样品保存过程中降解对GDGTs环境代用指标的影响

张佳皓; 裴宏业; 赵世锦; 李越; 杨欢

doi:10.3799/dqkx.2018.319

Volume 45 Issue 1

Jan. 2020

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Article Navigation > Earth Science > 2020 > 45(1): 317-329

Zhang Jiahao, Pei Hongye, Zhao Shijin, Li Yue, Yang Huan, 2020. The Impact of Degradation on the Tetraether-Based Proxies during the Sample Storage. Earth Science, 45(1): 317-329. doi: 10.3799/dqkx.2018.319

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Zhang Jiahao, Pei Hongye, Zhao Shijin, Li Yue, Yang Huan, 2020. The Impact of Degradation on the Tetraether-Based Proxies during the Sample Storage. Earth Science, 45(1): 317-329. doi: 10.3799/dqkx.2018.319

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The Impact of Degradation on the Tetraether-Based Proxies during the Sample Storage

doi: 10.3799/dqkx.2018.319

Zhang Jiahao^{1,2
,
,},
Pei Hongye²,
Zhao Shijin²,
Li Yue²,
Yang Huan^{1,2
,
,}

1.
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, China
2.
School of Earth Sciences, China University of Geosciences, Wuhan 430074, China

Received Date: 2018-08-19
Publish Date: 2020-01-15

Abstract

Abstract

The glycerol dialkyl glycerol ether (GDGTs) may be subjected to degradation during the sample storage, which may have an effect on the application of GDGTs. Thus, it is important to understand the resistance of GDGTs compounds to degradation for the accurate application of GDGT derived proxies. In this study, the extractions (GDGTs) of stalagmite sample from the year of 2012 was reanalyzed in 2017. It is found that the absolute concentration of GDGTs has decreased and the relative content of each component has changed significantly. The change of the concentration of bacterial brGDGT is smaller than that of the archaeal isoGDGTs, which corresponds to the decreased R_i/b value and increased BIT values. Therefore, compared to the isoGDGTs, the brGDGTs are more stable during the processes of degradation. Smaller changes of the concentration of archaeal isoGDGTs of less-cyclic-moieties and increasing CBT values indicate that GDGTs with fewer rings tend to be more stable during the degradation processes. The isoGDGTs based TEX₈₆ values also decrease significantly. The increasing of the brGDGTs based MBT values show that GDGTs with more cyclopentyl moieties are more easily to be degraded.
- GDGTs,
- degradation,
- TEX₈₆,
- MBT/CBT,
- R_i/b,
- BIT,
- environmental geology

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References(47)

References

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The Impact of Degradation on the Tetraether-Based Proxies during the Sample Storage

doi: 10.3799/dqkx.2018.319

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