江南中段慈化地区新元古代高镁安山岩的厘定及其构造意义

张玉芝; 王岳军; 郭小飞; 甘成势; 邢晓婉; 宋菁菁

doi:10.3799/dqkx.2015.159

江南中段慈化地区新元古代高镁安山岩的厘定及其构造意义

doi: 10.3799/dqkx.2015.159

张玉芝^{1, 2,},
王岳军^{2, 3},
郭小飞^{1, 2},
甘成势^{1, 2},
邢晓婉^{1, 2},
宋菁菁^{1, 2}

1.
中国科学院广州地球化学研究所同位素地球化学国家重点实验室, 广东广州 510640
2.
中山大学地球科学与地质工程学院, 广东广州 510275
3.
广东省地质过程与矿产资源探查重点实验室, 广东广州 510275

基金项目:

国家重点基础研究发展计划(973计划)项目 2014CB440901

国家自然科学基金项目 41402165

国家自然科学基金项目 41372198

国家自然科学基金项目 41190073

详细信息

作者简介:
张玉芝(1984-), 女, 助理研究员, 主要从事岩石大地构造研究.E-mail: zhangyz@gig.ac.cn

中图分类号: P59
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- 被引次数: 0
出版历程
- 收稿日期: 2015-02-09
- 刊出日期: 2015-11-15

Geochronology and Geochemistry of Cihua Neoproterozoic High-Mg Andesites in Jiangnan Orogen and Their Tectonic Implications

Zhang Yuzhi^{1, 2
,},
Wang Yuejun^{2, 3},
Guo Xiaofei^{1, 2},
Gan Chengshi^{1, 2},
Xing Xiaowan^{1, 2},
Song Jingjing^{1, 2}

1.
State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
2.
School of Earth Science and Geological Engineering, Sun Yat-Sen University, Guangzhou 510275, China
3.
Guangdong Provincial Key Lab of Geological Processes and Mineral Resource Survey, Guangzhou 510275, China

摘要

摘要: 江南造山带被普遍认为是扬子与华夏陆块在新元古代的拼合带, 其拼合机制及精细时代却一直备受争议.在江南造山带中段湘赣交界慈化地区识别出新元古代火山岩, 并对其进行了锆石U-Pb年代学及主微量地球化学研究.该火山岩发育于冷家溪群地层中, 其锆石LA-ICP-MS年代学测试得到了832±12 Ma的²⁰⁶Pb/²³⁸U加权平均年龄(n=16, MSWD=0.12), 代表其喷发年龄.主量元素结果显示, SiO₂和MgO含量分别为57.67%~61.33%和3.51%~4.29%, Mg^#为52~57, 高于正常弧火山岩, 属高镁安山岩.微量元素富集轻稀土元素和大离子亲石元素, 亏损高场强元素, 其Nb-Ta、Ti亏损, 具"弧型"地球化学特征, 可能来源于受板片熔体/流体或者俯冲再循环沉积物交代的难熔地幔源区.上述资料表明, 慈化高镁安山岩是江南造山带中段楔形地幔源区受消减组分交代作用的产物, 暗示此时江南造山带中段仍在消减, 扬子和华夏陆块尚未完全拼合.结合前人研究成果, 江南造山带不同区段的闭合时间可能存在差异.
- 慈化高镁安山岩 /
- 锆石U-Pb定年 /
- 新元古代俯冲作用 /
- 江南中段 /
- 地球化学.
Abstract: It is generally accepted that the Jiangnan orogenic belt led to the amalgamation of the Yangtze with Cathaysia blocks during the Neoproterozoic period. However, its tectonic evolution and amalgamation timing are still in debate. This paper presents a set of new geochronological and geochemical data for the newly-identified Neoproterozoic high-Mg volcanics from Cihua (Jiangxi). LA-ICP-MS zircon U-Pb dating of the representative sample yields a weighted mean age of 832±12 Ma (n=16, MSWD=0.12), representing the eruption age of the andesite. Geochemical results indicate that they can be classified as high-Mg andesites with SiO₂ ranging from 57.67% to 61.33%, MgO from 3.51% to 4.29% and Mg-number from 52 to 57. Their chondrite-normalized REE patterns exhibit a left-sloping pattern with enriched LREEs relative to HREEs. On the primitive mantle-normalized multi-element patterns, these samples have strong enrichment in LILE and depletion in HFSE with marked negative Nb-Ta, Ti and positive Th anomalies, similar to those of the typical arc volcanics. The generation of the volcanic rocks might have been attributed to an interaction of the subducted melt/fluid or sediment with the overlying refractory mantle, suggesting the central Jiangnan orogen was still on the subduction till ~832 Ma. It is concluded that the Jiangnan orogen consists of several branches with distinct amalgamation evolution.
- Cihua high-Mg andesite /
- zircon U-Pb dating /
- Neoproterozoic subduction /
- central Jiangnan orogen /
- geochemistry.

