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    豫西济源盆地中生代泥岩地球化学特征对物源区的指示

    杨文涛 杜远生

    杨文涛, 杜远生, 2017. 豫西济源盆地中生代泥岩地球化学特征对物源区的指示. 地球科学, 42(1): 53-67. doi: 10.3799/dqkx.2017.004
    引用本文: 杨文涛, 杜远生, 2017. 豫西济源盆地中生代泥岩地球化学特征对物源区的指示. 地球科学, 42(1): 53-67. doi: 10.3799/dqkx.2017.004
    ang Wentao, Du Yuansheng, 2017. Geochemistry of Mudstones from Mesozoic Jiyuan Basin,West Henan: Implications for Provenance Analysis. Earth Science, 42(1): 53-67. doi: 10.3799/dqkx.2017.004
    Citation: ang Wentao, Du Yuansheng, 2017. Geochemistry of Mudstones from Mesozoic Jiyuan Basin,West Henan: Implications for Provenance Analysis. Earth Science, 42(1): 53-67. doi: 10.3799/dqkx.2017.004

    豫西济源盆地中生代泥岩地球化学特征对物源区的指示

    doi: 10.3799/dqkx.2017.004
    基金项目: 

    国家自然科学基金项目 41440016

    河南省基础与前沿技术研究计划项目 152300410211

    详细信息
      作者简介:

      杨文涛(1984-),男,讲师,博士,从事沉积地质学研究及相关教学工作.ORCID:0000-0002-8589-3850.E-Mail: ywtao125@163.com

    • 中图分类号: P588.22

    Geochemistry of Mudstones from Mesozoic Jiyuan Basin,West Henan: Implications for Provenance Analysis

    • 摘要: 秦岭造山带印支期造山作用控制着济源盆地的形成与演化,对盆地中沉积物物源进行研究,有利于恢复造山带造山-隆升的细节.通过对济源盆地中生代泥岩地球化学的系统分析,发现样品的CIA(化学风化指数)校正值在早-中三叠世、晚三叠世、早-中侏罗世和中侏罗世后期的平均值分别为68.5、76.4、86.0和73.7,这一演化特征可能反映其经历了古气候控制的化学风化过程.但是三叠纪样品CIA值明显过低,可能与源区活动的构造背景相关;ICV(成分变异指数)值显示沉积物具有初次沉积的特征,反映了源区早期发生过弧-陆碰撞或具备陆缘弧特征的克拉通基底隆升.而早-中侏罗世样品表现为高的CIA值,ICV值显示沉积物具有再循环特征,其初次沉积可能发生在弧后盆地中,后随造山带的隆升,被剥露再搬运而沉积下来.泥岩物源区构造环境判别结果显示,沉积物主要来自活动大陆边缘和被动大陆边缘,且含有较多大陆岛弧(陆缘弧)的信息.由此说明,中生代济源盆地盆缘构造活动经历了由克拉通基底隆升到造山带剥露的过程,这一过程与秦岭造山带印支期的造山作用密切相关.

       

    • 图  1  华北克拉通及邻区构造纲要图及济源盆地位置(a),济源地区地质简图(b)

      图a据Liu et al.(2013)略修改

      Fig.  1.  Tectonic sketch of the North China Craton and its adjacent regions(a),geological sketch of the Jiyuan basin(b)

      图  2  济源盆地中生代地层柱状简图

      Fig.  2.  Measured section from the Mesozoic Jiyuan basin

      图  3  济源盆地中生代泥岩微量元素华北南缘上地壳标准化图(a)和稀土元素球粒陨石标准化图(b)

      Fig.  3.  Southern North China upper crust-normalized spider diagram(a)of the Mesozoic sediments from Jiyuan basin,and Chondrite-normalized REE patterns(b)of the Mesozoic sediments from Jiyuan basin

      图  4  济源盆地中生代泥岩A-CN-K图解(a)和济源盆地中生代泥岩Th/Sc-Zr/Sc图解(b)

      华北南缘上地壳数据来自Gao et al.(1998)

      Fig.  4.  A-CN-K diagram(a)of the Mesozoic sediments from Jiyuan basin,and Th/Sc-Zr/Sc diagram(b)of the Mesozoic sediments from Jiyuan basin

