豫北山前平原深层地下水硫酸盐来源与污染途径的同位素示踪

邹霜; 张东; 李小倩; 吴洋洋; 李玉红; 朱双双; 刘运涛; 段慧真; 郭文静

doi:10.3799/dqkx.2021.043

Volume 47 Issue 2

Feb. 2022

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Article Navigation > Earth Science > 2022 > 47(2): 700-716

Zou Shuang, Zhang Dong, Li Xiaoqian, Wu Yangyang, Li Yuhong, Zhu Shuangshuang, Liu Yuntao, Duan Huizhen, Guo Wenjing, 2022. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716. doi: 10.3799/dqkx.2021.043

Citation:

Zou Shuang, Zhang Dong, Li Xiaoqian, Wu Yangyang, Li Yuhong, Zhu Shuangshuang, Liu Yuntao, Duan Huizhen, Guo Wenjing, 2022. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716. doi: 10.3799/dqkx.2021.043

Citation:

Zou Shuang, Zhang Dong, Li Xiaoqian, Wu Yangyang, Li Yuhong, Zhu Shuangshuang, Liu Yuntao, Duan Huizhen, Guo Wenjing, 2022. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716. doi: 10.3799/dqkx.2021.043

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Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province

doi: 10.3799/dqkx.2021.043

1.
School of Resource and Environment, Henan Polytechnic University, Jiaozuo 454000, China
2.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
3.
The Fifth Institute of Geo-Exploration, Henan Bureau of Geo-Exploration & Mineral Development, Zhengzhou 450001, China
4.
Henan Province Research Center on Applied Engineering Technology of Hydrogeology, Zhengzhou 450001, China

Received Date: 2021-04-19
Publish Date: 2022-02-25

Abstract

Abstract

Deep groundwater sulfate in the piedmont alluvial plain in Jiaozuo had been increasing, however, the mechanism is still unclear. To illustrate the pollution mechanism of deep groundwater, deep groundwater in different hosting conditions was sampled to compare, and hydro-chemical compositions, hydrogen and oxygen isotopes (δD_H2O and δ¹⁸O_H2O), sulfate sulfur and oxygen isotopes (δ³⁴S_SO4 and δ¹⁸O_SO4) were determined to constrain the sulfate sources, pollution pathways and sulfate bacterial reduction processes with the presence of anthropogenic activities. The results indicated that there were small variations of monthly hydro-chemical and isotope compositions in respective deep groundwaters, but large spatial differences were found in the hydro-chemical compositions of these deep groundwater. Sulfate in the undisturbed deep groundwater was mainly derived from atmospheric deposition, pyrite oxidation and gypsum dissolution, and the bacterial sulfate reduction obviously occurred; There were two kinds of pollution pathways and processes in the polluted deep groundwater. First was that in the piedmont where deep groundwater was recharged, due to no obvious aquifuge between them, the precipitation and river water containing industrial wastes could easily infiltrate into deep groundwater with the result of increasing sulfate concentrations. Second was that in the discharge zone, increased deep groundwater sulfate was related with leapfrog recharge from the above aquifer where sulfate was rich, and the leapfrog recharge was due to overwhelming deep groundwater pumping. Our results well illustrated the sulfate pollution mechanism in deep groundwater underneath the piedmont alluvial plain in Jiaozuo, and provided vitally scientific evidences on effective management and protection of deep groundwater source.
- sulfate sources,
- groundwater bacterial sulfate reduction,
- sulfur and oxygen isotope tracing,
- Bayesian isotope mixing model,
- Piedmont alluvial plain,
- hydrogeology

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References(76)

References

Balci, N., Shanks, Iii., W, C., Mayer, B., et al., 2007. Oxygen and Sulfur Isotope Systematics of Sulfate Produced by Bacterial and Abiotic Oxidation of Pyrite. Geochimica et Cosmochimica Acta, 71(15): 3796-3811. https://doi.org/10.1016/j.gca.2007.04.017

Egbi, C.D., Anormu, G. K., Ganyaglo, S. Y., et al., 2020. Nitrate Contamination of Groundwater in the Lower Volta River Basin of Ghana: Sources and Related Human Health Risks. Ecotoxicology and Environmental Safety, 191: 110227. https://doi.org/10.1016/j.ecoenv.2020.110227

