Volume 36 Issue 1
Jan.  2011
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QIN Shen-jun, SUN Yu-zhuang, TANG Yue-gang, WANG Shuang-jie, ZHANG Shou-xin, 2011. Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature. Earth Science, 36(1): 122-130. doi: 10.3799/dqkx.2011.013
Citation: QIN Shen-jun, SUN Yu-zhuang, TANG Yue-gang, WANG Shuang-jie, ZHANG Shou-xin, 2011. Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature. Earth Science, 36(1): 122-130. doi: 10.3799/dqkx.2011.013

Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature

doi: 10.3799/dqkx.2011.013
  • Received Date: 2010-05-31
  • Publish Date: 2011-01-01
  • Conifer samples were simulated for more than five years at low temperature (80 ℃) in order to study their early alteration processes. The samples were analyzed by chromatography and gas chromatography-mass spectrometry when the simulation lasted approximately one year and five and a half years, respectively. The results show that the alkanes and terpenoids of coniferous organic matter can undergo a remarkable and rapid alteration after sedimentation. Some seldom reported evolutionary intermediates of terpenoids, i.e. two cadinatetraenes, one abietatetraene and three norabietatetraenes, were identified based on their mass fragments. Then the early evolutionary pathways of cadalane-type sesquiterpenoids and abietane-type diterpenoids were proposed. In these processes, the dehydrogenated and aromatic terpenoids are main evolutionary products, which may be mediated by undefined bacteria.

     

