内蒙古乌日尼图钨钼矿床成矿流体特征及地质意义

杨增海; 王建平; 刘家军; 王守光; 王清义; 康书光

doi:10.3799/dqkx.2012.135

内蒙古乌日尼图钨钼矿床成矿流体特征及地质意义

doi: 10.3799/dqkx.2012.135

杨增海^{1, 2,},
王建平^{1, 2, ,},
刘家军^{1, 2},
王守光³,
王清义⁴,
康书光⁴

1.
中国地质大学地质过程与矿产资源国家重点实验室, 北京 100083
2.
中国地质大学地球科学与资源学院, 北京 100083
3.
内蒙古自治区地质调查院, 内蒙古呼和浩特 010020
4.
内蒙古自治区第九地质矿产勘查开发院, 内蒙古锡林浩特 026000

基金项目:

中国地质调查局矿产资源调查评价专项工作项目"重要示范区带区域成矿系统研究" 1212011085471

详细信息

作者简介:
杨增海(1982-), 男, 硕士研究生, 主要从事矿床学与矿床地球化学的研究.E-mail: yangzenghai21023@163.com

通讯作者:
王建平, E-mail: jpwang@cugb.edu.cn

中图分类号: P611
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- 被引次数: 0
出版历程
- 收稿日期: 2012-07-19
- 网络出版日期: 2021-11-09
- 刊出日期: 2012-06-15

Characteristics and Its Geological Significance of Fluid Inclusions of the Wurinitu W-Mo Deposit in Inner Mongolia, China

1.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China
2.
School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
3.
Geological Survey Institute of Inner Mongolia, Huhehaote 010020, China
4.
Inner Mongolia Ninth Geology Mineral Exploration and Development Co. Ltd., Xilinhaote 026000, China

摘要

摘要: 乌日尼图钨钼矿位于内蒙古苏尼特左旗境内,是近几年该区新发现的较大规模的钨钼矿床.钨钼矿体主要产于燕山期花岗岩体的内外接触带附近,以细脉状矿化类型为主.该矿床中的流体包裹体主要发育气液两相、富气相、富液相和纯液相包裹体等类型.包裹体均一温度为130.0~371.7 ℃(峰值为160.0~260.0 ℃),盐度为0.2%~15.9% NaCl eqv(峰值为0.2%~12.5% NaCl eqv),属于中低温、中低盐度钨钼矿床.激光拉曼和群体包裹体成分分析结果表明,流体体系气相成分以H₂O、CO₂为主,其次为N₂、O₂以及少量CO、CH₄、C₂H₂、C₂H₄和C₂H₆等; 液相成分以Ca²⁺、Na⁺、SO₄^2-、Cl^-为主,其次为K⁺、F^-、NO₃^-、Mg²⁺以及少量Br^-和Li⁺.成矿流体为H₂O-NaCl-CO₂体系.流体包裹体氢氧同位素分析表明,成矿流体的δ¹⁸O_水的含量范围为-2.11%~-0.11%,δD_水的含量范围为-85%~-108%,成矿流体为岩浆水与大气降水的混合物.结合矿床地质和成矿流体特征,认为该矿床为与燕山期岩浆活动有关的中低温热液石英脉型钨钼矿床,成矿物质以深源为主.
- 石英脉型钨钼矿 /
- 流体包裹体 /
- 氢氧同位素 /
- 乌日尼图 /
- 岩石学 /
- 成矿预测 /
- 矿床.
Abstract: The Wurinitu W-Mo deposit,located in Sunid Zuoqi area in the Inner Mongolia autonomous region,is a large W-Mo deposit discovered in recent years. The W-Mo orebodies mainly occurred in Yanshanian granite rock body and the nearby contact zone,with the major type of veinlet mineralization. Petrographic study of fluid inclusions suggests that the main types of fluid inclusions of Wurinitu metallogenic fluid system are two-phase vapor-liquid inclusions,vapor-rich phase inclusions,liquid-rich phase inclusions and pure liquid phase inclusions. The homogenization temperature and salinity of the fluid inclusions vary in 130.0-371.7 ℃ (the peak value vary in 160-260 ℃) and 0.2%-15.9% NaCl eqv (the peak value vary in 0.2%-12.5% NaCl eqv). The deposit belongs to a medium-low temperature,medium-low salinity W-Mo deposit. Laser Raman spectroscopic and inclusion groups components studies indicate that gas composition of the ore-forming fluid are mainly H₂O and CO₂,some N₂ and O₂,and less CO,CH₄,C₂H₂,C₂H₄ and C₂H₆,liquid composition are mainly Ca²⁺,Na⁺,SO₄^2-,Cl^-,some K⁺,F^-,Mg²⁺ and NO₃^-,and less Br^- and Li⁺. The ore-forming fluids belong to the H₂O-NaCl-CO₂ system. The hydrogen and oxygen isotopic compositions of fluid inclusions showed that the ore-forming fluids had lower values of δ¹⁸O_water ranging from -2.11% to -0.11%,and the value of δD_water ranged from -85% to -108%. The ore-forming fluids came from the mixing of magma water and meteoric water. Based on the geological and ore-forming fluids characteristics of the deposit,it is concluded that the Wurinitu quartz vein type W-Mo deposit is a Yanshanian magmatism-related and moderate-low temperature hydrothermal system. The ore-forming materials were mainly derived from the depth.
- quartz vein type W-Mo deposit /
- fluid inclusions /
- hydrogen and oxygen isotope /
- Wurinitu /
- petrology /
- ore prospecting /
- ore deposits.

