塔里木盆地深层海相原油中硫代金刚烷系列化合物的鉴定

朱光有; 王瑞林; 王霆; 文志刚; 张志遥

doi:10.3799/dqkx.2022.414

Volume 48 Issue 2

Feb. 2023

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Article Navigation > Earth Science > 2023 > 48(2): 398-412

Zhu Guangyou, Wang Ruilin, Wang Ting, Wen Zhigang, Zhang Zhiyao, 2023. Identification of Thiadiamondoids in Oil Samples from Tazhong Uplift, Tarim Basin. Earth Science, 48(2): 398-412. doi: 10.3799/dqkx.2022.414

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Zhu Guangyou, Wang Ruilin, Wang Ting, Wen Zhigang, Zhang Zhiyao, 2023. Identification of Thiadiamondoids in Oil Samples from Tazhong Uplift, Tarim Basin. Earth Science, 48(2): 398-412. doi: 10.3799/dqkx.2022.414

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Identification of Thiadiamondoids in Oil Samples from Tazhong Uplift, Tarim Basin

doi: 10.3799/dqkx.2022.414

Zhu Guangyou^{1
,
,},
Wang Ruilin^{1, 2},
Wang Ting²,
Wen Zhigang²,
Zhang Zhiyao^{1, 3}

1.
Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China
2.
College of Resources and Environment, Yangtze University, Wuhan 430100, China
3.
School of Earth Resources, China University of Geosciences, Wuhan 430074, China

Received Date: 2022-12-01
Publish Date: 2023-02-25

Abstract

Abstract

Thiadiamondoids are commonly considered to be typical products of thermochemical sulfate reduction (TSR). Thiadiamondoids have been found in high quantities in crude oil in the Tarim Basin. By using a silver nitrate impregnated silica gel column, organic sulfur compounds (OSC) were separated from the marine oil samples from the Tarim Basin. By using GC⁃MS analysis, 76 compounds were identified in OSC fraction, including all lower thiadiamondoids (1⁃, 2⁃, and 3⁃cage thiadiamondoids), part of higher thiadiamondoids (4⁃, 5⁃, and 6⁃cage thiadiamondoids), and diamondoidthiols. C₀⁃C₂ thiaadamantanes (high volatile thiadiamondoids) comprise nearly half of the total thiaadamantanes in most of the samples. ZS1C and ZS5 samples are special compared with the rest of the samples, in which high volatile thiadiamondoids occupies only about 20% relative abundance. the ratios of thiaadamantanes: thiadiamantanes: thiatriamantanes of these two samples are approximately 4∶4∶1, while those of the other samples are generally 8∶1∶0. Thiadiamondoids can serve as a quantitative indicator of the strength of TSR. The oil sample has migrated, as evidenced by the high ratio of thiaadamantanes and the high relative abundance of high volatile thiadiamondoids. The content differences of thiadiamondoids can effectively indicate the intensity of TSR and to judge whether TSR is in⁃situ, and the OSC component of the TSR product is also present, along with a significant quantity of H₂S gas. It can also provide guidance for the prediction of the distribution and genesis of hydrogen sulfide and petroleum exploration and exploitation decisions in deep strata.
- thiadiamondoid,
- thermochemical sulfate reduction(TSR),
- diamondoidthiol,
- Tarim Basin,
- petroleum geology,

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References(44)

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