90	2.04	0.00	-	-	-
风化板岩	HY2-20-2	105.25	49.34	4.490	1.400	0.40	23.39	0.056	1.150	0.160	0.470	0.053	18.68	15.58	3.35	0.10	75.82	0.12	0.55
	HY2-20-1	102.75	45.36	4.650	2.500	0.34	24.80	0.060	0.920	0.160	0.350	0.072	16.58	12.35	4.24	0.10	79.55	0.14	0.44
	HY2-19-1	99.75	30.14	4.080	2.520	0.32	33.77	0.032	0.560	0.150	0.250	0.042	12.56	9.01	6.18	0.07	85.13	0.09	0.37
	HY2-18-1	97.50	30.51	4.060	1.220	0.29	34.51	0.045	0.620	0.180	0.220	0.029	12.78	10.72	5.44	0.06	83.18	0.08	0.38
	HY2-17-1	93.50	30.32	4.350	1.830	0.96	33.44	0.068	0.950	0.200	0.180	0.025	11.85	9.34	3.81	0.07	77.61	0.09	0.85
	HY2-16-1	90.00	32.71	4.400	1.240	0.57	32.44	0.110	1.040	0.190	0.230	0.023	12.64	10.71	3.36	0.07	74.70	0.09	0.67
	HY2-15-1	87.50	24.83	4.620	1.500	1.38	35.93	0.077	1.150	0.210	0.190	0.033	9.14	7.57	3.36	0.07	75.48	0.08	1.09
	HY2-14-1	85.00	17.92	2.300	0.550	0.40	43.29	0.030	0.650	0.100	0.170	0.025	13.25	11.49	3.05	0.03	74.10	0.03	0.79
钙质板岩	HY2-13-1	81.50	34.04	4.180	1.080	0.58	32.43	0.043	1.400	0.180	0.230	0.044	13.84	11.89	2.63	0.07	71.57	0.08	0.75
	HY2-12-1	78.75	30.36	4.960	1.280	0.83	33.34	0.048	1.700	0.220	0.290	0.042	10.41	8.94	2.58	0.08	71.24	0.09	0.83
	HY2-11-1	76.00	31.41	3.460	1.010	0.52	34.33	0.037	1.120	0.140	0.160	0.047	15.43	13.01	2.71	0.05	72.13	0.06	0.77
	HY2-10-1	70.00	43.97	7.320	2.840	1.26	22.56	0.070	2.740	0.350	1.140	0.055	10.21	8.19	2.37	0.17	69.56	0.21	0.88
	HY2-9-1	62.00	39.18	6.840	2.190	0.90	26.47	0.062	2.440	0.300	0.490	0.054	9.74	8.09	2.49	0.13	70.58	0.16	0.75
	HY2-8-1	56.00	41.35	5.860	2.090	0.99	25.58	0.058	2.180	0.270	0.380	0.053	12.00	9.77	2.38	0.12	69.63	0.15	0.87
	HY2-7-1	37.00	42.07	6.650	2.70	1.31	24.15	0.064	2.430	0.300	1.240	0.055	10.75	8.54	2.43	0.14	70.02	0.18	0.93
	HY2-6-1	29.00	41.37	5.970	2.390	1.14	25.37	0.061	2.220	0.270	1.030	0.061	11.78	9.39	2.38	0.12	69.58	0.15	0.92
	HY2-5-1	25.00	35.58	4.850	2.090	1.01	29.88	0.056	1.770	0.210	0.640	0.072	12.47	9.78	2.41	0.09	69.74	0.11	0.97
	HY2-4-1	19.75	35.73	4.920	2.360	1.16	29.60	0.051	1.710	0.210	0.660	0.068	12.35	9.45	2.54	0.09	70.86	0.11	1.01
	HY2-3-1	15.75	35.79	4.780	2.420	1.24	29.70	0.050	1.600	0.210	0.650	0.071	12.73	9.62	2.63	0.09	71.55	0.11	1.06
	HY2-2-1	9.00	47.16	8.000	2.650	1.49	19.99	0.070	2.620	0.360	1.120	0.049	10.02	8.27	2.70	0.20	72.25	0.24	0.86
	HY2-1-2	3.75	41.81	6.040	2.730	1.36	24.50	0.061	2.140	0.280	1.120	0.061	11.77	9.14	2.49	0.13	70.54	0.16	0.99
	HY2-1-1	1.25	43.51	6.310	2.760	1.33	23.36	0.061	2.190	0.290	0.880	0.059	11.72	9.17	2.55	0.14	71.00	0.18	0.95

