Volume 32 Issue 2
Mar.  2007
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FAN Xiao-yu, WU Xiu-ling, MENG Da-wei, LIU Wei-ping, WANG Xin-xing, ZHENG Jian-ping, 2007. Water in UHP Jadeite-Quartzites of Dabie Mountains: Evidence from Micro-FTIR. Earth Science, 32(2): 167-174.
Citation: FAN Xiao-yu, WU Xiu-ling, MENG Da-wei, LIU Wei-ping, WANG Xin-xing, ZHENG Jian-ping, 2007. Water in UHP Jadeite-Quartzites of Dabie Mountains: Evidence from Micro-FTIR. Earth Science, 32(2): 167-174.

Water in UHP Jadeite-Quartzites of Dabie Mountains: Evidence from Micro-FTIR

  • Received Date: 2006-10-30
  • Publish Date: 2007-03-25
  • The distribution characteristics of structural water in nominally anhydrous minerals (NAMs) from Dabie mountains can provide important microscopic information on some aspects of the related fluid activities, mineral deformation, dynamical process of blocks subduction and exhumation. The NAMs such as jadeites, garnets, rutiles and quarts in ultra-high pressure (UHP) jadeite-quartzites of Shuanghe and Bixiling areas from Dabie mountains were investigated by Fourier transform infrared spectroscopy (FTIR), the result of which indicates that NAMs contain hydrogen occurring as hydroxyl (OH-) or molecule H2O. It is found that the average structural water contents of the jadeites from the two areas are both close to 1 000×10-6; the rutilezs' are both above 2 000×10-6; the quarts' are both < 4×10-6. The structural water contents of garnets from different grains in the same area aren't uniform, while the water contents of UHP jadeite-quartzites from the two areas both range from 900×10-6 to 1 600×10-6. The results reveal that the water in crust or protolith can be transported into the earth's depth through NAMs in the UHP metamorphic rocks during the formation of the HP-UHP metamorphic rocks.

     

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  • Anies, R. D., Rossman, G. R., 1984. Water in minerals?Apeakin the infrared. J. Geophys. Res. , 89: 4059-4071. doi: 10.1029/JB089iB06p04059
    Bell, D. R., Ihinger, P. D., Rossman, G. R., 1995. Quantita-tive analysis of trace OH- in garnet and pyroxenes. Am. Mineral. , 80: 465-474. doi: 10.2138/am-1995-5-607
    Chakraborty, D., Lehmann, G., 1976. Distribution of OH- insynthetic and natural quartz crystals. J. Solid StateChem. , 17: 305-311. doi: 10.1016/0022-4596(76)90136-5
    Cheng, Y. Q., Zhuang, Y. X., Gao, T. S., et al., 2002. Li-thology and protolith of HP-UHP eclogites facies meta-morphic rocks and relevant rocks of the Changpu-Bixiling area, Dabie mountains. Acta Geologica Sinica, 76(1): 1-14(in Chinese with English Abstract).
    Cromer, D. T., Herrington, K., 1955. The structures of ana-tase and rutile. J. Am. Chem. Soc. , 77: 4708-4709. doi: 10.1021/ja01623a004
    Fu, B., Touret, J. L. R., Zheng, Y. F., 2001. Fluid inclusionsin coesite-bearing eclogites and jadeite quartzite atShuanghe, Dabie mountains(China). J. MetamorphicGeol. , 19: 529-545.
    Hammer, V. M. F., Beran, A., 1991. Variations in the OH- concentration of rutiles from different geological envi-ronments. Mineral. Petrol. , 45: 1-9. doi: 10.1007/BF01164498
    Han, Y. J., Zhang, Z. M., Liu, R., 1997. Fluidinclusions in coesite-bearing jadeite quartzite from Shuanghe, Anhui Province. Earth Science—Journal of China University of Geosci-ences, 22: 322-326(in Chinese with English Abstract).
