埋藏环境中硫酸盐岩生物岩溶作用的硫同位素证据

张凤娥; 卢耀如; 殷密英; 张胜; 王哲; 宋淑红

doi:10.3799/dqkx.2012.042

Volume 37 Issue 2

Mar. 2012

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Article Navigation > Earth Science > 2012 > 37(2): 357-364

ZHANG Feng-e, LU Yao-ru, YIN Mi-ying, ZHANG Sheng, WANG Zhe, SONG Shu-hong, 2012. Sulfur Isotopic Evidence for Biological Karst of Sulfate Rocks in Burial Environment. Earth Science, 37(2): 357-364. doi: 10.3799/dqkx.2012.042

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ZHANG Feng-e, LU Yao-ru, YIN Mi-ying, ZHANG Sheng, WANG Zhe, SONG Shu-hong, 2012. Sulfur Isotopic Evidence for Biological Karst of Sulfate Rocks in Burial Environment. Earth Science, 37(2): 357-364. doi: 10.3799/dqkx.2012.042

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Sulfur Isotopic Evidence for Biological Karst of Sulfate Rocks in Burial Environment

doi: 10.3799/dqkx.2012.042

Institute of Hydrogeology & Environmental Geology, Chinese Academy of Geological Sciences, Shijiazhuang 050061, China

Received Date: 2010-09-12
Publish Date: 2012-03-15

Abstract

Abstract

The purpose of this study is to explore the biological karst developing mechanism at the coexistence condition of the sulfate and carbonate rock. The study focuses on the geochemical processes in water-rock-bacteria system by tracing the stable sulfur isotope (³⁴S) fractionation through laboratory experiment combined with the isotope data of the pyrite filling in Ordovician weathering crust in the Ordos basin. The results suggest that the H₂S produced by bacterial sulfate reduction (BSR) is characterized by a significant isotope fractionation of ³⁴S, which was controlled by temperature and the SO₄^2- concentration from the dissolution of sulfate rocks in the system. Bacterial sulfate reduction in the experimental system provides an evidence for biological karst on sulfate rocks, and gives a good interpretation for the feature of karst development below the Ordovician weathering crust, Ordos basin. In addition, the presence of pyrite and compacted released water karst confirms that bacterial sulfate reduction took place within the weathering crust during the burial stage. The results provide a new perspective for the analysis of the formation of oil-gas reservoir and the exploration of petroleum gas geology resources.
- Ordos basin,
- bacterial sulfate reduction,
- sulfur isotopes,
- pyrite,
- biological karst,
- hydrogeology

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References

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Sulfur Isotopic Evidence for Biological Karst of Sulfate Rocks in Burial Environment

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