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表 3 龙宝峪剖面常量元素含量及风化系数(%)

Table 3. Major element contents and weathering parameters of Longbaoyu profile (%)

	样品号	厚度(cm)	SiO₂	Al₂O₃	TFe₂O₃	MgO	CaO	Na₂O	K₂O	TiO₂	P₂O₅	MnO	S/A	S/R	A/(NK)	A/(CNK)	CIA	残积系数	BA
豹皮灰岩	LBY-26	157.5	0.43	0.084	0.12	5.56	48.96	0.007	0.047	0.014	0.005	0.007	8.70	4.55	1.34	0.00	-	-	-
	LBY-25	142.5	0.44	0.078	0.17	6.86	47.07	0.007	0.039	0.019	0.007	0.008	9.59	4.01	1.45	0.00	-	-	-
	LBY-24	132.5	0.39	0.081	0.14	6.22	48.24	0.006	0.028	0.022	0.007	0.010	8.19	3.89	2.01	0.00	-	-	-
	LBY-23	118.5	5.93	1.720	1.17	11.36	37.01	0.011	0.770	0.120	0.032	0.027	5.86	4.09	2.01	0.03	-	-	-
	LBY-22	116.5	3.57	0.960	0.69	6.74	44.76	0.008	0.390	0.059	0.021	0.022	6.32	4.34	2.20	0.01	-	-	-
	LBY-21	115.5	4.37	1.420	0.88	7.57	42.59	0.008	0.570	0.089	0.032	0.023	5.23	3.75	2.25	0.02	-	-	-
	LBY-20	114.5	7.81	2.010	1.48	12.12	34.53	0.010	0.840	0.130	0.037	0.033	6.61	4.50	2.17	0.03	-	-	-
	LBY-19	113.5	19.74	5.940	2.46	13.82	22.32	0.022	2.500	0.400	0.100	0.038	5.65	4.47	2.16	0.14	-	-	-
	LBY-18	111.5	25.02	5.540	1.93	9.04	25.87	0.019	2.300	0.350	0.120	0.035	7.68	6.28	2.19	0.11	-	-	-
	LBY-17	106.0	3.21	0.130	0.20	4.72	48.80	0.006	0.039	0.022	0.007	0.031	41.98	21.19	2.49	0.00	-	-	-
	LBY-16	100.5	0.86	0.140	0.14	3.95	50.81	0.006	0.053	0.022	0.009	0.028	10.44	6.38	2.08	0.00	-	-	-
风化板岩	LBY-15	98.0	60.7	3.430	1.50	0.42	18.05	0.037	1.160	0.140	0.330	0.037	30.08	23.53	2.60	0.10	71.30	0.13	0.71
	LBY-14	96.0	55.76	2.610	0.79	0.27	22.11	0.031	0.880	0.095	0.240	0.035	36.32	30.44	2.59	0.06	71.18	0.08	0.67
	LBY-13	94.0	47.1	3.180	1.11	0.30	26.27	0.039	1.060	0.110	0.320	0.047	25.18	20.60	2.62	0.06	71.32	0.08	0.64
	LBY-12	92.0	42.43	3.040	1.43	0.30	28.69	0.036	1.040	0.110	0.300	0.058	23.73	18.25	2.56	0.06	70.91	0.07	0.66
	LBY-11	89.5	46.23	3.330	1.40	0.40	26.36	0.039	1.170	0.140	0.310	0.054	23.60	18.61	2.50	0.07	70.43	0.09	0.73
	LBY-10	86.5	44.53	4.280	1.51	0.49	26.32	0.051	1.420	0.170	0.460	0.064	17.69	14.44	2.63	0.09	71.47	0.11	0.69
	LBY-09	83.5	37.11	4.810	1.83	0.86	29.44	0.050	1.720	0.240	0.440	0.088	13.12	10.56	2.47	0.09	70.31	0.11	0.88
	LBY-08	81.0	34.99	5.710	2.52	1.19	29.17	0.054	1.950	0.270	0.480	0.073	10.42	8.13	2.59	0.10	71.34	0.13	0.93
钙质板岩	LBY-07	77.5	39.36	5.960	2.63	1.36	26.35	0.056	2.050	0.290	0.250	0.071	11.23	8.76	2.57	0.12	71.22	0.15	0.99
	LBY-06	67.5	32.62	6.220	3.08	1.51	29.72	0.055	2.050	0.250	0.430	0.080	8.92	6.78	2.69	0.11	72.11	0.14	1.01
	LBY-05	52.5	34.68	5.200	2.46	1.46	29.65	0.047	1.640	0.240	0.160	0.085	11.34	8.71	2.80	0.09	72.89	0.12	1.09
	LBY-04	42.5	28.06	3.760	1.87	1.07	35.33	0.032	1.220	0.150	0.460	0.097	12.69	9.63	2.73	0.06	72.46	0.07	1.11
	LBY-03	32.5	38.68	6.350	2.86	1.59	26.27	0.056	2.030	0.250	1.050	0.080	10.36	8.05	2.77	0.13	72.68	0.16	1.01
	LBY-02	17.5	48.24	5.910	3.09	1.62	20.58	0.120	1.680	0.310	1.320	0.081	13.88	10.41	2.93	0.15	72.71	0.19	1.07
	LBY-01	2.5	45.92	5.760	2.53	1.51	22.82	0.240	1.590	0.230	1.070	0.100	13.55	10.59	2.72	0.13	69.61	0.16	1.11

