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    湖南锡田矿田花岗岩时空分布与钨锡成矿关系:来自锆石U-Pb年代学与岩石地球化学的约束

    刘飚 吴堑虹 孔华 奚小双 蒋江波 李欢 曹荆亚 汤钰御

    刘飚, 吴堑虹, 孔华, 奚小双, 蒋江波, 李欢, 曹荆亚, 汤钰御, 2022. 湖南锡田矿田花岗岩时空分布与钨锡成矿关系:来自锆石U-Pb年代学与岩石地球化学的约束. 地球科学, 47(1): 240-258. doi: 10.3799/dqkx.2021.200
    引用本文: 刘飚, 吴堑虹, 孔华, 奚小双, 蒋江波, 李欢, 曹荆亚, 汤钰御, 2022. 湖南锡田矿田花岗岩时空分布与钨锡成矿关系:来自锆石U-Pb年代学与岩石地球化学的约束. 地球科学, 47(1): 240-258. doi: 10.3799/dqkx.2021.200
    Liu Biao, Wu Qianhong, Kong Hua, Xi Xiaoshuang, Jiang Jiangbo, Li Huan, Cao Jingya, Tang Yuyu, 2022. Spatiotemporal Distribution of Granites in Xitian Ore Field in Hunan and Its Tungsten-Tin Mineralization: Constraints from Zircon U-Pb Dating and Geochemical Characteristics. Earth Science, 47(1): 240-258. doi: 10.3799/dqkx.2021.200
    Citation: Liu Biao, Wu Qianhong, Kong Hua, Xi Xiaoshuang, Jiang Jiangbo, Li Huan, Cao Jingya, Tang Yuyu, 2022. Spatiotemporal Distribution of Granites in Xitian Ore Field in Hunan and Its Tungsten-Tin Mineralization: Constraints from Zircon U-Pb Dating and Geochemical Characteristics. Earth Science, 47(1): 240-258. doi: 10.3799/dqkx.2021.200

    湖南锡田矿田花岗岩时空分布与钨锡成矿关系:来自锆石U-Pb年代学与岩石地球化学的约束

    doi: 10.3799/dqkx.2021.200
    基金项目: 

    国家重点研发计划项目 2018YFC0603901

    国家重点研发计划项目 2018YFC0603902

    中国地质调查局项目 12120114052101

    详细信息
      作者简介:

      刘飚(1989-), 男, 博士, 讲师, 主要从事矿床学方面研究. ORCID: 0000-0003-0078-897X. E-mail: Biaoliu@csu.edu.cn

      通讯作者:

      汤钰御, E-mail: tangyuyu@csu.edu.cn

    • 中图分类号: P585

    Spatiotemporal Distribution of Granites in Xitian Ore Field in Hunan and Its Tungsten-Tin Mineralization: Constraints from Zircon U-Pb Dating and Geochemical Characteristics

    • 摘要:

      锡田钨锡多金属矿田位于南岭成矿带中段,发育多期次岩浆活动与钨锡成矿. 为了厘清花岗岩与钨锡成矿的时空关系,采用野外调查、显微鉴定、锆石U-Pb同位素定年与岩石地球化学的方法对矿田内多期次花岗岩岩体(脉)的空间分布、岩石类型、成岩时代、地球化学组成等进行了研究. 结果表明,锡田矿田发生了三期岩浆事件,分别为加里东期(435~441 Ma)、印支期(220~230 Ma)、燕山期(141~160 Ma);三期花岗岩普遍富集大离子亲石元素Rb、K、U、Th等,亏损Ti、P、Sr、Ba等微量元素,具明显的负Eu异常,其中加里东期花岗岩与印支期花岗岩为S型花岗岩,而燕山期花岗岩为A型花岗岩;不同时期花岗岩中的成矿元素从加里东期→印支期→燕山期逐渐升高,特别是W、Sn元素在燕山期白云母与二云母花岗岩中最为富集,这与华南地区燕山期钨锡大爆发的时间是一致的;印支期岩体接触带发育少量矽卡岩型Fe-Cu-W多金属矿床,燕山期岩体接触带也发育矽卡岩型W-Sn多金属矿床,并在附近陡倾的张裂隙中发育多个中大型石英脉型W-Sn矿床,而加里东期岩体附近尚未发现钨锡矿化. 因此,锡田矿田的多期次花岗岩与钨锡多金属成矿是时空耦合的,且成矿以燕山期矽卡岩型与石英脉型钨锡矿为主.

