全吉群碎屑锆石的U-Pb年龄谱和微量元素：基底热事件信息和早期演化启示

张璐; 巴金; 陈能松; 王勤燕; 廖梵汐; 李晓彦

doi:10.3799/dqkx.2012.S1.004

全吉群碎屑锆石的U-Pb年龄谱和微量元素：基底热事件信息和早期演化启示

doi: 10.3799/dqkx.2012.S1.004

张璐^{1, 2},
巴金^{1, 2},
陈能松^{1, 3, ,},
王勤燕¹,
廖梵汐^{1, 2},
李晓彦⁴

1.
中国地质大学地球科学学院，湖北武汉 430074
2.
中国地质大学研究生院，湖北武汉 430074
3.
中国地质大学地质过程与矿产资源国家重点实验室，湖北武汉 430074
4.
德国弗莱堡大学矿物与地球科学学院，弗莱堡 79104

基金项目:

国家自然科学基金 40972042

国家自然科学基金 40772041

详细信息

作者简介:
张璐(1987-)，女，博士研究生，岩石学专业

通讯作者:
陈能松，E-mail: nengsongchen@cug.edu.cn

中图分类号: P597.3
计量
- 文章访问数: 229
- HTML全文浏览量: 144
- PDF下载量: 3
- 被引次数: 0
出版历程
- 收稿日期: 2011-09-03
- 网络出版日期: 2021-11-15
- 刊出日期: 2012-05-01

U-Pb Age Spectra and Trace Elements of Detrital Zircon from Quanji Group: Implications for Thermal Events and Early Evolution in the Basement

ZHANG Lu^{1, 2},
BA Jin^{1, 2},
CHEN Neng-song^{1, 3
, ,},
WANG Qin-yan¹,
LIAO Fan-xi^{1, 2},
LI Xiao-yan⁴

1.
Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2.
Graduate School, China University of Geosciences, Wuhan 430074, China
3.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China
4.
Institute of Geoscience Mineralogy and Geochemistry, University of Freiburg, Freiburg 79104, Germany

摘要

摘要: 本研究应用LA-ICP-MS测定了从塔里木陆块离解出来的一个大陆碎块(片)，即全吉地块盖层全吉群下部南华纪石英砂岩中碎屑锆石的111个测点的U-Pb年龄和微量元素组成.87个谐和年龄构成的锆石年龄谱记录了强烈的古元古代~2.45、~2.32、~2.11和~1.95 Ga热事件以及微弱的太古代热事件信息，指示南华纪石英砂岩的物源可能是来自全吉地块中、东部的由达肯大坂岩群和未剥露到古元古代末基性岩墙群的德令哈杂岩组成的基底岩系.碎屑锆石的CL图像和微量元素组成表明，~2.45、~2.32和~2.11 Ga热事件的性质主体为岩浆侵入活动并可能伴随地壳生长；~1.95 Ga热事件主要为变质-深熔作用，但不排除存在岩浆侵入的可能性.本研究结果表明，全吉地块和其塔里木母陆块基底主要由古元古代岩石组成，发育区域性古元古代早-中期(~2.32~2.45 Ga)的岩浆侵入作用和地壳生长，与华北陆块具有相似的地质演化历史或可能发生过构造互动.
- 碎屑锆石年龄谱 /
- 微量元素 /
- 全吉地块 /
- 塔里木陆块 /
- 热事件 /
- 地壳演化 /
- 岩石学
Abstract: LA-ICP-MS U-Pb age and trace elements composition have been conducted from 111 spots analyses on detrital zircons from the sandstone of the lower Nanhua-Sinian Quanji Group, the unmetamorphosed sedimentary cover on the Quanji massif (a continental fragment separated from the Tarim block). The age spectra from 87 concordant ages records strong ~2.45, ~2.32, ~2.11 and ~1.95 Ga thermal events in the Paleoproterozoic and two weak thermal events in the Neoarchean time, and indicates that sediments of quartzo-sandstone were derived from the basement comprising of the Dakendaban Group and Delingha complex with unexposed Ended-Paleoproterozoic mafic dike swarm in the middle to eastern Quanji massif. CL images and trace elements of the detrital zircons suggest that the ~2.45, ~2.32 and ~2.11 Ga thermal events are characterized by magmatic intrusion along with crustal growth and the ~1.95 Ga event by strong regional metamorphism and anatexis, with magmatic intrusion a possible event that could not be ruled out. Our new data demonstrate that basement of the Quanji massif and its inherited Tarim craton are mainly composed of Paleoproterozoic rocks, however, they regionally developed magmatic intrusions accompanying crustal growth during ~2.32-2.45 Ga, thus share a similar geological evolution history or probably ever interacted with the North China craton in their early history.
- detrital zircon age spectra /
- trace elements /
- Quanji massif /
- Tarim block /
- thermal events /
- crustal evolution /
- petrology