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图 1 乌日尼图钨钼矿床矿区地质简图(据内蒙古自治区第九地质矿产勘查开发院, 2011, 苏尼特左旗乌日尼图钨钼矿1∶2 000地形地质图修编)

Q^eol.第四系风成砂；Qp.第四系砾石层；O_1-2w³.中下奥陶统乌宾敖包组三段；O_1-2w².中下奥陶统乌宾敖包组二段；γπ.花岗斑岩；SK.矽卡岩；1.地层界线及侵入岩接触界线；2.勘探线编号；3.钻孔位置；4.地层产状

Fig. 1. Simplified geological map of the Wurinitu tungsten and molybdenum deposit

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图 2 乌日尼图钨钼矿床550线勘探线剖面图(据内蒙古自治区地质调查院, 2010, 乌日尼图矿区550勘探线设计1∶1 000剖面图修编)

1.第四系砾石层；2.中下奥陶统乌宾敖包组二段变质粉砂岩；3.中下奥陶统乌宾敖包组二段粉砂质板岩；4.花岗斑岩；5.细粒二长花岗岩；6.大理岩；7.破碎带；8.矿体；9.钻孔位置及编号

Fig. 2. Exploration profiles in 550 line of the Wurinitu tungsten and molybdenum deposit

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图 3 乌日尼图钨钼矿床矿石宏观及显微组构特征

a.主成矿期细脉状辉钼矿；b.主成矿期颗粒状黄铁矿与板状黑钨矿共生；c.主成矿期辉钼矿与黑钨矿共生；d.显微镜下主成矿期板状黑钨矿与叶片状辉钼矿共生；Mo.辉钼矿；Py.黄铁矿；Wol.黑钨矿；Q.石英

Fig. 3. The petrofabric characteristics of ores from the Wurinitu tungsten and molybdenum deposit

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图 4 乌日尼图钨钼矿床中流体包裹体显微照片

a.纯液相包裹体及气液两相包裹体共生同一个结晶平面；b.富气包裹体；c.富液包裹体；d.含2个气泡的包裹体

Fig. 4. Photomicrographs of fluid inclusions in the Wurinitu tungsten and molybdenum deposit

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图 5 石英流体包裹体均一温度与盐度直方图

Fig. 5. Histgrams of homogenization temperatures and salinity of fluid inclusions in quartz

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图 6 乌日尼图钨钼矿床流体包裹体激光拉曼分析光图谱

a.气液两相包裹体中的CO₂和CO₃^2-；b.气液两相包裹体中的H₂O；Qz.石英

Fig. 6. Laser Raman spectra of fluid inclusions in the Wurinitu tungsten and molybdenum deposit

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图 7 乌日尼图钨钼矿床成矿流体的δ¹⁸O_水-δD_水图解

Fig. 7. δ¹⁸O_水-δD_水 diagram of ore-forming fluids in the Wurinitu tungsten and molybdenum deposit