       

    • 图  1  中国南岭地区主要W-Sn多金属矿床及成矿年代分布(据毛景文等,2007

      Fig.  1.  Distribution of major W-Sn deposits and mineralization age in the Nanling area, China (modified from Mao et al., 2007)

      图  2  锡田矿田地质图

      Fig.  2.  Geological map of Xitian ore field

      图  3  不同时期岩体间的穿插关系

      Fig.  3.  Interpenetration relationships of different stage granites

      图  4  不同期次花岗岩镜下特征

      a. 加里东期中细粒白云母花岗岩;b. 印支期细粒白云母花岗岩;c. 印支期细粒黑云母花岗岩;d. 印支期细粒二云母花岗岩;e. 燕山期二云母花岗岩;f. 燕山期细粒白云母花岗岩.Qz. 石英;Pl. 斜长石;Bt. 黑云母;Ms. 白云母

      Fig.  4.  Microscopic characteristics of different stage granites

      图  5  锡田矿田花岗岩锆石CL图像

      Fig.  5.  Cathodoluminescence (CL) images of zircon from Xitian granites

      图  6  锡田花岗岩锆石U-Pb年龄谐和图

      Fig.  6.  Zircon U-Pb isochron diagrams of Xitian granites

      图  7  锡田花岗岩SiO2-K2O图解及A/CNK-A/NK图解

      Fig.  7.  SiO2 vs. K2O diagram and A/CNK vs. A/NK diagram of Xitian granites

      图  8  锡田花岗岩稀土元素配分模式和微量元素蛛网图

      标准化值据Sun and McDonough(1989

      Fig.  8.  Chondrite-normalized REE pattern and primitive mantle-normalized trace element spider diagram of Xitian granites

      图  9  锡田矿田成岩与成矿年龄对比

      Fig.  9.  Comparison of diagenetic age and metallogenic age in the Xitian ore field

      图  10  不同构造期花岗岩成矿元素富集箱线图

      Fig.  10.  Box diagram of granite ore-forming element enrichment in different tectonic periods

      表  1  不同时期花岗岩样品信息

      Table  1.   Information of granite samples in different periods

      时期 样号 地区 坐标 岩性
      加里东期 170922-4s1 锡田岩体南部 113°42'11"E,26°43'48"N 中细粒白云母花岗岩
      170922-3s1 锡田岩体南部 113°42'11"E,26°43'48"N 中细粒白云母花岗岩
      印支期 150619-5s1 锡田地区 113°45'48"E,26°49'46"N 细粒白云母花岗岩岩脉
      181102-3s1 邓埠仙地区 113°44'43"E,27°8'14"N 细粒黑云母花岗岩岩脉
      181102-3s2 邓埠仙地区 113°44'43"E,27°8'14"N 细粒二云母花岗岩岩脉
      燕山期 160823-8s8 锡田地区 113°48'50"E,26°48'28"N 细粒白云母花岗岩岩脉
      下载: 导出CSV

      表  2  锡田矿田花岗岩主量(%)、微量(10-6)及稀土元素(10-6)组成

      Table  2.   Major (%), trace (10-6) and rare earth (10-6) element compositions of granites in Xitian ore field