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表 4 北沟剖面常量元素含量及风化系数(%)

Table 4. Major element contents and weathering parameters of Beigou profile (%)

	样品号	厚度(cm)	SiO₂	Al₂O₃	TFe₂O₃	MgO	CaO	Na₂O	K₂O	TiO₂	P₂O₅	MnO	S/A	S/R	A/(NK)	A/(CNK)	CIA	残积系数	BA
豹皮灰岩	BG-19	689.50	0.69	0.130	0.100	2.34	53.14	0.006	0.048	0.014	0.005	0.007	9.02	6.05	2.10	0.00	-	-	-
	BG-18	679.50	0.32	0.031	0.058	1.38	54.53	0.004	0.016	0.011	0.002	0.006	17.55	8.00	1.29	0.00	-	-	-
	BG-17	674.50	0.55	0.130	0.100	1.52	54.25	0.004	0.031	0.014	0.002	0.007	7.19	4.83	3.23	0.00	-	-	-
	BG-16	665.50	0.70	0.071	0.100	1.66	53.91	0.005	0.033	0.016	0.000	0.008	16.76	8.83	1.61	0.00	-	-	-
	BG-15	652.00	0.82	0.097	0.130	2.34	53.01	0.006	0.043	0.011	0.000	0.009	14.37	7.75	1.72	0.00	-	-	-
	BG-14	642.50	0.37	0.130	0.190	7.02	47.43	0.008	0.046	0.011	0.002	0.016	4.84	2.50	2.06	0.00	-	-	-
	BG-13	632.50	4.76	0.071	0.400	18.00	31.80	0.011	0.030	0.008	0.007	0.029	113.97	24.82	1.40	0.00	-	-	-
	BG-12	622.00	1.63	0.110	0.750	19.08	31.90	0.006	0.042	0.014	0.014	0.055	25.19	4.71	1.98	0.00	-	-	-
	BG-11	613.50	3.27	0.930	0.890	19.10	30.12	0.016	0.380	0.068	0.032	0.035	5.98	3.71	2.12	0.02	-	-	-
风化板岩	BG-10	601.00	4.90	1.460	0.940	19.44	28.61	0.071	0.460	0.097	0.037	0.036	5.71	4.05	2.37	0.03	66.58	0.02	34.46
	BG-09	583.00	7.09	2.430	1.220	18.74	27.39	0.026	0.970	0.150	0.044	0.041	4.96	3.76	2.22	0.05	68.10	0.03	20.13
	BG-08	567.50	9.89	2.430	1.310	17.94	26.44	0.023	0.900	0.160	0.051	0.044	6.92	5.15	2.40	0.05	69.78	0.03	19.26
	BG-07	555.00	14.92	4.280	1.830	15.92	24.04	0.042	1.560	0.250	0.081	0.043	5.93	4.66	2.43	0.09	70.04	0.06	9.91