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表 1 乌日尼图钨钼矿床石英中流体包裹体参数特征

Table 1. Parameter characteristics of fluid inclusion in quartz from the Wurinitu tungsten and molybdenum deposit

样号	个数	大小(μm)	气液比(%)	冰点T_{m, ice}(℃)	均一温度T_h(℃)	盐度(% NaCl eqv)	密度(g/cm³)	成矿压力(MPa)	成矿深度(km)
WR-1	16	4.6~38.7	5~30	-8.1~-3.5(-6.3)	187.0~263.8(233.2)	5.7~12.1(9.5)	0.82~0.96(0.90)	51.79~74.46(64.13)	1.73~2.48(2.14)
WR-2	14	4.1~13.5	10~15	-5.3~-0.3(-2.6)	224.1~243.0(238.5)	0.5~8.1(4.3)	0.81~0.88(0.85)	45.00~66.02(61.29)	1.50~2.20(2.04)
WR-3	15	3.1~12.9	5~35	-9.3~-4.6(-7.1)	161.7~316.6(229.7)	7.3~13.2(10.5)	0.77~0.97(0.91)	44.39~78.28(63.42)	1.48~2.89(2.11)
WR-4	16	2.0~6.5	5~20	-10.7~-3.8(-7.3)	174.4~321.1(234.6)	6.2~14.7 (10.7)	0.84~0.98(0.91)	48.38~89.48(64.79)	1.61~2.88(2.16)
WR-6	15	3.3~12.5	5~15	-11.7~-0.3(-3.8)	130.0~260.5(208.2)	0.5~15.7 (6.0)	0.84~0.98(0.90)	30.30~70.90(55.10)	1.01~2.36(1.84)
WR-15	14	2.7~17.5	5~20	-3.6~-0.3(-1.2)	168.2~258.9(215.5)	0.5~5.9 (2.0)	0.79~0.92(0.86)	39.02~65.47(50.86)	1.32~2.18(1.70)
WR-16	15	4.0~22.3	3~20	-11.9~-3.0(-7.7)	159.8~352.6(223.3)	5.0~15.9 (11.2)	0.78~1.01(0.92)	44.49~97.99(61.64)	1.48~3.27(2.05)
WR-18	15	3.5~10.6	5~35	-5.2~-1.6(-3.7)	162.4~271.4(209.6)	2.7~8.1 (6.0)	0.86~0.93(0.90)	42.47~74.05(56.51)	1.42~2.47(1.88)
WR-21	16	3.7~20.6	5~15	-5.4~-0.1(-3.2)	170.0~236.6(209.6)	0.2~8.4 (5.2)	0.82~0.96(0.89)	29.46~ 63.90(53.95)	0.98~2.13(1.80)
WR-22	14	3.0~30.2	5~15	-6.9~-3.9(-5.1)	174.9~216.5(201.1)	6.3~10.4 (7.9)	0.89~0.96(0.92)	48.18~59.81(55.00)	1.61~1.99(1.83)
WR-25	14	3.3~18.1	5~25	-9.3~-0.2(-3.4)	171.8~272.5(212.7)	0.4~13.2(5.3)	0.84~0.94(0.89)	32.89~75.22 (53.16)	1.10~2.51(1.77)
WR-26	16	2.0~9.5	3~30	-8.4~-2.6(-5.1)	139.7~334.5(211.0)	4.3~12.2(8.0)	0.77~0.99(0.91)	38.39~92.44(59.90)	1.28~3.08(2.00)
WR-37	16	2.4~13.5	3~15	-6.1~-0.2(-3.4)	136.4~211.9(168.5)	0.4~9.3(5.4)	0.89~0.97(0.94)	21.09~56.91(45.44)	0.70~1.90(1.51)
WR-41	16	5.2~15.5	5~15	-5.5~-1.0(-3.7)	179.5~265.5(205.0)	1.7~8.5(6.0)	0.81~0.95(0.90)	46.99~70.29(54.98)	1.57~2.34(1.83)
WR-42	15	3.2~13.4	5~15	-5.2~-2.0(-3.9)	134.0~256.7(205.8)	3.4~8.1(6.2)	0.86~0.97(0.90)	35.99~70.34(55.65)	1.20~2.34(1.86)
WR-46	16	3.2~14.6	10~15	-8.7~-0.1(-4.3)	219.5~305.7(259.4)	0.2~12.5(6.8)	0.74~0.90(0.84)	35.84~84.55(67.99)	1.19~2.82(2.27)
WR-47	15	2.7~9.7	10~30	-6.3~-0.3(-2.8)	178.2~371.7(240.3)	0.5~9.3(5.2)	0.68~0.91(0.85)	41.66~102.09(62.04)	1.39~3.40(2.07)
注：括号内为平均值.