      样品编号 170922-3s1 170922-3s2 170922-3s3 170922-4s1 170922-4s2 170922-4s3 1407-25 0822-5-s1 0823-4s1 0816-15s1 0619-5s1 0823-15s1 0818-12s1 0719-4s1 0720-13s1 0818-3s2
      加里东期细粒白云母花岗岩 印支期花岗岩 燕山期花岗岩
      SiO2 75.00 74.40 75.00 - - - 75.81 75.68 78.07 76.79 64.27 75.17 76.18 76.32 74.97 76.36
      TiO2 0.04 0.04 0.05 - - - 0.02 0.02 0.02 0.03 0.10 0.09 0.04 < 0.01 0.02 0.06
      Al2O3 14.10 14.30 14.20 - - - 13.44 13.65 12.58 13.26 18.46 13.33 12.88 13.17 13.56 12.40
      TFe2O3 0.96 0.99 1.05 - - - 0.34 0.81 0.78 1.64 0.51 1.13 1.13 1.14 0.43 1.39
      MnO 0.03 0.02 0.02 - - - 0.01 0.06 0.01 0.03 0.02 0.02 0.04 0.05 0.02 0.07
      MgO 0.25 0.31 0.31 - - - 0.26 0.05 0.03 0.05 0.22 0.10 0.04 0.11 0.04 0.08
      CaO 0.29 0.25 0.24 - - - 0.42 0.38 0.40 0.09 0.75 1.06 0.58 0.93 0.57 0.25
      Na2O 3.32 3.01 3.09 - - - 3.28 3.52 3.97 2.80 1.38 3.10 3.82 3.68 4.11 3.20
      K2O 4.21 4.26 4.18 - - - 6.13 4.37 4.38 4.09 13.30 5.59 4.66 3.55 5.36 4.79
      P2O5 0.16 0.14 0.13 - - - < 0.01 0.01 < 0.01 0.03 0.08 0.07 < 0.01 0.02 0.02 0.03
      LOI 1.13 1.40 1.36 - - - 0.58 0.68 0.49 1.19 0.88 0.41 0.54 1.31 0.51 0.61
      Na2O+K2O 7.53 7.27 7.27 - - - 9.41 7.89 8.35 6.89 14.68 8.69 8.48 7.23 9.47 7.99
      Total 100 100 100 - - - 100.29 99.23 100.73 100 99.97 100.07 99.91 100.28 99.61 99.24
      A/CNK 1.34 1.43 1.42 - - - 1.05 1.22 1.05 1.44 1.02 1.02 1.04 1.14 1.00 1.14
      A/NK 1.41 1.50 1.48 - - - 1.12 1.30 1.11 1.47 1.11 1.19 1.14 1.33 1.08 1.19
      DI 93.40 92.50 92.70 - - - 96.10 95.33 97.32 95.20 94.62 94.15 96.37 91.56 96.34 96.86
      V 2 2 2 2 1 1 1 1 < 1 1 2 3 1 1 1 2
      Cr 15 19 17 6 7 6 20 16 17 14 7 16 13 15 22 14
      Cs 24.3 22.5 22.3 28.8 28.5 28.4 20.9 85.2 20.4 34.0 53.6 12.45 59.7 34.0 32.4 41.1
      Ga 27.4 28.2 27.5 32.9 29.6 29.8 20.2 27.1 23.5 37.8 22.3 18.9 24.7 24.6 26.3 23.3
      Rb 393 393 391 460 430 431 560 900 520 600 590 383 820 590 880 830
      Ba 170.0 164.0 168.0 128.0 128.0 120.0 137.0 40.7 6.4 11.0 212.0 289.0 6.3 66.3 49.1 34.9
      Th 7.43 8.03 7.58 9.85 7.85 8.45 23.70 29.20 68.50 8.15 8.22 64.70 41.70 27.30 30.30 26.70
      U 10.70 9.30 9.40 4.60 4.20 4.20 21.60 23.60 47.10 21.20 34.70 15.50 35.90 34.70 22.10 20.30
      Ta 4.60 4.80 4.60 5.80 4.70 5.00 10.40 38.80 8.15 10.80 2.51 2.05 7.99 13.90 8.81 5.68
      Nb 20.9 21.5 21.8 28.9 22.5 24.3 11.3 13.8 21.8 5.1 11.2 10.1 42.2 33.2 26.3 25.2