HTML全文

图 1 全吉地块及其邻区构造位置

(据Xu et al., 2006修改)

Fig. 1. Tectonic position of the Quanji block and adjacent tectonic units

下载: 全尺寸图片幻灯片

图 2 碎屑锆石U-Pb年龄谐和图(a)和锆石U-Pb年龄概率分布直方图(b)

Fig. 2. U-Pb concordia plots of concordant detrital zircons (a) and relative probability plots of U-Pb ages for concordant detrital zircons (b)

下载: 全尺寸图片幻灯片

图 3 锆石U-Pb年龄与Th/U比值关系(a)和锆石REE球粒陨石标准化分配模式(b)

Fig. 3. Diagram showing relationship between Th/U ratios and U-Pb ages for detrital zircons (a) and chondrite-normalized REE patterns of zircon grains (b)

下载: 全尺寸图片幻灯片

图 4 锆石分类回归判别树(Belousova et al., 2002) (a)和锆石成分判别岩石类型(b)

K.金伯利岩; B.玄武岩; D.辉绿岩; C.碳酸岩; N.碱性正长岩和正长伟晶岩(Ne-S/SP); S.正长岩; S/M.正长岩/二长岩; G1.花岗岩类(＜65% SiO₂); G2.花岗岩类(70%~75% SiO₂); G3.花岗岩类(＞75% SiO₂)

Fig. 4. "Short" classification and regression trees for the recognition of zircons from different rock types (a) and relative of rock types derived from zircon compositions (b)

