Volume 29 Issue 1
Jan.  2004
Turn off MathJax
Article Contents
ZHENG Ji, MA Hong-wen, ZHANG Xi-huan, WEN Zhi-hui, 2004. Treatment on Acid Leaching Wastewater from K-Feldspar Powders. Earth Science, 29(1): 59-64.
Citation: ZHENG Ji, MA Hong-wen, ZHANG Xi-huan, WEN Zhi-hui, 2004. Treatment on Acid Leaching Wastewater from K-Feldspar Powders. Earth Science, 29(1): 59-64.

Treatment on Acid Leaching Wastewater from K-Feldspar Powders

  • Received Date: 2003-04-15
  • Publish Date: 2004-01-25
  • After sulfuric acid or hydrochloric acid leaching to remove iron from K-feldspar powders, the filtrate wastewater contains free acid and abundant useful metal ions such as iron. The leaching proportion of iron from K-feldspar powders is 88.3% after treated by the used sulfuric acid. With a purity of 94.1% and 74% respectively, voltaite crystal and solid FeCl3 have been produced by crystallizing in a lower temperature following the vaporization of the wastewater, with 70% iron and 96.5% potassium recovered. No need of high temperature and pressure, and with high efficiency, low energy loss and less pollution, this process proves its effectiveness. The strong acidity, Fe2+ and rather lower concentration of alkalis ions are responsible for voltaite, not jarosite, crystallizing from the acidic iron-bearing water.

     

  • loading
  • Beveridge, D., Day, P., 1979. Charge transfer in mixed-valence solids: Part 9. Preparation, characterization, and optical spectroscopy of the mixed-valence mineral voltaite[aluminium pentairon(Ⅱ)tri-iron dipotassium dodecasulphate 18-hydrate] and its solid solution with cadmium(Ⅱ). J. Chem. Soc. Dalton Trans. , 4: 648-653.
    Chen, J.Y., Yu, S.Q., Wu, Z.C., 1991. Separation and Application of iron in hydrometallurgy industry. Metallurgy Industry Press, Beijing, 93-103(in Chinese).
    Guiyang Institute of Geochemistry, CAS. A handbook of XRD identification of minerals. Science Press, Beijing, 165(in Chinese).
    Grohol, D., Nocera, D.G., 2002. Magnetic minerals made from scratch. Science, 295: 1797.
    Huang, B.L., 1987. A handbook of differential thermal analysis of minerals. Science Press, Beijing, 203-439(in Chinese).
    Sondi, I., Shi, S., Matijevi, E., 2001. Precipitation of monodis-persed basic iron(Ⅲ)sulfate(sodium jarosite)particles. Colloid Polymer Sciences, 279: 161-165. doi: 10.1007/s003960000401
    Shum, M., Lavkulich, L., 1999. Speciation and solubility relationships of Al, Cu and Fe in solutions associated with sulfuric acid leached mine waste rock. Environmental Geology, 38(1): 59-68. doi: 10.1007/s002540050401
    The Editorial Committee of Metal and Other Useful Components Extraction from Solution, 1995. Metal and other useful components extraction from solution. Metallurgy Industry Press, Beijing, 398-399(in Chinese).
    Wang, Z.M., Ma, X.F., Sun, W.T., et al., 1995. Study on acidic purification of diatomite and comprehensive utilization of wastewater. Non-metallic Mines, 1: 16-19(in Chinese with English abstract).
    Yang, Y.Q., Tian, H., Wang, H., 1994. Experiment of producing FeCl3from acidic leaching water using a non-chlorine oxidation method. Environmental Protection of Chemical Industry, 14(2): 88-91(in Chinese with English abstract).
    You, Z.M., 1990. A method of recovery of sulfuric acid leaching water. Chinese Patent, CN104353A.
    Zheng, J., Ma, H.W., Chen, H., et al., 2001. Experimental research into iron removal from K-feldspar powder by acid leaching. Earth Science—Journal of China University of Geosciences, 26(6): 657-666(in Chinese with English abstract).
    Zinck, J. M, Dutrizac, J.E., 1998. The behavior of zinc, cadmium, thallium, tin and selenium during ferrihydrite precipitation from sulphate media. CIM Bulletin, 91(1019): 94-101.
    陈家镛, 于淑秋, 伍志春, 1991. 湿法冶金中铁的分离与应用. 北京: 冶金工业出版社, 93-103.
    黄伯龄, 1987. 矿物差热分析鉴定手册. 北京: 科学出版社, 203-439.
    《溶液中金属及其他有用成分的提取》编委会, 1995. 溶液中金属及其他有用成分的提取. 北京: 冶金工业出版社, 398-399.
    王泽民, 马小凡, 孙文田, 等, 1995. 酸法提纯硅藻土及废酸综合利用研究. 非金属矿, 1: 16-19. https://www.cnki.com.cn/Article/CJFDTOTAL-FJSK501.002.htm
    杨运泉, 田皓, 王浩, 1994. 酸洗废液非氯氧化法生产三氯化铁工业实验. 化工环保, 14(2): 88-91. https://www.cnki.com.cn/Article/CJFDTOTAL-HGHB402.005.htm
    由正明, 1990. 硫酸酸洗废液再生的工艺方法. 中国专利, CN104353A.
    郑骥, 马鸿文, 陈煌, 等, 2001. 钾长石粉酸浸除铁的实验研究. 地球科学———中国地质大学学报, 26(6): 657-666. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200106016.htm
    中国科学院贵阳地球化学所, 1978. 矿物X射线粉晶鉴定手册. 北京: 科学出版社, 165.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(3)  / Tables(6)

    Article views (3562) PDF downloads(2) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return