      Sr 97.4 79.2 83.7 20.3 28.3 27.3 54.9 22.5 4.7 3.5 142.5 103.0 5.4 27.7 35.8 10.3
      Zr 41.0 45.0 42.0 43.0 44.0 40.0 95.0 60.0 236.0 28.0 53.0 82.0 108.0 104.0 67.0 71.0
      Hf 2.1 2.3 2.2 2.3 2.2 2.2 8.0 4.3 14.0 2.1 2.5 3.4 7.7 8.4 5.0 3.6
      La 10.5 7.1 6.0 9.6 11.1 8.9 9.8 11.8 12.8 4.2 10.6 10.8 27.5 19.7 21.8 24.6
      Ce 15.2 13.1 12.6 18.5 22.7 17.3 25.5 28.8 19.9 10.9 25.8 21.3 62.9 55.8 54.1 57.7
      Pr 2.18 1.78 1.61 2.32 2.62 2.06 3.09 3.64 4.32 1.40 3.20 2.45 10.00 7.95 6.79 7.02
      Nd 9.50 6.80 6.10 8.20 9.00 7.90 70.20 62.90 68.90 37.70 19.10 16.60 35.00 31.40 33.10 28.00
      Sm 3.26 2.57 2.21 2.77 2.86 2.35 2.94 5.32 10.15 1.83 3.27 3.39 17.15 15.50 10.80 7.95
      Eu 0.19 0.18 0.13 0.16 0.12 0.12 0.04 0.13 0.05 0.03 0.20 0.67 0.08 0.12 0.09 0.10
      Gd 4.18 3.33 2.92 2.75 2.69 2.62 2.54 6.92 16.05 1.83 3.09 4.52 20.10 18.70 13.55 8.57
      Tb 0.87 0.71 0.64 0.66 0.63 0.59 0.44 1.62 3.71 0.44 0.65 1.00 4.35 4.46 3.32 1.99
      Dy 4.33 3.71 3.18 3.20 3.30 3.26 2.91 11.85 27.20 3.11 4.86 6.43 28.80 32.70 23.30 14.10
      Ho 0.56 0.48 0.42 0.42 0.42 0.43 0.69 2.65 6.15 0.60 1.05 1.39 5.82 6.76 4.83 2.97
      Er 1.22 0.93 0.84 0.89 0.90 0.89 2.53 8.19 21.10 2.15 3.63 4.34 18.90 23.00 16.55 9.73
      Tm 0.15 0.11 0.10 0.10 0.11 0.11 0.52 1.31 3.35 0.42 0.64 0.64 3.18 3.95 2.87 1.60
      Yb 0.83 0.63 0.59 0.57 0.65 0.64 4.70 9.53 23.90 3.67 4.51 4.15 23.60 28.70 21.10 11.50
      Lu 0.11 0.09 0.08 0.07 0.09 0.09 0.87 1.48 3.72 0.57 0.68 0.63 3.65 4.31 3.18 1.78
      Y 20.8 16.4 19.2 14.7 16.0 15.4 27.60 61.30 220.00 21.00 32.80 42.00 189.00 185.50 151.00 87.70
      ΣREE 53.10 41.50 37.40 50.20 57.20 47.30 126.77 156.14 221.30 68.85 81.28 78.31 261.03 253.05 215.38 177.61
      LREE 40.80 31.50 28.70 41.60 48.40 38.60 111.57 112.59 116.12 56.06 62.17 55.21 152.63 130.47 126.68 125.37
      HREE 12.30 9.99 8.77 8.66 8.79 8.63 15.20 43.55 105.18 12.79 19.11 23.10 108.40 122.58 88.70 52.24
      LREE/HREE 3.33 3.16 3.27 4.80 5.51 4.48 7.34 2.59 1.10 4.38 3.25 2.39 1.41 1.06 1.43 2.40
      LaN/YbN 9.07 8.08 7.29 12.1 12.3 9.97 1.50 0.89 0.38 0.82 1.69 1.87 0.84 0.49 0.74 1.53
      Eu/Eu* 0.16 0.19 0.16 0.18 0.13 0.15 0.04 0.07 0.01 0.05 0.19 0.52 0.01 0.02 0.02 0.04
      Ce/Ce* 0.74 0.88 0.97 0.93 1.00 0.95 1.13 1.07 0.65 1.10 1.08 0.98 0.93 1.09 1.08 1.06
      下载: 导出CSV