下载: 全尺寸图片幻灯片

图 5 锆石阴极发光图及²⁰⁷Pb/²⁰⁶Pb年龄

Fig. 5. CL images of the zircons and ²⁰⁷Pb/²⁰⁶Pb age

下载: 全尺寸图片幻灯片

表 1 碎屑锆石U-Pb同位素数据

Table 1. U-Pb isotopic data for detrital zircons

分析点号	浓度(10^-6)			²³²Th/²³⁸U	同位素比值						谐和度	年龄(Ma)						成因	类型
分析点号	Pb	²³²Th	²³⁸U	²³²Th/²³⁸U	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ	谐和度	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ	成因	类型
1	197.8	124.9	544.3	0.23	0.135 7	0.002 7	6.596 2	0.140 5	0.350 6	0.003 2	112	2 173	34	2 059	19	1 937	16	M
2	47.3	117.4	104.2	1.13	0.124 0	0.002 4	6.254 3	0.120 5	0.364 3	0.002 8	101	2 017	35	2 012	17	2 003	13	G	D
3	36.2	93.8	81.6	1.15	0.123 2	0.002 6	6.060 3	0.125 4	0.355 7	0.003 1	102	2 003	37	1 985	18	1 962	15	M
4	129.3	321.7	381.3	0.84	0.138 8	0.002 3	5.577 8	0.093 4	0.290 0	0.002 0	135	2 213	30	1 913	14	1 641	10	G	D
5	73.9	105.7	155.0	0.68	0.144 6	0.002 6	8.381 2	0.151 5	0.418 0	0.002 9	101	2 284	31	2 273	16	2 252	13	G	D
6	98.9	107.9	199.2	0.54	0.154 5	0.003 1	9.586 0	0.193 6	0.447 4	0.003 8	101	2 396	34	2 396	19	2 384	17	G	G1
7	99.0	94.0	247.1	0.38	0.131 0	0.002 6	6.970 3	0.137 2	0.383 7	0.003 1	101	2 122	35	2 108	17	2 094	14	M
8	83.9	272.3	167.0	1.63	0.131 6	0.002 9	6.730 4	0.155 6	0.368 7	0.003 5	105	2 120	39	2 077	20	2 023	17	M
9	45.7	214.7	76.0	2.83	0.122 0	0.002 6	6.160 3	0.129 4	0.364 9	0.002 7	99	1 987	38	1 999	18	2 005	13	M
10	116.0	237.1	199.4	1.19	0.158 2	0.002 5	10.089 2	0.161 0	0.459 8	0.003 0	100	2 437	28	2 443	15	2 439	13	G	D
11	18.9	77.2	31.2	2.47	0.129 1	0.004 6	6.805 4	0.239 1	0.382 7	0.005 3	100	2 087	63	2 086	31	2 089	25	M
12	142.1	429.7	414.9	1.04	0.143 9	0.003 1	5.743 5	0.119 4	0.288 8	0.004 2	139	2 276	36	1 938	18	1 636	21	M
13	113.3	103.6	320.5	0.32	0.135 1	0.002 6	6.393 7	0.122 3	0.341 6	0.002 9	114	2 165	34	2 031	17	1 894	14	M
14	143.4	71.2	362.1	0.20	0.142 1	0.002 8	7.640 2	0.150 6	0.387 8	0.003 0	107	2 253	33	2 190	18	2 113	14	M
15	118.7	200.2	222.8	0.90	0.165 9	0.002 8	9.864 1	0.163 5	0.429 3	0.002 7	109	2 517	28	2 422	15	2 302	12	M
16	40.8	29.2	70.5	0.41	0.190 7	0.003 6	14.133 6	0.306 3	0.535 3	0.006 8	99	2 750	31	2 759	21	2 764	29	G	D
17	54.0	278.4	85.8	3.24	0.118 9	0.002 5	5.738 4	0.133 3	0.348 3	0.003 9	101	1 940	37	1 937	20	1 927	19	G	G1
18	24.7	91.4	30.9	2.96	0.159 2	0.006 2	10.235 9	0.386 9	0.466 3	0.004 8	99	2 447	71	2 456	35	2 467	21	M
19	170.1	119.4	383.0	0.31	0.144 6	0.002 6	8.428 5	0.155 5	0.421 1	0.002 8	101	2 283	31	2 278	17	2 266	13	G	G1
20	107.2	141.5	226.0	0.63	0.148 6	0.002 5	8.817 2	0.170 7	0.428 0	0.004 2	101	2 329	28	2 319	18	2 297	19	G	D
21	190.8	340.4	430.3	0.79	0.187 9	0.003 5	9.498 4	0.168 4	0.365 1	0.003 0	136	2 724	30	2 387	16	2 006	14	G	D
22	160.0	508.7	951.3	0.53	0.101 0	0.001 7	2.141 6	0.038 3	0.152 9	0.001 2	179	1 643	31	1 162	12	917	6	M
23	68.3	155.4	258.3	0.60	0.106 4	0.002 4	3.557 1	0.087 1	0.241 2	0.003 1	125	1 739	46	1 540	19	1 393	16	M
24	22.3	16.3	59.4	0.27	0.119 2	0.002 7	6.041 0	0.138 2	0.366 1	0.003 6	97	1 946	41	1 982	20	2 011	17	M
25	118.0	118.3	268.6	0.44	0.135 4	0.002 5	7.649 4	0.147 8	0.407 0	0.003 6	99	2 169	37	2 191	17	2 201	17	G	D
