秭归地区震旦系陡山沱组碳酸盐岩结核成因新认识及其地质意义

张明正; 彭松柏; 张利; 方家松; 张先进; 韩庆森

doi:10.3799/dqkx.2016.138

Volume 41 Issue 12

Dec. 2016

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Article Navigation > Earth Science > 2016 > 41(12): 1977-1994

Zhang Mingzheng, Peng Songbai, Zhang Li, Fang Jiasong, Zhang Xianjin, Han Qingsen, 2016. New Recognition of Carbonate Nodules Genesis in Sinian Doushantuo Formation in Zigui Area and Its Geological Implication. Earth Science, 41(12): 1977-1994. doi: 10.3799/dqkx.2016.138

Citation:

Zhang Mingzheng, Peng Songbai, Zhang Li, Fang Jiasong, Zhang Xianjin, Han Qingsen, 2016. New Recognition of Carbonate Nodules Genesis in Sinian Doushantuo Formation in Zigui Area and Its Geological Implication. Earth Science, 41(12): 1977-1994. doi: 10.3799/dqkx.2016.138

Citation:

Zhang Mingzheng, Peng Songbai, Zhang Li, Fang Jiasong, Zhang Xianjin, Han Qingsen, 2016. New Recognition of Carbonate Nodules Genesis in Sinian Doushantuo Formation in Zigui Area and Its Geological Implication. Earth Science, 41(12): 1977-1994. doi: 10.3799/dqkx.2016.138

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New Recognition of Carbonate Nodules Genesis in Sinian Doushantuo Formation in Zigui Area and Its Geological Implication

doi: 10.3799/dqkx.2016.138

1.
School of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2.
Geologic Party No.216, China National Nuclear Corporation, Urumqi 830011, China
3.
Center for Global Tectonics, China University of Geosciences, Wuhan 430074, China
4.
State Key Laboratory of Marine Geology, Tongji University, Shanghai 200092, China

Received Date: 2016-05-24
Publish Date: 2016-12-15

Abstract

Abstract

The carbonate nodules with strongly negative δ¹³C anomalies are widely developed in the black muddy shale in the forth member of the Doushantuo Formation from the Sinian System in the Zigui area, Yangtze Craton. Whether they were related to leakage of gas hydrate deserves further studies. Studies of sedimentary structure, petrography and geochemistry of these carbonate nodules show that these nodules have typical oscillatory zoning, sparry sphere structure, framboidal pyrite and agglomerate fabrics, which are related to venting system. The carbonate nodules display obvious negative δ¹³C anomalies (-5.65‰ to -6.76‰), strong enrichment of U and Mo elements (U_EF=8-26, Mo_EF=99-320) and Y/Ho ratios between 31.05 and 37.31. Their REE distributions display gentle left-sloping patterns and their major and trace elements such as K, Sc, V, Cr, Co, Ni, Rb, Sr, Ba, Th, U and Mo indicate a hypoxia and sulfidic setting, which is consistent with characteristics and formation environment of cold seep carbonates. SiO₂, MgO, CaO and CO₂ contents of oscillatory zoning within the nodules show continuously increase or decrease changes, respectively. They reflect three stages of continuous evolution processes including primary formation, subsequent diagenesis-metasomatism and final diagenetic reworking. Accordingly, it can be proposed that these carbonate nodules were ultimately developed as decomposition, diagenesis and metasomatism of the low temperature stored solid gas hydrate sediment in the black muddy shale when the temperature became higher after the Neoproterozoic Gaskiers glaciation (582-551 Ma). This study provides an important record that confirms existence of the ancient natural gas hydrate and offers an important geological evidence for exploring shale gas (methane gas) reservoirs in the Sinian System and Lower Paleozoic sedimentary covers in the Yangtze Craton of South China.
- Yangtze Craton,
- Zigui area,
- fourth member of Doushantuo Formation,
- ancient natural gas hydrate,
- cold seep carbonate nodule,
- geochemistry

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References(123)

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New Recognition of Carbonate Nodules Genesis in Sinian Doushantuo Formation in Zigui Area and Its Geological Implication

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