      图  5  济源盆地中生代泥岩物源区K2O/Na2O-SiO2构造环境判别

      a.SiO2校正前;b.SiO2校正后

      Fig.  5.  K2O/Na2O-SiO2 diagram of the Mesozoic sediments from Jiyuan basin

      图  6  济源盆地中生代泥岩La-Th-Sc(a)、Th-Sc-Zr/10(b)及Th-Co-Zr/10(c)构造环境判别

      OIA.大洋岛弧;CIA.大陆岛弧;ACM.活动大陆边缘;PM.被动大陆边缘

      Fig.  6.  La-Th-Sc(a),Th-Sc-Zr/10(b)and Th-Co-Zr/10(c)diagrams of the Mesozoic sediments from Jiyuan basin

      表  1  济源盆地中生代泥岩主量元素分析结果(%)

      Table  1.   The major elements (%) of the Mesozoic sediments from the Jiyuan basin

      样品编号SiO2TiO2Al2O3Fe2O3MnOMgOCaONa2OK2OP2O5LOICIACIAcorrICV
      Tl-h262.930.5910.383.350.082.927.731.761.360.129.1358.859.8 1.71
      Th-h453.170.7113.666.240.102.968.751.122.960.1710.4566.472.9 1.67
      Th-h354.640.6211.234.800.102.4111.021.332.300.1211.7162.066.8 2.01
      Th-h253.420.6211.234.800.082.3311.811.142.300.1312.4964.369.5 2.06
      Th-h156.250.6410.964.620.102.4710.491.482.150.1310.9760.364.3 2.00
      Te-h453.500.7416.197.700.063.794.571.314.130.228.1064.873.1 1.38
      Te-h356.400.8817.138.670.053.891.521.984.300.265.1463.070.4 1.24
      Te-h258.620.7315.226.740.073.223.832.703.480.235.4554.658.8 1.36
      Te-h156.390.7715.727.530.083.553.922.214.000.215.8857.563.6 1.40
      Ty-h453.190.7617.277.330.053.584.171.023.360.209.4271.277.3 1.17
      Ty-h356.400.7716.276.960.043.383.601.603.280.217.7364.870.0 1.21
      Ty-h258.740.7316.117.200.053.102.811.793.800.245.6861.767.9 1.21
      Ty-h160.060.7516.336.690.042.901.631.643.010.257.0166.270.7 1.02
      Tc-h218.200.235.273.351.510.7637.080.311.200.1132.2669.477.4 8.43
      Tc-h357.500.8417.656.830.032.861.711.243.900.237.4568.075.1 0.99
      Tc-h152.300.6013.274.750.122.2610.350.682.760.1313.0471.779.0 1.62
      Tc-h544.050.6912.725.060.041.8016.140.052.600.1317.0081.090.6 2.07
      Tt-h147.060.595.322.130.063.6819.380.321.120.1020.3170.177.1 5.13
      Tt-147.250.6611.584.330.073.5613.320.302.460.1616.0875.984.7 2.13
      Tt-250.810.6713.655.830.093.638.650.782.650.1712.8371.477.7 1.63
      Tt-342.890.8112.786.230.065.0411.960.353.000.1616.3774.484.6 2.15
      Ja-h255.180.627.083.430.053.7413.020.641.440.1114.9765.971.4 3.24
      Ja-h948.440.7614.366.270.032.0011.470.183.090.1413.6078.488.3 1.66
      Ja-h1052.500.7917.736.890.042.345.800.153.890.1510.0179.089.4 1.12
      Ja-h1459.111.0120.275.670.011.770.710.104.130.147.3980.890.3 0.66
      Ja-152.081.0219.247.640.032.793.980.194.400.168.0978.189.0 1.04
      Ja-260.141.0518.696.810.032.010.980.213.380.176.3081.188.6 0.77
      Jy-h152.430.9622.407.360.031.941.140.474.080.239.3078.986.1 0.71
      Jy-h254.871.2120.817.020.021.811.220.693.800.268.5376.583.1 0.76
      Jy-164.140.8016.886.240.041.281.101.432.520.235.1272.175.5 0.79
      Jm-138.870.5110.684.890.142.4519.700.373.070.4118.7270.182.7 2.91
      Jm-267.420.7113.523.550.031.792.761.053.330.115.5465.773.7 0.98
      下载: 导出CSV

      表  2  济源盆地中生代泥岩微量元素分析结果(10-6)

      Table  2.   The trace elements (10-6) of the Mesozoic sediments from the Jiyuan basin