26	11.9	10.3	32.9	0.31	0.118 5	0.003 3	5.690 5	0.151 8	0.349 1	0.003 9	101	1 944	50	1 930	23	1 930	19	M
27	37.3	33.5	85.8	0.39	0.130 5	0.002 4	7.330 1	0.135 3	0.405 5	0.003 3	96	2 106	33	2 152	16	2 194	15	M
28	90.2	73.1	224.9	0.33	0.131 2	0.002 3	7.093 3	0.128 7	0.389 9	0.003 5	100	2 114	30	2 123	16	2 122	16	M
29	95.7	297.0	195.9	1.52	0.116 7	0.002 2	5.947 1	0.112 9	0.367 4	0.002 9	95	1 907	34	1 968	17	2 017	13	M
30	137.0	269.4	316.5	0.85	0.153 0	0.003 3	8.142 8	0.184 4	0.383 3	0.003 4	114	2 379	37	2 247	20	2 092	16	M
31	75.7	61.5	207.6	0.30	0.118 2	0.002 4	5.885 6	0.120 3	0.358 8	0.002 7	98	1 929	35	1 959	18	1 976	13	M
32	117.8	251.0	190.4	1.32	0.161 2	0.002 9	10.617 6	0.195 3	0.475 1	0.004 2	98	2 468	29	2 490	17	2 506	18	G	D
33	53.4	84.5	148.8	0.57	0.119 9	0.002 2	5.822 7	0.110 0	0.350 6	0.003 3	101	1 954	33	1 950	16	1 937	16	M
34	131.0	413.7	457.8	0.90	0.138 6	0.002 6	4.792 2	0.091 2	0.249 4	0.002 2	154	2 210	33	1 784	16	1 436	11	G	D
35	85.3	212.2	187.1	1.13	0.125 4	0.002 6	6.354 3	0.129 3	0.366 0	0.002 9	101	2 035	36	2 026	18	2 010	14	M
36	108.1	290.6	234.9	1.24	0.121 3	0.002 6	6.131 3	0.131 7	0.364 6	0.003 0	99	1 976	38	1 995	19	2 004	14	M
37	74.9	93.0	182.3	0.51	0.125 9	0.002 8	6.645 2	0.147 1	0.380 9	0.003 2	98	2 043	39	2 065	20	2 080	15	M
38	163.9	320.0	443.2	0.72	0.137 4	0.002 8	6.356 6	0.131 6	0.333 8	0.003 2	118	2 195	35	2 026	18	1 857	15	M
39	64.2	88.1	129.1	0.68	0.145 0	0.002 7	8.806 5	0.165 2	0.440 3	0.003 7	97	2 287	33	2 318	17	2 352	16	G	D
40	51.3	228.7	110.9	2.06	0.121 5	0.003 2	5.072 9	0.139 2	0.301 3	0.003 9	117	1 989	47	1 832	23	1 698	19	M
41	93.0	185.6	242.5	0.77	0.141 1	0.003 0	6.600 6	0.136 5	0.338 0	0.004 1	119	2 243	36	2 059	18	1 877	20	G	D
42	66.4	70.6	149.0	0.47	0.137 3	0.002 5	7.893 6	0.143 8	0.415 3	0.003 9	98	2 194	32	2 219	16	2 239	18	G	G1
43	94.1	241.0	206.8	1.17	0.116 5	0.002 1	5.960 0	0.107 6	0.369 2	0.003 5	94	1 906	32	1 970	16	2 025	16	M
44	140.9	374.1	703.6	0.53	0.109 6	0.001 8	2.867 2	0.047 7	0.188 8	0.001 7	161	1 792	29	1 373	13	1 115	9	G	G2
45	47.2	34.2	112.6	0.30	0.129 3	0.002 3	7.294 4	0.129 3	0.407 1	0.003 3	95	2 100	31	2 148	16	2 202	15	M
46	76.0	156.5	200.9	0.78	0.118 3	0.002 0	5.614 3	0.092 0	0.342 9	0.002 7	102	1 931	31	1 918	14	1 901	13	G	D
47	114.3	282.3	412.4	0.68	0.125 5	0.002 5	4.459 7	0.087 8	0.256 3	0.002 4	138	2 037	41	1 724	16	1 471	12	M
48	104.2	177.3	217.0	0.82	0.141 6	0.002 6	8.081 2	0.149 8	0.411 5	0.003 2	101	2 247	33	2 240	17	2 222	14	G	D
49	123.8	133.3	248.5	0.54	0.148 8	0.002 9	9.145 0	0.166 4	0.444 8	0.004 6	98	2 332	33	2 353	17	2 372	21	G	D
50	129.6	768.2	593.3	1.29	0.121 4	0.002 4	2.860 5	0.053 1	0.170 2	0.001 5	195	1 977	35	1 372	14	1 013	8	M
51	68.5	95.0	131.4	0.72	0.151 0	0.002 4	9.473 0	0.156 3	0.452 5	0.003 7	98	2 357	28	2 385	15	2 406	16	G	D
52	97.9	210.4	169.5	1.24	0.149 1	0.002 6	9.158 5	0.152 6	0.443 5	0.002 8	99	2 336	30	2 354	15	2 366	12	M
53	62.2	52.1	161.3	0.32	0.123 1	0.002 2	6.363 2	0.107 5	0.373 2	0.002 6	98	2 002	30	2 027	15	2 045	12	M
54	39.9	30.9	111.1	0.28	0.117 7	0.002 2	5.786 5	0.107 8	0.355 1	0.002 8	98	1 921	34	1 944	16	1 959	14	M
