湖相富有机质泥质白云岩生排烃模拟及其对页岩油勘探的启示

李志明; 郑伦举; 蒋启贵; 马中良; 陶国亮; 徐二社; 钱门辉; 刘鹏; 曹婷婷

doi:10.3799/dqkx.2018.025

Volume 43 Issue 2

Feb. 2018

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Article Navigation > Earth Science > 2018 > 43(2): 566-576

Li Zhiming, Zheng Lunju, Jiang Qigui, Ma Zhongliang, Tao Guoliang, Xu Ershe, Qian Menhui, Liu Peng, Cao Tingting, 2018. Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration. Earth Science, 43(2): 566-576. doi: 10.3799/dqkx.2018.025

Citation:

Li Zhiming, Zheng Lunju, Jiang Qigui, Ma Zhongliang, Tao Guoliang, Xu Ershe, Qian Menhui, Liu Peng, Cao Tingting, 2018. Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration. Earth Science, 43(2): 566-576. doi: 10.3799/dqkx.2018.025

Citation:

Li Zhiming, Zheng Lunju, Jiang Qigui, Ma Zhongliang, Tao Guoliang, Xu Ershe, Qian Menhui, Liu Peng, Cao Tingting, 2018. Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration. Earth Science, 43(2): 566-576. doi: 10.3799/dqkx.2018.025

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Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration

doi: 10.3799/dqkx.2018.025

Li Zhiming^{1,2,3,4
,},
Zheng Lunju^1,2,3,4,
Jiang Qigui^1,2,3,4,
Ma Zhongliang^1,2,3,4,
Tao Guoliang^1,2,3,4,
Xu Ershe^1,2,3,4,
Qian Menhui^1,2,3,4,
Liu Peng^1,2,3,4,
Cao Tingting^1,2,3,4

1.
Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi 214126, China
2.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Wuxi 214126, China
3.
State Energy Center for Shale Oil Research and Development, Wuxi 214126, China
4.
Key Laboratory of Petroleum Accumulation Mechanisms, SINOPEC, Wuxi 214126, China

Received Date: 2017-07-14
Publish Date: 2018-02-15

Abstract

Abstract

The organic-rich lacustrine dolomitic mudstone, argillaceous dolomite, organic-poor siltstone and dolomite interlayer are important areas for shale oil exploration in terrestrial basins in China. However, the research on the integration of hydrocarbon generation, expulsion and hydrocarbon accumulation in the lacustrine organic-rich dolomitic mudstone or argillaceous dolomite under near geological conditions is still blank. An integrate experiment of hydrocarbon generation and expulsion simulation from argillaceous dolomite rich in organic matter under near geological condition in confined systems, has been carried out with typical lower mature organic-rich argillaceous dolomite. The four-stage of hydrocarbon generation and expulsion evolution model is revealed. The results show that the first stage is characterized by relatively slow oil generation associated hydrocarbon gases and by limited ability of oil expulsion when R_o is ≤ 0.74%. The second stage is characterized by rapid oil generation associated hydrocarbon gases and with incremental ability of oil expulsion when R_o is in the range of 0.74%-0.84%. The third stage is characterized by hydrocarbon gas generation associated oil and oil initial cracking, and by oil expulsion effectively at 0.84% < R_o ≤ 1.28%≈1.30%. The fourth stage is characterized by oil cracking into hydrocarbon gas associated hydrocarbon gases generation from kerogen when R_o is > 1.30%. And the retained oil is mainly occurred as adsorption phase with organic matter at R_o < 0.68%, and mainly occurred as free phase within micron to nano-scale pores and microfractures in mineral matrix of argillaceous dolomite at 0.68% ≤ R_o ≤ 2.00%. The range of thermal maturity for favorable shale oil exploration within lacustrine dolomite measures, is proposed at 0.84%-1.30%, on the basis of the results of simulation of hydrocarbon generation and expulsion for lacustrine organic-rich argillaceous dolomite, integrated with geological conditions and exploring economic benefit.
- lacustrine,
- organic-rich argillaceous dolomite,
- simulation of hydrocarbon generation and expulsion,
- occurrence,
- maturity,
- petroleum geology

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Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration

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