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表 2 乌日尼图钨钼矿床石英中流体包裹体群气相和液相成分(μg/g)

Table 2. Gas components and aqueous components of grouped fluid inclusions from quartz in the Wurinitu tungsten and molybdenum deposit

样号	WR-1	WR-4	WR-6	WR-25	WR-26	WR-37
样品名称	含矿石英脉	含矿石英脉	含矿石英脉	含矿石英脉	含矿石英脉	含矿石英脉
CH₄	1.134	0.091	0.138	0.659	0.240	0.122
C₂H₂+C₂H₄	0.355	0.228	0.345	0.641	0.587	0.215
C₂H₆	微量	微量	0.010	0.072	0.027	微量
CO₂	215.394	93.991	179.044	352.493	204.057	92.912
H₂O	217.082	204.064	60.020	421.716	178.399	174.747
O₂	8.623	9.626	19.379	9.512	12.011	8.343
N₂	42.338	45.142	93.596	58.817	63.648	39.963
CO	15.688	11.242	48.108	93.460	70.792	13.137
CO₂/H₂O	0.406	0.189	1.221	0.342	0.468	0.218
CO₂/N₂	3.238	1.325	1.218	3.815	2.041	1.480
Li⁺	0.038	0.076	0.022	0.047	0	0.035
Na⁺	3.617	4.047	2.446	3.891	2.035	4.490
K⁺	2.269	3.439	2.223	1.949	2.940	2.434
Mg²⁺	0.025	0.028	0.043	0.031	0.029	0.021
Ca²⁺	1.481	2.145	3.002	2.347	2.333	1.600
F^-	0.454	0.263	0.289	0.671	0.166	0.372
Cl^-	2.968	2.712	2.757	3.672	2.126	4.532
NO₂^-	0	0	0	0	0	0
Br^-	0	0	0.087	0.156	0	0
NO₃^-	2.117	2.345	2.122	2.448	1.823	1.880
SO₄^2-	10.334	8.621	6.971	9.442	7.319	9.078
(Na⁺+K⁺)/(Ca²⁺+Mg²⁺)	5.670	4.829	2.129	3.662	2.756	6.315
Mg²⁺/Ca²⁺	0.028	0.022	0.024	0.022	0.020	0.022
Na⁺/K⁺	2.711	2.001	1.871	3.395	1.177	3.137
Na⁺/Ca²⁺	4.258	3.289	1.420	2.890	1.521	4.892
F^-/Cl^-	0.285	0.181	0.196	0.341	0.146	0.153
Cl^-/SO₄^2-	0.778	0.852	1.072	1.054	0.787	1.353
注：数据由中国地质科学院地质矿产资源研究所流体包裹体实验室分析，分析人杨丹.

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表 3 乌日尼图钨钼矿床氢氧同位素测试结果

Table 3. Hydrogen and oxygen isotope data of the Wurinitu tungsten and molybdenum deposit

样号	WR-1	WR-3	WR-16	WR-18	WR-21	WR-25	WR-26	WR-37	WR-42	WR-47
产出位置	矿石	矿石	矿石	矿石	矿石	矿石	矿石	矿石	矿石	矿石
测试矿物	石英	石英	石英	石英	石英	石英	石英	石英	石英	石英
δ¹⁸O_石英(%)	8.7	10.5	9.6	10.5	10.3	10.0	11.1	9.9	12.2	8.5
δD_水(%)	-99	-97	-105	-103	-85	-106	-108	-105	-87	-99
δ¹⁸O_水(%)	-1.91	-0.11	-1.01	-0.11	-0.31	-0.61	0.49	-0.71	1.59	-2.11

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