55	77.0	123.7	195.1	0.63	0.112 2	0.002 0	5.503 7	0.102 4	0.354 7	0.002 6	94	1 836	33	1 901	16	1 957	13	M
56	156.3	39.7	480.2	0.08	0.115 1	0.001 9	5.298 5	0.088 6	0.332 6	0.002 5	102	1 883	35	1 869	14	1 851	12	M
57	35.3	144.5	68.4	2.11	0.112 9	0.002 3	5.329 0	0.108 9	0.342 0	0.002 9	98	1 856	37	1 874	17	1 896	14	M
58	94.0	424.0	181.8	2.33	0.118 8	0.002 0	5.586 5	0.096 4	0.340 5	0.003 0	103	1 939	31	1 914	15	1 889	15	G	G1
59	123.4	253.9	292.3	0.87	0.116 8	0.001 8	5.845 4	0.096 7	0.361 7	0.003 0	96	1 907	28	1 953	14	1 990	14	M
60	61.5	351.5	204.9	1.72	0.123 1	0.003 0	3.982 4	0.097 0	0.234 0	0.002 5	148	2 002	43	1 631	20	1 355	13	M
61	77.2	93.6	146.5	0.64	0.160 1	0.003 1	9.512 0	0.193 0	0.429 0	0.003 6	107	2 457	38	2 389	19	2 301	16	G	D
62	122.1	137.2	301.9	0.45	0.129 1	0.002 0	6.551 8	0.108 6	0.366 2	0.002 5	104	2 087	27	2 053	15	2 011	12	G	G1
63	48.4	127.2	108.6	1.17	0.117 8	0.002 0	5.747 7	0.100 3	0.352 8	0.002 9	99	1 924	31	1 939	15	1 948	14	M
64	87.8	168.1	221.0	0.76	0.119 4	0.001 9	5.596 8	0.090 7	0.338 7	0.002 4	104	1 948	29	1 916	14	1 880	12	M
65	138.3	216.2	246.8	0.88	0.156 3	0.002 6	9.941 5	0.163 6	0.459 5	0.003 4	99	2 416	28	2 429	15	2 437	15	G	D
66	162.5	269.7	532.8	0.51	0.129 8	0.002 4	4.879 3	0.087 5	0.271 6	0.001 8	135	2 095	33	1 799	15	1 549	9	G	G1
67	48.1	84.7	94.0	0.90	0.148 0	0.002 9	8.606 4	0.170 5	0.419 9	0.003 6	103	2 324	33	2 297	18	2 260	16	G	D
68	126.6	154.9	265.9	0.58	0.147 4	0.002 3	8.572 9	0.139 0	0.419 6	0.003 1	103	2 316	27	2 294	15	2 259	14	M
69	62.8	96.9	154.4	0.63	0.147 3	0.002 7	7.228 7	0.132 6	0.355 0	0.003 7	118	2 315	31	2 140	16	1 958	17	G	D
70	175.3	330.8	784.5	0.42	0.122 1	0.002 1	3.513 7	0.058 9	0.207 6	0.001 5	163	1 987	30	1 530	13	1 216	8	G	G1
71	73.7	200.9	151.2	1.33	0.125 5	0.002 2	6.497 7	0.113 5	0.373 7	0.002 7	99	2 036	36	2 046	15	2 047	13	M
72	76.6	217.9	158.2	1.38	0.122 1	0.002 3	6.226 3	0.119 4	0.367 8	0.002 7	98	1 988	34	2 008	17	2 019	13	M
73	37.6	134.0	73.3	1.83	0.121 9	0.002 8	6.067 3	0.136 7	0.360 1	0.003 1	100	1 984	41	1 986	20	1 983	15	M
74	57.2	82.9	145.9	0.57	0.121 8	0.002 2	5.988 9	0.109 7	0.355 1	0.002 7	101	1 983	33	1 974	16	1 959	13	M
75	128.1	196.0	535.5	0.37	0.121 5	0.002 1	4.044 3	0.082 3	0.240 3	0.002 9	143	1 989	31	1 643	17	1 388	15	M
76	85.7	184.3	211.0	0.87	0.124 9	0.001 9	6.009 7	0.093 0	0.347 8	0.002 5	105	2 028	31	1 977	13	1 924	12	G	G1
77	64.9	154.3	153.3	1.01	0.116 5	0.001 9	5.629 0	0.092 4	0.349 7	0.002 7	98	1 903	29	1 921	14	1 933	13	M
78	92.1	268.7	188.9	1.42	0.122 5	0.002 2	6.277 9	0.116 1	0.370 5	0.002 8	98	1 992	36	2 015	16	2 032	13	M
79	155.1	427.2	449.1	0.95	0.137 1	0.002 3	5.504 6	0.098 2	0.290 4	0.002 6	133	2 191	29	1 901	15	1 644	13	G	D
80	102.5	131.7	215.4	0.61	0.145 8	0.002 2	8.531 7	0.139 5	0.423 1	0.003 5	101	2 298	26	2 289	15	2 275	16	G	G1
81	94.8	212.5	218.1	0.97	0.120 6	0.001 9	6.075 0	0.098 2	0.364 1	0.002 7	98	1 966	28	1 987	14	2 001	13	M
82	17.6	71.0	32.1	2.21	0.118 9	0.003 2	5.987 2	0.163 6	0.365 3	0.004 5	97	1 940	48	1 974	24	2 007	21	M
83	60.8	216.4	112.7	1.92	0.121 6	0.002 2	6.350 9	0.121 4	0.377 2	0.003 0	96	1 979	33	2 026	17	2 063	14	M