      样品编号ScVCrCoNiCuZnGaRbSrYZrNbCsBaHfTaPbThU
      T1-h28.456.138.820.919.012.854.713.668.1105.024.9236.013.04.4166.06.41.012.414.92.9
      Th-h111.376.558.017.628.028.853.813.389.7133.024.9192.013.34.7495.05.11.019.311.62.7
      Th-h211.174.454.315.828.029.256.014.399.5128.025.3170.012.95.5227.04.60.918.611.62.8
      Th-h311.468.660.516.629.328.856.814.097.5134.024.4172.013.25.4768.04.60.919.510.82.4
      Th-h414.595.678.620.639.032.168.517.1121.0118.028.4178.014.36.6475.04.81.022.712.72.8
      Te-h115.1110.088.224.145.944.5104.021.7156.0223.021.6125.013.57.7537.03.40.932.811.72.3
      Te-h213.081.785.821.740.037.088.720.9125.0276.020.1180.013.05.2565.04.80.826.210.01.9
      Te-h317.0111.0103.023.051.047.1112.024.7170.0204.021.0165.016.18.5559.04.31.034.813.62.3
      Te-h415.2106.080.419.041.842.5106.022.7171.0153.026.8130.015.09.7396.03.51.033.714.02.8
      Ty-h113.293.879.419.238.147.495.022.4109.0172.018.9208.013.95.4744.05.30.928.411.51.8
      Ty-h213.395.773.820.735.637.492.822.1150.0185.025.4155.015.08.2666.04.21.030.512.72.8
      Ty-h314.193.271.115.534.345.7100.022.3126.0194.025.6150.015.75.7576.04.01.129.315.42.8
      Ty-h415.2100.073.415.237.751.4108.023.6130.0120.025.4121.015.86.7522.03.31.127.316.43.1
      Tc-h111.579.352.014.425.427.967.817.9112.0203.021.0166.012.76.2451.04.40.916.611.92.2
      Tc-h24.929.323.911.615.512.326.37.653.7229.034.550.65.12.4179.01.40.46.75.21.2
      Tc-h315.5104.088.316.740.750.0104.026.3161.0157.026.0195.016.57.4796.05.21.125.015.32.6
      Tc-h512.796.365.016.030.930.060.816.7105.090.126.1144.014.36.1369.03.81.015.311.82.4
      Tt-h16.240.224.918.513.16.1832.36.943.6256.020.1287.010.41.6164.07.30.810.610.12.0
      Tt-19.142.938.414.529.029.063.014.6110.0193.020.4163.014.68.4276.04.23.027.214.92.0
      Tt-28.650.149.215.429.034.870.715.898.6160.019.9148.013.47.5347.03.91.129.612.32.7
      Tt-310.156.347.717.032.636.269.214.6111.0150.025.4177.015.66.7315.04.61.225.711.61.8
      Ja-h27.853.834.521.717.69.3442.29.055.4146.022.0277.010.92.3199.07.00.811.79.71.9
      Ja-h915.1110.065.618.532.633.880.819.4140.0159.026.9159.015.47.7420.04.31.119.914.22.7
      Ja-h1016.6127.077.516.032.532.476.123.1172.096.725.7153.016.09.3524.04.21.215.715.62.8
      Ja-h1420.6121.0105.022.461.831.790.628.8182.055.345.8236.021.319.4696.06.31.49.120.33.3
      Ta-112.985.070.617.040.151.489.522.2168.0112.034.9190.019.211.2432.04.61.519.716.02.8
      Ta-212.970.084.618.152.251.984.620.9126.074.237.3219.019.611.8532.05.61.120.814.33.2
      Jy-h220.9147.0112.014.233.017.676.430.3148.0139.042.1269.020.49.2438.07.61.519.118.85.2
      Jy-h121.5158.095.211.934.125.780.032.6160.0139.042.9238.017.09.9481.06.91.219.516.34.3
      Jy-18.250.940.29.728.529.465.215.975.6121.030.2202.014.05.0364.04.80.921.08.82.4
      Jm-16.846.146.016.142.834.064.213.284.1312.012.595.611.29.7441.02.50.726.39.62.8
      Jm-26.655.141.611.330.826.453.214.2116.685.818.5200.013.711.1321.05.00.813.59.21.8
      下载: 导出CSV

      表  3  济源盆地中生代泥岩稀土元素分析结果(10-6)

      Table  3.   The rare earth elements (10-6) of the Mesozoic sediments from the Jiyuan basin

