Volume 28 Issue 2
Mar.  2003
Turn off MathJax
Article Contents
LIU Peng, ZHENG Jian-hua, PI Zhen-bang, QIAO Xue-hua, 2003. Synthesis and Characterization of Magnesium-Aluminum-Indium Hydrotalcite-Like Compounds. Earth Science, 28(2): 163-166.
Citation: LIU Peng, ZHENG Jian-hua, PI Zhen-bang, QIAO Xue-hua, 2003. Synthesis and Characterization of Magnesium-Aluminum-Indium Hydrotalcite-Like Compounds. Earth Science, 28(2): 163-166.

Synthesis and Characterization of Magnesium-Aluminum-Indium Hydrotalcite-Like Compounds

  • Received Date: 2002-05-18
  • Publish Date: 2003-03-25
  • Carbonate pillared Mg-Al-In hydrotalcites were synthesized by coprecipitation. Various preparative factors such as precipitation method, operation temperature, pH value, aging time and n (Mg): n (Al): n (In) molar ratio, which affect the purity and crystal form of Mg-Al-In hydrotalcite-like compound were studied. The results of product characterization by XRD and IR methods show that high supersaturation coprecipitation at constant pH, handing precepitation temperature and aging temperature at 65℃, washing temperature at room temperature, pH ranging from 10 to 11.5, aging for 8 h and n (In3+)/n (M3+) molar ratio ranging from 0.1 to 0.8, may give rise to high purity and better crystal form of Mg-Al-In hydrotalcite-like compounds.

     

  • loading
  • [1]
    Cavani F, Trifiro F, Vaccari A. Hydrotalcite-type anionic clays: preparation, properties and application[J]. Catal Today, 1991, 11: 173-301. doi: 10.1016/0920-5861(91)80068-K
    [2]
    Kaneda K, Yamaguchi K, Mori K, et al. Catalyst design of hydrotalcite compounds for efficient oxidations[J]. Catal Surv Jpn, 2000, 4: 31-38. doi: 10.1023/A:1019048407764
    [3]
    张岩, 王梅祥, 黄志镗, 等. 水相中金属有机化学反应的研究进展[J]. 化学进展, 1999, 4: 394-402. doi: 10.3321/j.issn:1005-281X.1999.04.007

    ZHANG Y, WANG M X, HUANG Z T, et al. Advances in organometallic reactions in aqueous media[J]. Progress in Chemistry, 1999, 4: 394-402. doi: 10.3321/j.issn:1005-281X.1999.04.007
    [4]
    袁耀峰, 曹忠, 胡爱国, 等. 铟试剂在有机合成中的应用[J]. 有机化学, 2000, 3: 269-281. doi: 10.3321/j.issn:0253-2786.2000.03.001

    YUAN Y F, CAO Z, HUAG, et al. Application of indium reagents in organic synthesis[J]. Chinese Journal of Organic Chemistry, 2000, 3: 269-281. doi: 10.3321/j.issn:0253-2786.2000.03.001
    [5]
    Aramendía M A, Borau V, Jiménez C, et al. Synthesis and characterization of a novel Mg/In hydrotalcite-like compound[J]. Mater Lett, 2000, 43: 118-121. doi: 10.1016/S0167-577X(99)00243-8
    [6]
    肖轶, 马骏, 杨锡尧, 等. 碳酸根离子柱撑钴铝水滑石的合成与表征[J]. 催化学报, 1999, 4: 459-462. doi: 10.3321/j.issn:0253-9837.1999.04.020

    XIAO Y, MA J, YANG X Y, et al. Synthesis and characterization of carbonate pillared Co-Al hydrotalcite-like compound[J]. Chinese Journal of Catalysis, 1999, 4: 459-462. doi: 10.3321/j.issn:0253-9837.1999.04.020
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(2)  / Tables(4)

    Article views (3455) PDF downloads(2) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return