Fan, B. L., Zhang, D., Tao, Z. H., et al., 2017. Compositions of Hydrogen and Oxygen Isotope Values of Yellow River Water and the Response to Climate Change. China Environmental Science, 37(5): 1906-1914(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-ZGHJ201705038.htm

Fan, B.L., Zhao, Z. Q., Tao, F. X., et al., 2014. Characteristics of Carbonate, Evaporite and Silicate Weathering in Huanghe River Basin: A Comparison among the Upstream, Midstream and Downstream. Journal of Asian Earth Sciences, 96: 17-26. https://doi.org/10.1016/j.jseaes.2014.09.005

Fouillac, C., Fouillac, A.M., Criaud, A., 1990. Sulphur and Oxygen Isotopes of Dissolved Sulphur Species in Formation Waters from the Dogger Geothermal Aquifer, Paris Basin, France. Applied Geochemistry, 5(4): 415-427. https://doi.org/10.1016/0883-2927(90)90018-Z

Gilhooly, III. W.P., Reinhard, C.T., Lyons, T.W., 2016. A Comprehensive Sulfur and Oxygen Isotope Study of Sulfur Cycling in a Shallow, Hyper-Euxinic Meromictic Lake. Geochimica et Cosmochimica Acta, 189: 1-23. https://doi.org/10.1016/j.gca.2016.05.044

Guo, H., Zhou, Y., Jia, Y., et al., 2016. Sulfur Cycling-Related Biogeochemical Processes of Arsenic Mobilization in the Western Hetao Basin, China: Evidence from Multiple Isotope Approaches. Environmental Science & Technology, 50(23): 12650-12659. https://doi.org/10.1021/acs.est.6b03460

He, J.Y., Zhang, D., Zhao, Z.Q., 2017. Spatial and Temporal Variations in Hydrochemical Composition of River Water in Yellow River Basin, China. Chinese Journal of Ecology, 36(5): 1390-1401(in Chinese with English abstract). http://www.cnki.com.cn/Article/CJFDTotal-STXZ201705028.htm

Holser, W.T., Kaplan, I.R., Sakai, H., et al., 1979. Isotope Geochemistry of Oxygen in the Sedimentary Sulfate Cycle. Chemical Geology, 25(1): 1-17. https://doi.org/10.1016/0009-2541(79)90079-2

Hong, Y.T., Zhang, H.B., Zhu, Y.X., et al., 1994. Sulfur Isotopic Composition of Precipitation in China. Advancesin Natural Sciences-Correspondence of State Key Laboratories, 4(6): 741-745(in Chinese).

Huang, Q.B., Qin, X.Q., Liu, P.Y., et al., 2014. The Characteristics and Influencing Factors of SO₄^2- and Sulfate Isotope(δ³⁴S) in Different Types of Groundwater in Fenyang, ShanXi Province. Quaternary Sciences, 34(2): 364-371(in Chinesewith English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DSJJ201402010.htm

Jia, X. S., Zhang, D., Zhao, Z. Q., 2016. Hydrogen and Oxygen Isotopic Compositions of Groundwater and Surface Water in South Piedmont Plain of Taihang Mountain and Its Environmental Significance. Earth and Environment, 44(3): 281-289(in Chinesewith English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZDQ201603001.htm

Jiao, Y. J., Wang, G. C., Cui, L. F., et al., 2014. Characteristics of Hydrochemistry and Stable Hydrogen, Oxygen Isotopes in Surface Water and Groundwater in Jiyuan Basin. Environment Chemistry, 33(6): 962-968(in Chinese with English abstract). http://d.wanfangdata.com.cn/periodical/hjhx201406015

Lang, Y. C., Liu, C. Q., Satake, H., et al., 2008. δ³⁷Cl and δ³⁴S Variations of Cl^- and SO₄^2- in groundwater and Surface Water of Guiyang Area, China. Advances in Earth Science, (2): 151-159(in Chinesewith English abstract). http://www.researchgate.net/publication/288930235_d37_Cl_and_d34S_Variations_of_Cl-_and_SO42-_in_groundwater_and_surface_water_of_Guiyang_area_China_J

Li, W. P., Wang, L. F., Yang, H. F., et al., 2020a. The Groundwater Overexploitation Status and Countermeasure Suggestions of the North China Plain. China Water Resources, (13): 26-30(in Chinese with English abstract).