    Ingrin, J., Latrous, K., Doukhan, J. C., et al., 1989. Water indiopside: An electron microscopy and infrared spectros-copy study. Eur. J. Mineral. , 1: 327-341. doi: 10.1127/ejm/1/3/0327
    Ingrin, J., Skogby, H., 2000. Hydrogen in nominally anhy-drous upper-mantle minerals: Concentration levels andi mplications. Eur. J. Mineral. , 12: 543-570. doi: 10.1127/ejm/12/3/0543
    Katayama, I., Nakashi ma, S., 2003. Hydroxyl in clinopyrox-ene from the deep subducted crust: Evidence for H2Otransport into the mantle. Am. Mineral. , 88: 229-234. doi: 10.2138/am-2003-0126
    Lager, G. A., Armbruster, T., Rotella, F. J., et al., 1989. OH- substitutionin garnets: X-ray and neutron diffrac-tion, infrared, and geometric-modelling studies. Am. Mineral. , 74: 840-851.
    Langer, K., Robarick, E., Sobolev, N. V., et al., 1993. Single-crystal spectra of garnets from diamondiferoushigh-pressure metamorphic rocks from Kazakhstan: In-dications for OH-, H2O, and FeTi charge transfer. Eur. J. Mineral. , 5: 1091-1100. doi: 10.1127/ejm/5/6/1091
    Li, X. P., Li, Y. L., Shu, G. M., 2005. Breakdown of lawso-nite subsequent to peak UHP metamorphismin the Da-bie terrane and its i mplication for fluid activity. ChineseScience Bulletin, 50(13): 1366-1372.
    Libowitzky, E., Rossman, G. R., 1996. Principles of quanti-tative absorbance measurement in anisotropic crystals. Phys. Chem. Mineral. , 23: 319-327. doi: 10.1007/BF00199497
    Liou, J. G., Zhang, R. Y., Jahn, B. M., 1997. Geochemistryand isotope data on an ultrahigh-pressurejadeite quartz-ite from Shuanghe, Dabie mountains, eastern China. Lithos, 41: 59-78. doi: 10.1016/S0024-4937(97)82005-1
    Liu, X. W., Jin, Z. M., Jin, S. Y., et al., 2005. Differences of de-formation characteristics of garnets fromtwo types of eclo-gites: Evidence from TEMstudy. Acta Petrologica Sinica, 21(2): 399-404(in Chinese with English abstract).
    Lu, R., Keppler, H., 1997. Water solubility in pyrope to100kbar. Contrib. Mineral. Petrol. , 129: 35-42. doi: 10.1007/s004100050321
    Luth, R. W., Virgo, D., Boyd, F. R., et al., 1990. Ferric ironin mantle-derived garnets. Contrib. Mineral. Petrol. , 104: 56-72. doi: 10.1007/BF00310646
    Miller, G. H., Rossman, G. R., Harlow, G. E., 1987. Thenatural occurrence of hydroxide in olivine. Phys. Chem. Minerals. , 19: 1155-1164. doi: 10.1007/BF00628824
    Paterson, M., 1982. The determination of hydroxyl by infra-red absorptionin quartz, silicate glasses and si milar ma-terials. Bull. Mineral. , 105: 20-29. https://www.persee.fr/doc/bulmi_0180-9210_1982_num_105_1_7582
    Rossman, G. R., Aines, R. D., 1991. The hydrous compo-nents in garnets: Grossular-hydrogrossular. Am. Miner-al. , 76: 1153-1164. https://pubs.geoscienceworld.org/msa/ammin/article-abstract/76/7-8/1153/42558/The-hydrous-components-in-garnets-Grossular
    Sheng, Y. M., Xia, Q. K., Yang, X. Z., 2004. Heterogeneityof water in UHP eclogites from Bixiling in Dabieshan: Evidence fromgarnet. Chinese Science Bulletin, 49(5): 481-486. doi: 10.1007/BF02900969
    Sheng, Y. M., Xia, Q. K., Hao, Y. D., et al., 2005a. Water inUHP eclogites at Shuanghe, Dabie mountains: Micro-FTIRanalysis. Earth Science—Journal of China Uni-versity of Geosciences, 30(6): 673-684(in Chinesewith English abstract).
