三斜水钠锰矿层间阳离子交换作用的拉曼谱学

段鉴书; 李艳; 许晓明; 丁竑瑞; 刘菲菲; 鲁安怀

doi:10.3799/dqkx.2018.416

Volume 43 Issue 5

May 2018

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Article Navigation > Earth Science > 2018 > 43(5): 1623-1634

Duan Jianshu, Li Yan, Xu Xiaoming, Ding Hongrui, Liu Feifei, Lu Anhuai, 2018. Raman Spectroscopy of Ion Exchange in Interlayer of Triclinic Birnessite. Earth Science, 43(5): 1623-1634. doi: 10.3799/dqkx.2018.416

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Duan Jianshu, Li Yan, Xu Xiaoming, Ding Hongrui, Liu Feifei, Lu Anhuai, 2018. Raman Spectroscopy of Ion Exchange in Interlayer of Triclinic Birnessite. Earth Science, 43(5): 1623-1634. doi: 10.3799/dqkx.2018.416

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Raman Spectroscopy of Ion Exchange in Interlayer of Triclinic Birnessite

doi: 10.3799/dqkx.2018.416

Duan Jianshu^{1,2,3
,},
Li Yan^{1,2,3
,
,},
Xu Xiaoming^1,2,3,
Ding Hongrui^1,2,3,
Liu Feifei^1,2,3,
Lu Anhuai^1,2,3

1.
Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, Peking University, Beijing 100871, China
2.
Beijing Key Laboratory of Mineral Environmental Function, Peking University, Beijing 100871, China
3.
School of Earth and Space Sciences, Peking University, Beijing 100871, China

Received Date: 2017-09-07
Publish Date: 2018-05-15

Abstract

Abstract

Birnessite is a group of manganese oxide minerals widely found in nature. However, its ion exchange behavior and structural transformation have not been fully understood, and the characterization techniques are limited. To study the ion exchange behavior of birnessite and the reflection of structural transformation in Raman spectroscopy, triclinic Na-birnessite was synthesized using MnSO₄ and NaOH, and ion exchange experiments on NH₄⁺, K⁺, Mg²⁺, Ca²⁺, Ba²⁺, Co²⁺, and Zn²⁺ were carried out. Ion exchange birnessite samples were characterized using ICP-OES, XRD, and Raman spectroscopy. Raman study shows the relative strength of two stretching vibration modes in[MnO₆] octahedra around 570-585 cm^-1 and 640-655 cm^-1 and the band location of the mode around 570-585 cm^-1 are indicators of the symmetry of birnessite. High strength and frequency of the mode around 570-585 cm^-1 are signs of triclinic symmetry. Raman bands around 280 cm^-1 and 500 cm^-1 are indicators of interlayer cations. If alkalis and alkaline-earth metals (i.e., Na⁺, K⁺, Mg²⁺, Ca²⁺, Ba²⁺, etc.) are in the interlayer of birnessite, a band around 280 cm^-1 and two separate bands around 500 cm^-1 will appear; whereas other interlayer cations only give rise to one single band at 500 cm^-1, indicating disorder in the interlayer.
- birnessite,
- ion exchange,
- Raman spectroscopy,
- structural symmetry,
- interlayer distance,
- mineralogy

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References(57)

References

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