Li, X., Tang, C., Cao, Y., et al., 2020b. A Multiple Isotope (H, O, N, C and S) Approach to Elucidate the Hydrochemical Evolution of Shallow Groundwater in a Rapidly Urbanized Area of the Pearl River Delta, China. Science of The Total Environment, 724: 137930. https://doi.org/10.1016/j.scitotenv.2020.137930

Li, X., Zhou, A., Gan, Y., et al., 2011. Controls on the δ³⁴S and δ¹⁸O of Dissolved Sulfate in the Quaternary Aquifers of the North China Plain. Journal of Hydrology, 400(3-4): 312-322. https://doi.org/10.1016/j.jhydrol.2011.01.034

Li, X.D., Liu, C. Q., Harue, M., et al., 2010. The Use of Environmental Isotopic (C, Sr, S) and Hydrochemical Tracers to Characterize Anthropogenic Effects on Karst Groundwater Quality: A Case Study of the Shuicheng Basin, SW China. Applied Geochemistry, 25(12): 1924-1936. https://doi.org/10.1016/j.apgeochem.2010.10.008

Liu, F., Wang, S., Yeh, T. J., et al., ,2020. Using Multivariate Statistical Techniques and Geochemical Modeling to Identify Factors Controlling the Evolution of Groundwater Chemistry in a Typical Transitional Area between Taihang Mountain and North China Plain. Hydrological Processes, 34(8): 1888-1905. https://doi.org/10.1002/hyp.13701

Liu, Y. T., Zhang, D., Zhao, Z. Q., 2017. Hydro-Chemical and Isotopic Compositions of Groundwater in Piedmont Plain of the South Taihang Mountain. Earth and Environment, 45(2): 203-213(in Chinesewith English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZDQ201702012.htm

Markovic, S., Paytan, A., Li, H., et al., 2016. A Revised Seawater Sulfate Oxygen Isotope Record for the Last 4 Ma. Geochimica et Cosmochimica Acta, 175: 239-251. https://doi.org/10.1016/j.gca.2015.12.005

Parnell, A.C., Inger, R., Bearhop, S., et al., 2010. Source Partitioning Using Stable Isotopes: Coping with too Much Variation. PloS one, 5(3): e9672. https://doi.org/10.1371/journal.pone.0009672

Pei, J. G., Tao, Y.L., Tong, C.S., 1993. Environmental Isotope of Natural Water and Its Application in Karst Hydrogeologyin Jiaozuo Area. Carsologica Sinica, 12(1): 45-53(in Chinesewith English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZGYR199301005.htm

Qin, Y., Zhang, D., Zhao, Z. Q., 2016. Spatial and Temporal Variations of Hydrochemical Compositions of River Water in Qinhe Basin. Chinese Journal of Ecology, 35(6): 1516-1524(in Chinese with English abstract). http://www.cqvip.com/QK/90811X/201606/669054175.html

Shi, J.S., Li, G.M., Liang, X., et al., 2014. Evolution Mechanism and Control of Groundwater in the North China Plain. Acta Geoscientica Sinica, 35(5): 527-534(in Chinese with English abstract).

Song, H. B., Zhang, Z. J., Fei, Y. H., et al., 2007. Down-Movement of the Fresh-Saline Groundwater Interface in the Middle of the Hebei Plain under the Condition of Exploitation. Hydrogeology and Engineering Geology, (1): 44-46, 52(in Chinesewith English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SWDG200701009.htm

Song, X. Q., Peng, Q., Wang, W., et al., 2019. Analysis of Environmental Background Valuesof Chloride and Sulfate in Shallow Groundwater in Karst Area of Guizhou. Earth Science, 44(11): 3926-3938(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-DQKX201911027.htm

Turchyn, A.V., Tipper, E.T., Galy, A., et al., 2013. Isotope Evidence for Secondary Sulfide Precipitation along the Marsyandi River, Nepal, Himalayas. Earth and Planetary Science Letters, 374: 36-46. https://doi.org/10.1016/j.epsl.2013.04.033

Tuttle, M.L.W., Breit, G.N., Cozzarelli, I.M., 2009. Processes Affecting δ³⁴S and δ¹⁸O values of Dissolved Sulfate in Alluvium along the Canadian River, Central Oklahoma, USA. Chemical Geology, 265(3-4): 455-467. https://doi.org/10.1016/j.chemgeo.2009.05.009

Wang, H. C., 1991. Introduction to Isotopic Hydrogeology. Geology Press, Beijing, 191(in Chinese).