84	36.5	111.7	74.1	1.51	0.123 9	0.002 6	6.347 6	0.134 1	0.370 7	0.003 2	99	2 013	37	2 025	19	2 032	15	M
85	70.0	108.8	176.4	0.62	0.121 4	0.002 3	6.223 9	0.122 2	0.369 6	0.003 1	98	1 977	33	2 008	17	2 028	14	M
86	39.6	106.8	86.4	1.24	0.117 1	0.002 3	5.828 7	0.118 6	0.359 6	0.003 2	97	1 913	35	1 951	18	1 980	15	M
87	143.4	295.8	322.6	0.92	0.120 1	0.001 9	6.289 1	0.097 0	0.378 2	0.002 3	95	1 958	29	2 017	14	2 068	11	G	G1
88	21.6	81.1	40.0	2.03	0.121 7	0.003 0	6.095 7	0.149 3	0.363 7	0.004 1	99	1 981	45	1 990	21	2 000	20	G	D
89	97.3	39.9	260.2	0.15	0.116 9	0.001 9	6.134 5	0.100 1	0.379 0	0.002 8	92	1 910	30	1 995	14	2 072	13	M
90	46.6	73.4	115.5	0.64	0.119 7	0.002 4	5.985 9	0.123 6	0.360 9	0.003 1	98	1 954	35	1 974	18	1 987	15	M
91	107.1	143.5	215.7	0.67	0.183 2	0.003 4	10.522 4	0.195 7	0.414 8	0.003 8	120	2 683	36	2 482	17	2 237	17	M
92	89.8	78.5	186.9	0.42	0.150 1	0.002 4	9.147 9	0.155 2	0.440 0	0.003 7	100	2 347	27	2 353	16	2 351	17	M
93	147.7	238.1	320.3	0.74	0.144 7	0.002 6	7.963 6	0.137 3	0.397 5	0.003 7	106	2 284	32	2 227	16	2 158	17	G	D
94	143.4	294.8	246.4	1.20	0.152 5	0.002 3	9.505 0	0.150 8	0.449 8	0.003 6	99	2 376	25	2 388	15	2 394	16	G	G1
95	132.1	284.4	336.1	0.85	0.117 7	0.002 0	5.465 0	0.092 3	0.335 4	0.002 6	103	1 921	30	1 895	14	1 864	13	M
96	34.4	123.2	69.3	1.78	0.120 2	0.002 6	5.886 9	0.126 5	0.354 3	0.003 5	100	1 961	38	1 959	19	1 955	17	M
97	56.4	154.7	144.8	1.07	0.117 7	0.002 1	5.303 8	0.096 9	0.325 4	0.002 3	106	1 922	33	1 869	16	1 816	11	M
98	63.5	135.6	160.8	0.84	0.116 1	0.002 0	5.475 7	0.094 0	0.340 8	0.002 4	100	1 898	31	1 897	15	1 891	11	M
99	102.6	148.5	258.3	0.57	0.135 5	0.002 7	6.810 5	0.143 8	0.362 7	0.003 4	109	2 170	35	2 087	19	1 995	16	G	D
100	58.4	75.3	156.6	0.48	0.117 1	0.002 2	5.660 9	0.109 0	0.348 9	0.002 7	99	1 913	33	1 925	17	1 930	13	M
101	60.2	209.2	120.2	1.74	0.118 5	0.002 1	5.859 3	0.105 9	0.357 3	0.002 9	99	1 944	31	1 955	16	1 969	14	M
102	64.0	153.8	142.8	1.08	0.122 1	0.002 3	6.082 4	0.115 3	0.360 6	0.003 6	100	1 988	33	1 988	17	1 985	17	G	D
103	94.2	129.2	225.6	0.57	0.118 3	0.002 0	6.229 4	0.110 5	0.380 1	0.002 7	93	1 931	31	2 009	16	2 077	13	M
104	18.8	34.0	46.5	0.73	0.116 2	0.002 5	5.686 5	0.120 0	0.355 1	0.003 6	97	1 899	38	1 929	18	1 959	17	M
105	111.3	207.9	280.9	0.74	0.115 1	0.001 8	5.514 7	0.087 9	0.346 4	0.002 7	98	1 883	28	1 903	14	1 917	13	M
106	60.4	160.0	137.0	1.17	0.116 9	0.002 3	5.683 2	0.108 0	0.351 9	0.003 3	98	1 910	36	1 929	16	1 944	16	M
107	40.6	114.4	86.3	1.33	0.119 4	0.002 5	5.971 6	0.123 7	0.362 0	0.003 2	98	1 947	37	1 972	18	1 992	15	M
108	88.0	135.6	221.8	0.61	0.120 2	0.002 1	5.912 5	0.102 4	0.355 3	0.002 9	100	1 961	31	1 963	15	1 960	14	G	G1
109	435.7	262.3	1316.0	0.20	0.249 9	0.003 9	7.440 6	0.123 8	0.215 1	0.001 8	253	3 184	25	2 166	15	1 256	10	M
110	97.3	127.1	289.0	0.44	0.120 4	0.002 2	5.211 5	0.097 5	0.313 5	0.003 6	112	1 961	33	1 855	16	1 758	18	G	D
111	40.2	37.0	72.1	0.51	0.166 4	0.002 7	11.230 3	0.178 5	0.488 6	0.003 8	98	2 522	28	2 542	15	2 565	16	G	D
注：M.变质成因；G.岩浆成因；D.辉绿石；G1.花岗岩类(SiO₂含量＜65%)；G2.花岗岩类(SiO₂含量为70%~75%).