      表  3  锡田矿田花岗岩成矿元素组成(10-6)

      Table  3.   Ore-forming element compositions (10-6) of granites in Xitian ore field

      样品编号 期次 岩石名称 采样位置 W Sn Cu Pb Zn
      170922-3s2 加里东期 中细粒白云母花岗岩 茶陵水库边 10.9 17.7 3.6 9.0 21
      170922-3s3 加里东期 中细粒白云母花岗岩 茶陵水库边 6.7 18.3 3.5 9.0 16
      170922-3s4 加里东期 中细粒白云母花岗岩 茶陵水库边 6.1 17.9 3.7 8.6 17
      170922-4s2 加里东期 中细粒白云母花岗岩 茶陵水库边 7.8 25.5 5.3 16.6 32
      170922-4s3 加里东期 中细粒白云母花岗岩 茶陵水库边 6.3 21.8 2.2 8.7 23
      170922-4s4 加里东期 中细粒白云母花岗岩 茶陵水库边 6.3 22.0 1.8 7.7 22
      1407-17-3s4 印支期 似斑状黑云母花岗岩 花木矿废石堆 2.0 17.0 29.0 44.0 38
      1407-15-11s1 印支期 似斑状黑云母花岗岩 狗打栏矿废石堆 19.0 51.0 12.0 68.0 54
      1407-17-1s9 印支期 似斑状黑云母花岗岩 荷树下矿废石堆 18.0 18.0 8.0 62.0 58
      1407-21-5s1 印支期 似斑状黑云母花岗岩 高垄公路边 11.0 40.0 1.0 82.0 32
      170929-15s2-1 印支期 粗粒黑云母花岗岩 垄山矿石碓 3.7 19.5 14.8 99.2 47
      150619-5s1 印支期 细粒白云母花岗岩 垄上228中段 11.4 30.3 8.7 55.2 14
      160822-05-s1 燕山期 细粒黑云母花岗岩 白石凹 43.1 19.8 1.2 51.1 37
      160823-04s1 燕山期 细粒黑云母花岗岩 小船里 13.7 7.2 8.6 90.0 12
      160818-12s1 燕山期 细粒黑云母花岗岩 小船里 1.6 4.7 0.9 69.6 21
      160818-3s2 燕山期 细粒黑云母花岗岩 圆树山 8.5 41.4 1.4 55.3 49
      1407-20-12s1 燕山期 细粒黑云母花岗岩 荷树下3号坑道 30.0 14.0 1.0 72.0 11
      1407-15-11s9 燕山期 细粒黑云母花岗岩 狗打栏钨锡矿 29.0 26.0 1.0 83.0 19
      1407-17-1s10 燕山期 细粒黑云母花岗岩 荷树下矿废石堆 16.0 15.0 10.0 115.0 17
      160823-15s1 燕山期 细粒二云母花岗岩 圆树山 41.9 25.8 13.3 69.4 39
      615-8s1 燕山期 细粒二云母花岗岩 湘东钨矿矿石堆 23.1 41.5 13.8 10.9 35
      160816-15s1 燕山期 细粒白云母花岗岩 岩口水库公路旁 930 78.2 51.7 39.6 19
      1407-24-15s1 燕山期 细粒白云母花岗岩 垄上坑道253 283.0 24.0 137.0 56.0 25
      1407-25 燕山期 细粒白云母花岗岩 垄上 251.0 8.5 26.5 38.9 24
      1407-20-13s1 燕山期 细粒白云母花岗岩 荷树下3号坑道 146.0 10.1 1.1 60.8 58
      1407-19-4s1 燕山期 细粒白云母花岗岩 垄上228中段 84.5 32.9 6.4 66.1 63
      - - 花岗岩 全国 1.0 2.2 5.5 0.1 40[1]
      - - 上地壳 中国东部 0.8 1.8 17.0 0.4 63[2]
      - - 上地壳 华南地块 1.2 2.5 19.0 23.0 69[3]
      注:数据[1]来源于迟清华等(2012);数据[2]与数据[3]来源于鄢明才等(1997).
      下载: 导出CSV
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    出版历程
    • 收稿日期:  2021-05-19
    • 网络出版日期:  2022-02-11
    • 刊出日期:  2022-01-20

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