    Sheng, Y. M., Xia, Q. K., Ding, Q., et al., 2005b. Water ingarnets from Dabie mountains eclogites: FTIRanalysis. Acta Mineralogica Sinica, 25(4): 334-340(in Chinesewith English abstract).
    Skogby, H., Bell, D. R., Rossman, G. R., 1990. Hydroxide inpyroxenes: Variations in the natural environment. Am. Mineral. , 75: 764-774. https://pubs.geoscienceworld.org/msa/ammin/article-abstract/75/7-8/764/42400/Hydroxide-in-pyroxene-variations-in-the-natural
    Skogby, H., Rossman, G. R., 1989. OH- in pyroxene: Anexperi mental study of incorporation mechanismand sta-bility. Am. Mineral. , 74: 1059-1069.
    Su, W., Ji, Z. P., You, Z. D., et al., 2004. Distribution of hy-drous components in jadeite of the Dabie mountains. Earth Planet. Sci. Lett. , 222(1): 85-100. doi: 10.1016/j.epsl.2004.02.028
    Su, W., You, Z. D., Cong, B. L., et al., 2002. Cluster of wa-ter molecules in garnet from ultrahigh-pressure eclo-gites. Geology, 30(7): 611-614. doi: 10.1130/0091-7613(2002)030<0611:COWMIG>2.0.CO;2
    Su, W., You, Z. D., Cong, B. L., et al., 2003. Roles of waterin deformed omphacite in UHP eclogite fromthe Dabiemountains, eastern China. Acta Geologica Sinica, 77(3): 320-325. doi: 10.1111/j.1755-6724.2003.tb00748.x
    Swope, R. J., Smyth, J. R., 1995. H+in rutile-type com-pounds: Single-crystal neutron and X-ray diffractionstudy of Hin rutile. Am. Mineral. , 80: 448-453. doi: 10.2138/am-1995-5-604
    Wang, L., Jin, Z. M., Liu, X. W., et al., 2004. Microfabric char-acteristics of ultrahigh pressurejadeite quartzite andits rhe-ology significances in Shuanghe, Dabie mountains. EarthScience—Journal of China University of Geosciences, 29(3): 293-302(in Chinese with English abstract).
    Wilkins, R. W., Sabine, W., 1973. Water content of somenominally anhydrous silicates. Am. Mineral. , 58: 508-516.
    Wu, X. L., Meng, D. W., Han, Y. J., et al., 2005. Nano-scalefluid inclusions in quartz of jadeite quartzite at Shuang-he, Dabie mountains. J. Minreal. Petrol. , 25(2): 7-10(in Chinese with English abstract).
    Xia, Q. K., 2005. Water in the deep subducted continentalplate: Message from NAMs. Bulletin of MineralogyPetrology and Geochemistry, 24(1): 1-6(in Chinesewith English abstract).
    Xia, Q. K., Chen, D. G., Guo, L. H., 1998. Structural OH- in mantle-derived clinopyroxene megacrysts from Nush-an. Chinese Science Bulletin, 43(20): 1742-1745. doi: 10.1007/BF02883977
    Xia, Q. K., Chen, D. G., Rossman, G. R., 2000. Ani mportantcarrier for HP-UHP metamorphic fluids: Nominally an-hydrous minerals. Geological Review, 46: 461-465(inChinese with English abstract).
    You, Z. D., Han, Y., Yang, W., et al., 1996. The high-pres-sure and ultra-high-pressure metamorphic belt in theeast Qinling and Dabie mountains, China. China Univer-sity of Geosciences Press, Wuhan, 1-150.
    Zhang, J. F., Jin, Z. M., GreenⅡ, H. W., et al., 2001. Hy-droxyl in continental deep subduction zone: Evidencefrom UHP eclogites of the Dabie mountains. ChineseScience Bulletin, 46(7): 592-596.