      样品编号LaCePrNdSmEuGdTbDyHoErTmYbLu∑REELREE/HREELa /Yb(La /Yb)NδEu
      T1-h238.373.28.532.15.91.05.50.84.60.92.50.32.20.3176.19.317.311.70.5
      Th-h133.569.78.030.66.11.25.50.84.60.92.40.32.30.4166.38.714.69.80.6
      Th-h231.564.47.628.85.71.15.20.84.70.92.60.42.30.3156.28.113.59.10.6
      Th-h330.665.47.529.25.71.35.20.84.50.92.40.32.30.3156.38.413.59.10.7
      Th-h440.776.88.833.86.61.36.10.95.31.02.80.42.70.4187.58.615.410.40.6
      Te-h142.279.59.034.06.01.35.30.74.00.82.20.32.10.3187.711.019.913.40.7
      Te-h243.479.89.334.65.91.35.00.73.80.72.10.32.10.3189.311.620.914.10.7
      Te-h343.685.49.735.76.31.45.10.84.10.82.30.42.40.4198.111.317.912.10.7
      Te-h447.186.310.238.37.01.46.00.94.80.92.70.42.40.4208.710.319.413.10.6
      Ty-h141.977.710.037.96.61.45.00.73.40.72.10.32.10.3190.112.019.913.40.7
      Ty-h246.686.410.038.77.11.56.00.94.70.92.50.42.30.4208.210.620.413.70.7
      Ty-h341.968.69.134.46.41.45.70.94.70.92.60.42.40.4179.79.117.812.00.7
      Ty-h444.868.89.636.06.61.45.70.94.70.92.60.42.40.4185.09.418.912.70.7
      Tc-h131.062.17.126.54.91.04.40.73.50.82.10.32.10.3146.89.415.010.10.7
      Tc-h272.946.911.138.76.11.05.50.84.70.92.40.31.80.3193.510.539.626.70.5
      Tc-h333.260.78.733.66.41.45.50.84.50.92.70.42.80.4162.08.012.08.10.7
      Tc-h533.668.07.929.75.61.15.30.84.60.92.60.42.50.4163.48.313.39.00.6
      Tt-h132.765.07.627.95.10.84.50.73.50.71.90.31.80.3152.610.318.112.20.5
      Tt-135.775.48.936.05.91.15.80.84.70.82.40.32.30.4180.59.315.810.70.6
      Tt-234.274.88.935.76.11.25.60.84.70.82.60.42.50.4178.79.013.69.20.6
      Tt-338.283.29.840.36.81.46.90.95.91.13.20.53.10.5201.78.212.48.40.6
      Ja-h231.163.97.428.15.30.94.70.73.90.82.20.32.00.3151.79.215.510.40.6
      Ja-h933.266.87.929.55.71.15.20.84.81.02.80.42.80.4162.47.912.08.10.6
      Ja-h1039.472.38.230.55.61.15.10.84.60.92.80.42.80.4174.98.814.09.40.6
      Ja-h1457.099.511.642.87.61.57.01.16.91.44.20.64.10.6246.08.513.99.40.6
      Ja-150.4110.012.751.48.51.88.51.28.01.54.60.74.40.8264.47.911.57.70.6
      Ja-251.8119.013.856.910.12.29.81.48.51.64.60.74.20.6285.08.112.28.20.7
      Jy-h271.6125.013.044.76.91.36.51.06.01.34.30.74.60.7287.610.415.510.40.6
      Jy-h159.5105.011.642.16.91.46.51.06.41.44.20.74.40.7251.89.013.59.10.6
      Jy-139.593.611.247.18.21.87.81.17.01.33.80.53.50.7227.07.911.47.70.7
      Jm-124.349.56.023.53.80.83.70.52.80.51.50.21.50.3118.89.816.611.20.7
      Jm-230.870.68.434.46.01.25.50.84.70.92.50.42.40.4168.98.712.88.70.6
      下载: 导出CSV

      表  4  4阶段样品与不同构造环境杂砂岩稀土元素特征参数的对比

      Table  4.   Compared the REE values of four stages with the data from different tectonic settings

      构造背景LaCe∑REELREE/HREELa/Yb(La/Yb)NEu/Eu*
      大洋岛弧8±1.719±3.758±103.8±0.94.2±1.32.8±0.91.04±0.11
      大陆岛弧27±4.559±8.2146±207.7±1.711±3.67.5±2.50.79±0.13
      活动大陆边缘37781869.112.58.50.60
      被动大陆边缘39852108.515.910.80.56
      T1+241 34*76 63*184 153*9.8817.6411.890.67
      T339 33*67 56*172 143*9.1317.489.650.61
      J1-248 40*95 79*228 190*8.6313.268.940.62
      J228 23*60 50*144 120*9.2614.749.940.66
      注:大洋、大陆岛弧以及活动、被动大陆边缘数据据Bhatia(1985);其他为本文值,其中*为校正值.
      下载: 导出CSV
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    • 收稿日期:  2016-07-02
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