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图 1 湘东北-赣西北地区地质概况及采样点位置

图1改编自Zhang et al., 2013

Fig. 1. NE Hunan and NW Jiangxi provinces with the sampling location

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图 2 慈化高镁安山岩样品LA-ICP-MS锆石U-Pb年龄谐和图和阴极发光图像(CL)

Fig. 2. Concordia diagrams of zircon U-Pb data for the Cihua high-Mg andesitic sample

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图 3 慈化高镁安山岩样品SiO₂-K₂O+Na₂O (a)和SiO₂-Mg-number (b)关系

Fig. 3. Relation of SiO₂-K₂O+Na₂O (a) and SiO₂-Mg-number (b) for the Cihua high-Mg andesite in NW Jiangxi Province

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图 4 慈化高镁安山岩球粒陨石标准化稀土元素配分图(a)和原始地幔标准化微量元素蛛网图(b)

球粒陨石和原始地幔标准化数据分别引自文献Taylor and McLennan(1985)和Sun and McDonough(1989)

Fig. 4. The patterns of the chondrite-normalized rare-earth elements (a) and primitive mantle-normalized spidergram (b) for the Cihua high-Mg andesite in NW Jiangxi Province

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图 5 慈化高镁安山岩样品Cr-Ni关系

Fig. 5. Plot of Cr vs. Ni for the Cihua high-Mg andesite in NW Jiangxi Province

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图 6 慈化高镁安山岩与文家市-芳溪N-MORB岩石球粒陨石标准化稀土元素配分图(a)和原始地幔标准化微量元素蛛网图(b)

b.数据来自Zhang et al., 2013

Fig. 6. The chondrite-normalized rare-earth elements (a) and primitive mantle-normalized spidergram (b) of the Cihua high-Mg andesite and Wenjiashi-Fangxi N-MORB

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表 1 慈化高镁安山岩样品LA- ICP-MS锆石U-Pb分析结果

Table 1. Table 1 LA-ICP-MS zircon U-Pb dating results for the Cihua high-Mg andesite

分析点	Th/U	²⁰⁷Pb/²⁰⁶U		²⁰⁷Pb/²³⁵U		²⁰⁶Pb/²³⁸U		²⁰⁷Pb/²⁰⁶U		²⁰⁷Pb/²³⁵U		²⁰⁶Pb/²³⁸U
分析点	Th/U	比值	±1σ	比值	±1σ	比值	±1σ	年龄(Ma)	±1σ	年龄(Ma)	±1σ	年龄(Ma)	±1σ
12WS-79A-01	0.13	0.067 7	0.002 0	1.289 1	0.039 6	0.138 2	0.004 2	859	63	834	24	841	18
12WS-79A-02	0.47	0.112 3	0.003 4	5.156 5	0.156 9	0.332 9	0.010 1	1 839	54	1 852	49	1 845	26
12WS-79A-03	0.59	0.067 9	0.002 0	1.285 7	0.039 7	0.137 2	0.004 2	878	36	829	24	839	18
12WS-79A-04	1.18	0.159 5	0.004 8	9.952 4	0.308 7	0.452 5	0.014 0	2 450	51	2 406	62	2 430	29
12WS-79A-05	0.33	0.067 0	0.002 0	1.273 2	0.042 9	0.137 3	0.004 6	839	63	829	26	834	19
12WS-79A-06	0.98	0.079 3	0.002 4	2.240 3	0.069 4	0.204 9	0.006 3	1 189	60	1 202	34	1 194	22
12WS-79A-07	0.24	0.116 9	0.003 5	5.402 9	0.165 2	0.335 2	0.010 3	1 910	54	1 864	49	1 885	26
12WS-79A-08	0.28	0.067 7	0.002 0	1.278 0	0.039 4	0.136 9	0.004 2	861	63	827	24	836	18
12WS-79A-09	0.33	0.069 2	0.002 1	1.314 7	0.040 5	0.137 8	0.004 2	906	61	832	24	852	18
12WS-79A-10	0.27	0.068 2	0.002 1	1.293 8	0.040 1	0.137 4	0.004 2	876	62	830	24	843	18
12WS-79A-11	0.36	0.068 6	0.002 1	1.303 7	0.040 0	0.137 8	0.004 2	887	56	832	24	847	18
12WS-79A-12	0.57	0.098 0	0.002 9	3.734 6	0.114 5	0.276 2	0.008 5	1 587	56	1 572	43	1 579	25
12WS-79A-13	0.12	0.067 0	0.002 0	1.270 7	0.039 0	0.137 6	0.004 2	839	63	831	24	833	17
12WS-79A-14	0.38	0.067 3	0.002 0	1.282 3	0.039 2	0.138 1	0.004 2	856	63	834	24	838	17
12WS-79A-15	0.44	0.067 4	0.002 0	1.281 4	0.039 4	0.137 8	0.004 2	850	68	832	24	837	18
12WS-79A-16	0.60	0.112 8	0.003 4	5.166 7	0.159 0	0.332 2	0.010 2	1 844	54	1 849	49	1 847	26
12WS-79A-17	0.27	0.066 8	0.002 0	1.276 6	0.039 6	0.138 5	0.004 3	831	63	836	24	835	18
12WS-79A-18	0.18	0.066 6	0.002 0	1.260 5	0.038 5	0.137 2	0.004 2	833	63	829	24	828	17
12WS-79A-19	0.35	0.067 1	0.002 0	1.276 9	0.039 2	0.137 9	0.004 2	843	62	833	24	835	17
12WS-79A-20	0.61	0.067 0	0.002 0	1.276 7	0.039 3	0.138 2	0.004 2	839	63	834	24	835	18
12WS-79A-21	0.23	0.067 8	0.002 0	1.295 2	0.039 8	0.138 6	0.004 2	861	63	837	24	844	18
12WS-79A-22	0.55	0.111 8	0.003 4	5.126 7	0.156 5	0.332 6	0.010 1	1 829	55	1 851	49	1 841	26
12WS-79A-23	0.26	0.067 0	0.002 0	1.272 5	0.039 2	0.137 8	0.004 2	837	63	832	24	833	18
12WS-79A-24	0.51	0.114 0	0.003 4	5.214 4	0.159 4	0.331 5	0.010 1	1 865	54	1 846	49	1 855	26
12WS-79A-25	0.12	0.124 0	0.003 7	6.275 6	0.192 6	0.367 1	0.011 3	2 015	53	2 016	53	2 015	27
12WS-79A-26	0.35	0.067 7	0.002 0	1.285 0	0.039 4	0.137 7	0.004 2	857	63	831	24	839	18
12WS-79A-27	1.05	0.104 8	0.003 2	4.369 4	0.133 9	0.302 2	0.009 2	1 722	56	1 702	46	1 707	25
12WS-79A-28	0.52	0.113 8	0.003 6	5.120 1	0.188 5	0.325 9	0.011 4	1 861	57	1 819	55	1 839	31
12WS-79A-29	0.59	0.154 2	0.004 6	9.340 4	0.286 5	0.439 1	0.013 5	2 394	50	2 347	60	2 372	28
12WS-79A-30	0.48	0.113 3	0.003 4	5.219 6	0.160 4	0.333 9	0.010 2	1 853	54	1 857	50	1 856	26