Wang, Y. J., Hu, Y. Y., Sheng, J. F., et al., 2011. Sulfur and Lead Isotope Composition and Tracing for Sources of Ore-Forming Materials in Beiming River Iron Deposits, Southern Taihang Mountains. Geoscience, 25(5): 846-852(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-XDDZ201105008.htm

Wang, Y. T., Li, J. X., Xue, X. B., et al., 2021. Similarities and Differences of Main Controlling Factors of Natural High Iodine Groundwater between North China Plain and Datong Basin. Earth Science, 46(1): 308-320(in Chinese with English abstract). http://www.sciencedirect.com/science/article/pii/S0269749121010642

Xiao, H. Y., Liu, C.Q., 2011. The Elemental and Isotopic Composition of Sulfur and Nitrogen in Chinese coals. Organic Geochemistry, 42(1): 84-93. https://doi.org/10.1016/j.orggeochem.2010.10.011

Xiao, H. Y., Liu, C. Q., Li, S. L., 2003. Geochemical Characteristics of Sulfur and Nitrogen Isotopic Compositions in Rains of Guiyang in Summer. Geochimica, 32(3): 248-254(in Chinesewith English abstract). http://www.researchgate.net/publication/288882911_Geochemical_characteristics_of_sulfur_and_nitrogen_isotopic_compositions_in_rains_of_Guiyang_in_summer

Xie, X., Ellis, A., Wang, Y., et al., 2009. Geochemistry of Redox-SensitiveElements and Sulfur Isotopes in the High Arsenic Groundwater System of Datong Basin, China. Science of The Total Environment, 407(12): 3823-3835. https://doi.org/10.1016/j.scitotenv.2009.01.041

Xie, X., Wang, Y., Ellis, A., et al., 2013. Multiple Isotope (O, S and C) Approach Elucidates the Enrichment of Arsenic in the Groundwater from the Datong Basin, Northern China. Journal of Hydrology, 498: 103-112. https://doi.org/10.1016/j.jhydrol.2013.06.024

Xue, X. B., Li, J. X., Qian, K., et al., 2018. Spatial Distribution and Mobilization of Iodine in Groundwater System of North China Plain: Taking Hydrogeological Section from Shijiazhuang, Hengshui to Cangzhou as an Example. Earth Science, 43(3): 910-921(in Chinese with English abstract). http://europepmc.org/abstract/MED/29611121

Xue, D., De, Baets. B., Botte, J., et al., 2012. Use of a Bayesian Isotope Mixing Model to Estimate Proportional Contributions of Multiple Nitrate Sources in Surface Water. Environmental Pollution, 161: 43-49. https://doi.org/10.1016/j.envpol.2011.09.033

Yang, X.C., Sheng, Z.L., Wen, D.G., et al., 2008. Hydrochemical Characteristics and Sources of Sulfate in Groundwater of the Ordoscretaceous Goundwater Basin. Acta Geoscientica Sinica, (5): 553-562(in Chinese with English abstract). http://en.cnki.com.cn/article_en/cjfdtotal-dqxb200805004.htm

Yang, L. Z., Qu, W. L., Zhang, Y., et al., 2013. A Discussion on Deep Groundwater Origin of Dezhou in Shandong Province Based on Water Chemical Composition and Environmental Isotopic Information. Acta Geoscientica Sinica, 34(4): 463-469(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DQXB201304011.htm

Zhang, D., Li, X.D., Zhao, Z.Q., et al., 2015. Using Dual Isotopic Data to Rack the Sources and Behaviors of Dissolved Sulfate in the Western North China Plain. Applied Geochemistry, 52: 43-56. https://doi.org/10.1016/j.apgeochem.2014.11.011

Zhang, D., Huang, X. Y., Li, C. J., 2013. Sources of Riverine Sulfate in Yellow River and Its Tributaries Determined by Sulfur and Oxygen Isotopes. Advances in Water Science, 24(3): 418-426(in Chinesewith English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SKXJ201303017.htm