    Zhang, J. F., Jin, Z. M., GreenⅡ, H. W., 2005. Hydroxylinduced eclogite fabric and deformation mechanism. Chinese Science Bulletin, 50(7): 685-690. doi: 10.1360/982004-274
    Zheng, Y. F., Fu, B., Li, Y. L., et al., 1998. Oxygen and hy-drogenisotope geochemistry of ultrahigh pressure eclo-gites from the Dabie mountains and the Sulu terrane. Earth Planet. Sci. Lett. , 155: 113-129. doi: 10.1016/S0012-821X(97)00203-3
    Zheng, Y. F., Fu, B., Gong, B., et al., 2003. Stable isotopegeochemistry of ultrahigh pressure metamorphic rocksfromthe Dabie-Sulu orogen in China: I mplications forgeodynamics and fluid regi me. Earth-Science Reviews, 62: 105-161. doi: 10.1016/S0012-8252(02)00133-2
    程裕淇, 庄育勋, 高天山, 等, 2002. 大别山菖蒲-碧溪岭地区高压-超高压榴辉岩相变质岩和有关岩石的岩石类型及其原岩性质. 地质学报, 76(1): 1-14. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE200201001.htm
    韩郁菁, 张泽明, 刘嵘, 1997. 安徽双河含柯石英硬玉石英岩中流体包裹体的研究. 地球科学——中国地质大学学报, 22(3): 322-326. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX703.017.htm
    李旭平, 李一良, 舒桂明, 2005. 大别山黄镇榴辉岩和蓝晶石-石英脉中硬柱石分解的岩石学研究及其流体活动意义. 科学通报, 50(10): 1000-1006. doi: 10.3321/j.issn:0023-074X.2005.10.011
    刘祥文, 金振民, 金淑燕, 等, 2005. 两类榴辉岩的石榴石变形特征差异——来自TEM的证据. 岩石学报, 21(2): 399-404. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200502015.htm
    盛英明, 夏群科, 杨晓志, 2004. 大陆深俯冲过程中水分布的不均一性: 大别山碧溪岭榴辉岩中石榴石的红外光谱分析. 科学通报, 49(4): 390-395. doi: 10.3321/j.issn:0023-074X.2004.04.016
    盛英明, 夏群科, 郝艳东, 等, 2005a. 大别山双河超高压榴辉岩中的水: 微区红外光谱分析. 地球科学——中国地质大学学报, 30(6): 673-684. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200506003.htm
    盛英明, 夏群科, 丁强, 等, 2005b. 大别山榴辉岩中石榴石的结构水: 红外光谱分析. 矿物学报, 25(4): 334-340. https://www.cnki.com.cn/Article/CJFDTOTAL-KWXB200504003.htm
    王璐, 金振民, 刘祥文, 等, 2004. 大别山双河超高压硬玉石英岩显微组构特征及其流变学意义. 地球科学——中国地质大学学报, 29(3): 293-302. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200403005.htm
    吴秀玲, 孟大维, 韩郁菁, 等, 2005. 大别山双河硬玉石英岩石英中的纳米-亚微米级流体包裹体. 矿物岩石, 25(2): 7-10. doi: 10.3969/j.issn.1001-6872.2005.02.002
    夏群科, 2005. 大陆深俯冲过程中的水: "名义上无水矿物(NAMs)"的信息. 矿物岩石地球化学通报, 24(1): 1-6. doi: 10.3969/j.issn.1007-2802.2005.01.001
    夏群科, 陈道公, 郭立鹤, 1998. 女山幔源单斜辉石巨晶中的结构OH. 科学通报, 43(16): 1764-1767. doi: 10.3321/j.issn:0023-074X.1998.16.017
    夏群科, 陈道公, Rossman, G. R., 2000. 高压超高压变质流体的一种重要载体: 名义上的无水矿物. 地质论评, 46: 461-465. doi: 10.3321/j.issn:0371-5736.2000.05.003
    章军峰, 金振民, GreenⅡ, H. W., 等, 2000. 大陆深俯冲带中的水: 来自大别山超高压榴辉岩的证据. 科学通报, 45(17): 1889-1894. doi: 10.3321/j.issn:0023-074X.2000.17.018
    章军峰, 金振民, GreenⅡ, H. W., 2005. 结构水引起的榴辉岩变形组构和变形机制. 科学通报, 50(6): 559-564. doi: 10.3321/j.issn:0023-074X.2005.06.010
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