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  • Cong, P.Z., Li, S.Y., 2003. Mass spectrometry of natural products. Chinese Medicine and Technology Publishing House, Beijing (in Chinese).
    Cranwell, P.A., 1985. Long-chain unsaturated ketones in recent lacustrine sediments. Geochimica et Cosmochimica Acta, 49(7): 1545-1551. doi: 10.1016/0016-7037(85)90259-5
    Dai, S.F., Chou, C.L., Yue, M., et al., 2005. Mineralogy and geochemistry of a Late Permian coal in the Dafang coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids. International Journal of Coal Geology, 61(3-4): 241-258. doi: 10.1016/j.coal.2004.09.002
    Dehmer, J., 1995. Petrological and organic geochemical investigation of recent peats with known environments of deposition. International Journal of Coal Geology, 28(2-4): 111-138. doi: 10.1016/0166-5162(95)00016-X
    Del Rio, J.C., Gonzalez-vila, F.J., Martin, F., 1992. Variation in the content and distribution of biomarkers in two closely situated peat and lignite deposits. Organic Geochemistry, 18(1): 67-78. doi: 10.1016/0146-6380(92)90144-M
    Duan, Y., Luo, B.J., 1990. Distributional and evolutionary characteristics of the tri-and tetarcyclic diterpenoids in modern marsh sediments. Acta Sedimentologica Sinica, 8(2): 113-119 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-CJXB199002015.htm
    Hajje, N., Jaffe, R., 2006. Molecular characterization of Cladium peat from the Florida Everglades: biomarker associations with humic fractions. Hydrobiologia, 569(1): 99-112. doi: 10.1007/s10750-006-0125-0
    Huang, D.F., 1999. Advances in hydrocarbon generation theory (Ⅰ): generation and evolution model for immature oils and hydrocarbon. Journal of Petroleum Science and Engineering, 22(1-3): 121-130. doi: 10.1016/S0920-4105(98)00061-8
    Huang, Y.S., Fu, J.M., Sheng, G.Y., et al., 1991. Identification and confirmation of α-cedrene cuparene in high wax oils and altered source rocks. Geochimica, 20(3): 276-282 (in Chinese with English abstract). http://ci.nii.ac.jp/naid/10026606252
    Martin, J.J.V., Yu, Z.T., Mohn, W.W., 1999. Recent advances in understanding resin acid biodegradation: microbial diversity and metabolism. Arch Microbiol, 172(3): 131-138. doi: 10.1007/s002030050752
    Otto, A., Simoneit, B.R.T., 2001. Chemosystematics and diagenesis of terpenoids in fossil conifer species and sediment from the Eocene Zeitz formation, Saxony, Germany. Geochimica et Cosmochimica Acta, 65(20): 3505-3527. doi: 10.1016/S0016-7037(01)00693-7
    Otto, A., Walther, H., Puttmann, W., 1997. Sesqui and diterpenoid biomarkers preserved in Taxodum-rich Oligocene oxbow lake clays, Weisselster basin, Germany. Organic Geochemistry, 26(1-2): 105-115. doi: 10.1016/S0146-6380(96)00133-7
    Pancost, R.D., Baas, M., Geel, B.V., et al., 2002. Biomarkers as proxies for plant inputs to peats: an example from a sub-boreal ombrotrophic bog. Organic Geochemistry, 33(7): 675-690. doi: 10.1016/S0146-6380(02)00048-7
    Peters, K.E., Moldowan, J.M., 1993. The Biomarker Guide: interpreting molecular fossils in petroleum and ancient sediments. Prentice hall, Englewood Cliffs, New Jersey.
    Philp, R.P., 1985. Fossil fuel biomarkers. Applications and spectra. Methods in Geochemistry and Geophysik, 23. Elsevier, Amsterdam.
    Qin, S.J., Sun, Y.Z., Tang, Y.G., 2008. Early hydrocarbon generation of algae and influences of inorganic environments during low temperature simulation. Energy Exploration & Exploitation, 26(6): 377-396. doi: 10.1260/014459808788262251
    Shi, J.Y., Xiang, M.J., Qu, D.C., 2001. Thermal simulation experiment and evolution of fatty acid in immature oil source rocks. Chinese Science Bulletin, 46(18): 1567-1572 (in Chinese). doi: 10.1360/csb2001-46-18-1567
    Simoneit, B.R.T., 1977. Diterpenoid compounds and other lipids in deep-sea sediments and their geochemical significance. Geochimica et Cosmochimica Acta, 41(4): 463-476. doi: 10.1016/0016-7037(77)90285-X
    Simoneit, B.R.T., Grimalt, J.O., Wang, T.G., et al., 1986. Cyclic terpenoids of contemporary resinous plant detritus and of fossil woods, ambers and coals. Organic Geochemistry, 10(4-6): 877-889. doi: 10.1016/S0146-6380(86)80025-0
    Simoneit, B.R.T., Mazurek, M.A., 1982. Organic matter of the troposphere—Ⅱ. Natural background of biogenic lipid matter in aerosols over the rural western United States. Atmospheric Environment, 16(9): 2139-2159. doi: 10.1016/0004-6981(82)90284-0
    Sun, Y.Z., Lu, J.L., Chen, J.P., et al., 2006. Experimental study of decay conditions of organic matter and its significant for immature oil generation. Energy Exploration & Exploitation, 24: 161-170. doi: 10.1260/014459806779367473
    Sun, Y.Z., Qin, S.J., Wang, P., et al., 2008. Experimental study of earlier formation processes of macerals. World Journal of Engineering, 5(1): 101- 102. http://www.researchgate.net/publication/262822762_Experimental_study_of_earlier_formation_processes_of_macerals
    Sun, Y.Z., Qin, S.J., Zhao, C.L., et al., 2010. Experimental study of early formation processes of macerals and sulfides. Energy & Fuels, 24(2): 1124-1128. doi: 10.1021/ef901019b
    Wang, T.G., Zhong, N.N., Hou, D.J., et al., 1997. Several genetic mechanisms of immature crude oils in China. Acta Sedimentologic Sinica, 15(2): 75-83 (in Chinese with English abstract). http://www.researchgate.net/publication/285088193_Several_genetic_mechanisms_of_immature_crude_oils_in_China
    丛浦珠, 李笋玉, 2003. 天然有机质谱学. 北京: 中国医药科技出版社.
    段毅, 罗斌杰, 1990. 现代沼泽沉积物中三、四环萜类的分布及演化特征. 沉积学报, 8(2): 113-119. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB199002015.htm
    黄永松, 傅家漠, 盛国英, 等, 1991. 高蜡原油及其生油岩中新生物标志物——雪松烯和花侧柏烯. 地球化学, 20(3): 276-282. doi: 10.3321/j.issn:0379-1726.1991.03.009
    史继扬, 向明菊, 屈定创, 2001. 未熟-低熟烃源岩中脂肪酸的热模拟实验及演化. 科学通报, 46(18): 1567-1572. doi: 10.3321/j.issn:0023-074X.2001.18.017
    王铁冠, 钟宁宁, 候读杰, 等, 1997. 中国低熟油的几种成因机制. 沉积学报, 15(2): 75-83. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB702.015.htm
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