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表 2 锆石标样91500微量元素数据与前人数据对比

Table 2. Trace elements data (10^-6) for the 91500 zircon standard compared with previously reported data

微量元素	本次研究(n=42)	Belousova et al.(2002)(n=4)	Wiedenbeck et al.(1995)
Y	145.5±9.5	147±22
La	0.04±0.03	＜0.08±0.05
Ce	2.6±0.2	2.5±0.5	2.0±0.1	n=4, IP
Pr	0.03±0.02	＜0.05±0.05
Nd	0.315±0.275	＜0.35±0.07	0.4	n=1, IP
Sm	0.395±0.275	0.41±0.2	0.3	n=1, IP
Eu	0.26±0.12	0.37±0.17	0.26±0.07	n=6, IP/NAA
Gd	2.365±0.455	2.1±0.35	1.93±0.10	n=4, IP
Dy	11.8±1.0	12±2.1	8.0±1.4	n=4, IP
Ho	4.85±0.45	4.9±0.7
Er	28.7±2.8	26±3.6	20.4±0.8	n=4, IP
Yb	69.3±4.1	66±7.3	57.4±16.7	n=6, IP/NAA
Lu	13.8±1.0	14±1.9	12.4±0.9	n=2, NAA
Th	30.6±2.7	31±4.9	34.6±6.9	n=4, ID/NAA
U	82.85±5.15	88±15	81.2±4.5	n=11, ID
Hf(%)	0.64±0.03	0.64±0.09	0.59±0.01	n=18, PMP
			0.73±0.05	n=16, IP
			0.59±0.03	n=4, ID
			0.56±0.01	n=99, EMP

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