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表 2 慈化高镁安山岩主量(%)和微量元素(10^-6)分析结果

Table 2. Major (%) and trace element (10^-6) analytical results for the Cihua high-Mg andesite

样品号	12WS-79A	12WS-79B	12WS-79C	12WS-79D	12WS-79E
SiO₂	57.03	59.67	55.89	56.71	59.78
Al₂O₃	19.46	16.78	19.96	18.76	18.10
CaO	2.76	3.25	3.02	4.63	3.10
FeO^t	6.19	6.59	6.47	6.83	6.93
MgO	4.05	3.61	3.78	3.48	3.35
MnO	3.92	3.72	4.16	3.51	3.43
K₂O	0.07	0.10	0.08	0.11	0.09
Na₂O	1.76	1.41	1.63	1.72	1.47
P₂O₅	0.14	0.15	0.12	0.13	0.14
TiO₂	0.91	1.02	0.96	1.09	0.86
Loi	2.49	2.24	2.48	2.03	1.86
Total	99.47	99.54	99.40	99.37	99.49
Mg^#	57.1	53.3	57.0	53.2	52.2
Sc	22.8	23.0	24.3	14.2	16.1
V	163	176	214	110	140
Cr	109.0	91.6	102	54.9	75.1
Co	18.2	18.2	19.5	17.3	19.8
Ni	39.3	39.8	40.4	34.1	36.3
Rb	189	201	180	182	173
Sr	107.0	149.0	136.0	62.0	73.7
Y	35.7	38.4	39.2	26.7	28.9
Zr	196	262	265	194	212
Nb	15.4	17.7	18.0	13.1	14.4
Ba	1 123	402	371	355	354
La	42.5	59.0	59.7	35.8	36.0
Ce	89.3	118.0	121.0	73.8	71.7
Pr	11.10	14.90	14.80	9.25	8.80
Nd	39.4	53.1	55.2	32.8	33.5
Sm	8.13	10.20	10.00	6.40	6.25
Eu	1.97	2.37	2.28	1.04	0.98
Gd	7.22	8.06	8.34	5.61	5.89
Tb	1.14	1.30	1.30	0.90	0.91
Dy	6.62	7.24	7.48	5.27	5.52
Ho	1.40	1.55	1.56	1.14	1.16
Er	3.79	4.19	4.37	3.03	3.11
Tm	0.58	0.62	0.65	0.46	0.48
Yb	3.92	4.12	4.40	2.99	3.18
Lu	0.59	0.62	0.69	0.44	0.49
Hf	5.97	7.82	6.98	6.07	5.56
Ta	1.33	1.57	1.64	1.15	1.21
Pb	26.1	30.0	29.6	15.9	15.4
Th	19.4	23.7	22.5	14.4	13.8
U	3.85	4.74	4.79	3.04	3.05

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