Zhang, D., Li, Y. H., Zhang, H.Y., 2019a. Application of Modified DDARP Method for Purification of Barite in Natural Water Samples. Rock and Mineral Analysis, 38(1): 77-84(in Chinese with English abstract). http://www.researchgate.net/publication/342782405_Application_of_Modified_DDARP_Method_for_Purification_of_Barite_in_Natural_Water_Samples

Zhang, Q., Wang, H., Lu, C., 2020. Tracing Sulfate Origin and Transformation in an Area with Multiple Sources of Pollution in Northern China by Using Environmental Isotopes and Bayesian Isotope Mixing Model. Environmental Pollution, 265: 115105. https://doi.org/10.1016/j.envpol.2020.115105

Zhang, D., Liu, C.Q., Wang, F.S., et al., 2015. Inorganic Carbon Cycling in Subsurface Environment Influenced by Agricultural Activities. China Environmental Science, 35(11): 3359-3370(in Chinese with English abstract). http://www.researchgate.net/profile/Zhi_Qi_Zhao2/publication/288230069_Inorganic_carbon_cycling_in_subsurface_environment_influenced_by_agricultural_activities/links/56e4e74408ae98445c1ef9d1/Inorganic-carbon-cycling-in-subsurface-environment-influenced-by-agricultural-activities.pdf

Zhang, D., Yang, J.M., Huang, X.Y., et al., 2019b. Sources of Dissolved Heavy Metals in River Water of the Yiluo River Basin Based on Sulfur Isotope of Sulfate. China Environmental Science, 39(6): 2549-2559(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-ZGHJ201906042.htm

Zhang, H.L., Wang, C., Pang, W., et al., 2019. Using Sulfur and Oxygen Isotope to Trace the Source of Sulphate in Baotuquan Spring Area of Jinan. Geological Survey of China, 6(1): 75-80(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-DZDC201901011.htm

Zhang, Z.J., Fei, Y.H., Guo, C.Y., et al., 2012. Regional Groundwater Contamination Assessment in the North China Plain. Journal of Jilin University(Earth Science Edition), 42(5): 1456-1461(in Chinese with English abstract). http://www.researchgate.net/publication/281604046_Regional_groundwater_contamination_assessment_in_the_North_China_Plain

Zhou, J., Zhang, Y., Zhou, A., et al., 2016. Application of Hydrochemistry and Stable Isotopes (δ³⁴S, δ¹⁸O and δ³⁷Cl) to Trace Natural and Anthropogenic Influences on the Quality of Groundwater in the Piedmont Region, Shijiazhuang, China. Applied Geochemistry, 71: 63-72. https://doi.org/10.1016/j.apgeochem.2016.05.018

范百龄, 张东, 陶正华, 等, 2017. 黄河水氢、氧同位素组成特征及其气候变化响应. 中国环境科学, 37(5): 1906-1914. doi: 10.3969/j.issn.1000-6923.2017.05.038

何姜毅, 张东, 赵志琦, 2017. 黄河流域河水水化学组成的时间和空间变化特征. 生态学杂志, 36(5): 1390-1401. https://www.cnki.com.cn/Article/CJFDTOTAL-STXZ201705028.htm

洪业汤, 张鸿斌, 朱詠煊, 等, 1994. 中国大气降水的硫同位素组成特征. 自然科学进展: 国家重点实验室通讯, 4(6): 741-745. doi: 10.3321/j.issn:1002-008X.1994.06.013

黄奇波, 覃小群, 刘朋雨, 等, 2014. 汾阳地区不同类型地下水SO₄^2-、δ³⁴S的特征及影响因素. 第四纪研究, 34(2): 364-371. doi: 10.3969/j.issn.1001-7410.2014.02.10

贾新生, 张东, 赵志琦, 2016. 南太行山山前平原地下水和地表水氢氧同位素组成及环境意义. 地球与环境, 44(3): 281-289. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201603001.htm

焦艳军, 王广才, 崔霖峰, 等, 2014. 济源盆地地表水和地下水的水化学及氢、氧同位素特征. 环境化学, 33(6): 962-968. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX201406015.htm

郎赟超, 刘丛强, Satake H., 等, 2008. 贵阳地表水-地下水的硫和氯同位素组成特征及其污染物示踪意义. 地球科学进展(2): 151-159. doi: 10.3321/j.issn:1001-8166.2008.02.005

李文鹏, 王龙凤, 杨会峰, 等, 2020. 华北平原地下水超采状况与治理对策建议. 中国水利, (13): 26-30. doi: 10.3969/j.issn.1000-1123.2020.13.017