	BG-06	510.00	17.75	5.620	0.990	15.36	22.71	0.140	2.010	0.340	0.078	0.042	5.37	4.83	2.33	0.13	68.02	0.08	7.44
	BG-05	480.00	24.72	6.690	2.910	13.00	19.80	0.330	2.240	0.450	0.120	0.055	6.28	4.92	2.25	0.17	65.55	0.12	5.48
钙质板岩	BG-04	460.00	23.70	6.250	2.950	13.96	19.59	0.340	2.090	0.400	0.100	0.061	6.45	4.96	2.21	0.16	64.86	0.11	6.24
	BG-03	153.00	32.92	4.490	1.450	0.88	32.00	0.053	1.590	0.190	0.530	0.066	12.46	10.34	2.48	0.07	70.27	0.09	0.92
	BG-02	142.50	32.42	3.280	1.470	0.88	33.02	0.041	1.250	0.160	0.340	0.074	16.80	13.07	2.30	0.05	68.74	0.07	1.14
	BG-01	3.75	31.08	2.720	1.630	0.82	34.36	0.039	1.050	0.110	0.280	0.081	19.43	14.06	2.26	0.04	68.21	0.06	1.23
注：表 1~4中主量元素氧化物以百分含量(%)表示；CIA=[Al₂O₃/(Al₂O₃+CaO^+K₂O+Na₂O)]×100，n(CaO^)=n(CaO)-10/3·n(P₂O₅)；残积系数表达式为(Al₂O₃+Fe₂O₃)/(CaO+Na₂O+MgO)；BA=[(CaO^*+Na₂O+K₂O+MgO)/Al₂O₃]×100；受岩性影响“—”表示未求府君山组豹皮灰岩中的CIA、残积系数和BA值.

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表 5 景儿峪组与府君山组之间古风壳与现代风化壳风化系数统计表

Table 5. The statistic of weathering coefficient in paleo-regolith between Jingeryu and Fujunshan formations and modern regolith sections

剖面	CIA(%)		S/A		S/R		资料来源
剖面	范围	均值	范围	均值	范围	均值	资料来源
黄院Ⅰ	71.41~73.41	72.16	7.55~20.97	13.69	6.76~15.60	10.89	本文研究数据
黄院Ⅱ	70.00~70.54	70.77	9.14~18.68	12.43	7.57~15.58	10.04
龙宝峪	69.61~72.71	71.51	8.92~36.32	18.05	6.78~30.44	14.34
北沟	68.21	68.21	4.96~16.80	7.88	3.76~13.07	6.19
贵阳BY-Ⅱ	67.70~84.20	77.00	12.26~27.64	19.55	9.87~20.08	14.90	(Liu et al., 2013)
昆明石林	95.93~96.88	96.46	2.73~10.88	6.29	2.03~7.47	4.39	(张涛等，2017)
湖南吉首	58.13~76.75	69.81	3.64~5.73	4.15	3.02~5.33	3.47	(王世杰等，2002)

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