刘运涛, 张东, 赵志琦, 2017. 南太行山山前平原地下水水化学以及同位素组成研究. 地球与环境, 45(2): 203-213. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201702012.htm

裴建国, 陶友良, 童长水, 1993. 焦作地区天然水环境同位素组成及其在岩溶水文地质中的应用. 中国岩溶, 12(1): 45r53. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGYR199301005.htm

秦勇, 张东, 赵志琦, 2016. 沁河流域水化学组成的空间和时间变化特征. 生态学杂志, 35(6): 1516-1524. https://www.cnki.com.cn/Article/CJFDTOTAL-STXZ201606017.htm

石建省, 李国敏, 梁杏, 等, 2014. 华北平原地下水演变机制与调控. 地球学报, 35(5): 527-534. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201405001.htm

宋海波, 张兆吉, 费宇红, 等, 2007. 开采条件下河北平原中部咸淡水界面下移. 水文地质工程地质, (1): 44-46, 52. doi: 10.3969/j.issn.1000-3665.2007.01.009

宋小庆, 彭钦, 王伟, 等, 2019. 贵州岩溶区浅层地下水氯化物及硫酸盐环境背景值. 地球科学, 44(11): 3926-3938. doi: 10.3799/dqkx.2019.166

王恒纯, 1991. 同位素水文地质概论. 北京: 地质出版社, 191.

王艳娟, 胡援越, 申俊峰, 等, 2011. 太行山南段北洺河铁矿S、Pb同位素组成及其对成矿物质来源的示踪. 现代地质, 25(5): 846-852. doi: 10.3969/j.issn.1000-8527.2011.05.003

王雨婷, 李俊霞, 薛肖斌, 等, 2021. 华北平原与大同盆地原生高碘地下水赋存主控因素的异同. 地球科学, 46(1): 308-320. doi: 10.3799/dqkx.2019.261

肖化云, 刘丛强, 李思亮, 2003. 贵阳地区夏季雨水硫和氮同位素地球化学特征. 地球化学, 32(3): 248-254. doi: 10.3321/j.issn:0379-1726.2003.03.006

薛肖斌, 李俊霞, 钱坤, 等, 2018. 华北平原原生富碘地下水系统中碘的迁移富集规律: 以石家庄-衡水-沧州剖面为例. 地球科学, 43(3): 910-921. doi: 10.3799/dqkx.2017.564

杨丽芝, 曲万龙, 张勇, 等, 2013. 基于水化学组分和环境同位素信息探讨山东德州深层承压地下水起源. 地球学报, 34(4): 463-469. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201304011.htm

杨郧城, 沈照理, 文冬光, 等, 2008. 鄂尔多斯白垩系地下水盆地硫酸盐的水文地球化学特征及来源. 地球学报(5): 553-562. doi: 10.3321/j.issn:1006-3021.2008.05.003

张东, 黄兴宇, 李成杰, 2013. 硫和氧同位素示踪黄河及支流河水硫酸盐来源. 水科学进展, 24(3): 418-426. https://www.cnki.com.cn/Article/CJFDTOTAL-SKXJ201303017.htm

张东, 李玉红, 张鸿禹, 2019a. 应用改进DDARP方法纯化天然水体样品中硫酸钡固体的效果评价. 岩矿测试, 38(1): 77-84. https://www.cnki.com.cn/Article/CJFDTOTAL-YKCS201901011.htm

张东, 杨锦媚, 黄兴宇, 等, 2019b. 基于硫酸盐硫同位素的伊洛河流域河水溶解性重金属来源. 中国环境科学, 39(6): 2549-2559. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGHJ201906042.htm

张东, 刘丛强, 汪福顺, 等, 2015. 农业活动干扰下地下水无机碳循环过程研究. 中国环境科学, 35(11): 3359-3370. doi: 10.3969/j.issn.1000-6923.2015.11.022

张海林, 王重, 逄伟, 等, 2019. 硫氧同位素示踪污染物来源在济南岩溶水中的应用. 中国地质调查, 6(1): 75-80. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDC201901011.htm

张兆吉, 费宇红, 郭春艳, 等, 2012. 华北平原区域地下水污染评价. 吉林大学学报(地球科学版), 42(5): 1456-1461. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201205019.htm

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Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province

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