Two Epochs of Mo Mineralization in Cuihongshan Fe-Mo-Polymetallic Ore field, Heilongjiang Province
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摘要:
黑龙江省翠宏山铁钼多金属矿田属于小兴安岭-张广才岭铁多金属成矿带，发育铁、铅、锌、钼、钨等多金属大规模成矿作用. 尤以钼矿化最具特色，出现矽卡岩-斑岩型钼钨矿化、斑岩型钼矿化和隐爆角砾岩型钼矿化等多种类型的钼矿化在单一矿田中并存的现象. 但三种钼矿化类型的矿化特征和时空关系等缺乏系统梳理，钼成矿事件尚未清晰厘定. 选取该矿田内翠宏山、霍吉河和宏铁山等含钼矿床，开展矿床地质特征解析，结合辉钼矿Re-Os定年，初步厘定翠宏山矿田存在晚三叠世矽卡岩-斑岩型和隐爆角砾岩型钼矿化以及早侏罗世斑岩型钼矿化两期钼成矿事件. 辉钼矿Re含量和成矿岩浆岩石学研究揭示翠宏山矿田中钼为幔源新生物质与古老地壳混源，相较于晚三叠世成矿期，早侏罗世成矿期加入了更多幔源新生物质. 综合矿化特征和成矿物质来源分析认为区内钼成矿与松嫩地块与佳木斯地块在晚三叠世-早侏罗世期间的碰撞拼合过程有关.
Abstract:Cuihongshan Fe-Mo-polymetallic ore field in Heilongjiang Province belongs to the Lesser Xing'an Range-Zhangguangcailing Fe-polymetallic metallogenic belt, and is characterized by the large-scale mineralization of Fe, Pb, Zn, Mo and W. Among them, Mo mineralization is the most noticeable, with three mineralization styles, including skarn-porphyry Mo-W, porphyry Mo-only, and cryptoexplosion breccias Mo, coexisting in a single ore field. However, the mineralization characteristics and spatio-temporal relationship of the three Mo mineralization types have not been systematically analyzed, and the Mo mineralization events have not been clearly defined. In this paper, the Cuihongshan, Huojihe and Hongtieshan Mo (polymetallic) deposits were selected for the geological characteristics analyses. Combining the geological characteristics with molybdenite Re-Os dating, two Mo mineralization events in Cuihongshan ore field were defined, including the Late Triassic skarn-porphyry Mo-Wand cryptoexplosion Mo mineralization and the Early Jurassic porphyry Mo-only mineralization. The Re content of molybdenite and petrogenesis of ore-forming magma reveal that Mo in Cuihongshan ore field were derived from a mixed source containing mantle-derived juvenile materials and ancient crustal components. And compared with the Late Triassic mineralization, more mantle-derived juvenile materials were involved during the Early Jurassic mineralization. Based on the mineralization characteristics and ore-forming material source analysis, the Mo mineralization is suggested to be related to the collision process between Songnen block and Jiamusi block during Late Triassic to Early Jurassic.
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Key words:
- Cuihongshan /
- Fe-Mo-polymetallic ore field /
- Mo mineralization /
- Re-Os dating /
- Heilongjiang Province /
- mineral deposit
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图 1 东北大地构造单元格架及研究区位置(a)和翠宏山矿田区域地质简图(b)
图a据Hu et al. (2014)；图b据杨健等(2020)
Fig. 1. Tectonic framework of Northeast China and location of the study area (a) and geological map of the Cuihongshan ore field area (b)
图 2 翠宏山铁钼多金属矿床地质图(a)和54号勘探线剖面图(b)(据Hu et al.，2014)
Fig. 2. Sketch geological map (a) and No. 54 cross section (b) of the Cuihongshan Fe-Mo-polymetallic deposit (from Hu et al., 2014)
图 3 翠宏山铁钼多金属矿床矿化蚀变特征
a. 辉钼矿化花岗斑岩；b. 绿泥石化花岗斑岩；c. 花岗斑岩与透辉石矽卡岩接触带；d. 透辉石矽卡岩；e. 花岗斑岩穿插矽卡岩；f. 矽卡岩中浸染状磁铁矿和方解石团块；g. 块状磁铁矿石；h. 黄铜矿石中浸染状辉钼矿；i. 大理岩中浸染状辉钼矿；j. 花岗斑岩中浸染状白钨矿；k. 花岗斑岩中浸染状辉钼矿；l. 辉钼矿呈叶片状穿插黄铜矿. 矿物缩写：Mag. 磁铁矿；Ccp. 黄铜矿；Mol. 辉钼矿；Cal. 方解石；Phl. 金云母；Sch. 白钨矿
Fig. 3. Typical mineralization and alteration features of the Cuihongshan Fe-Mo-polymetallic deposit
图 4 霍吉河钼矿床地质简图(a)和西矿段7号勘探线剖面图(b)(据Hu et al.，2019)
Fig. 4. Geological map (a) and No. 7 cross section in the western block (b) of the Huojihe Mo deposit (from Hu et al., 2019)
图 5 霍吉河钼矿床矿化蚀变特征
a. 花岗闪长岩；b. 斑状花岗闪长岩；c. 斑状花岗闪长岩中辉钼矿网脉状；d. 二长花岗岩中辉钼矿网脉状；e. 镜下的脉状辉钼矿；f. 镜下的浸染状辉钼矿；g. 黄铁矿包裹磁黄铁矿和黄铜矿；h. 浸染状黄铁矿和黄铜矿；i. 钾化；j. 硅化；k. 青磐岩化；l. 绢云母化‒泥化. 矿物缩写：Py. 黄铁矿；Kfs. 钾长石；Mol. 辉钼矿；Ccp. 黄铜矿；Po. 磁黄铁矿；Qtz. 石英；Ep. 绿帘石；Chl. 绿泥石
Fig. 5. Typical mineralization and alteration features of the Huojihe Mo deposit
图 6 宏铁山铁钼矿床矿化特征
a. 宏铁山钼铁矿化宏观空间特征；b. 隐爆角砾岩筒穿切二长花岗岩；c.二长花岗岩与花岗闪长岩接触边界；d. 花岗闪长岩胶结的隐爆角砾岩；e. 热液胶结的隐爆角砾岩；f. 隐爆角砾岩中的辉钼矿；g. 隐爆角砾岩中浸染状辉钼矿；h. 隐爆角砾岩中叶片状辉钼矿. 矿物缩写：Grt. 石榴石；Ep. 绿帘石；Mol. 辉钼矿
Fig. 6. Typical mineralization features of the Hongtieshan Fe-Mo deposit
图 7 翠宏山矿田辉钼矿Re-Os同位素图
a. 翠宏山矿床和翠中矿床辉钼矿Re-Os同位素等时线；b. 霍吉河矿床辉钼矿Re-Os同位素等时线；c. 翠宏山矿田辉钼矿Re-Os同位素模式年龄频谱图；d. 翠宏山矿田辉钼矿Re-Os同位素年龄加权平均值
Fig. 7. Re-Os isotopic charts of molybdenite from the Cuihongshan ore field
表 1 翠宏山矿田辉钼矿Re⁃Os年龄测试结果
Table 1. Re-Os isotopic data for molybdenite from the Cuihongshan ore field
矿区 样品编号 样重(g) Re (ng/g) 普Os (ng/g) 187Re (ng/g) 187Os (ng/g) 模式年龄(Ma) 数据来源 含量 2σ 含量 2σ 含量 2σ 含量 2σ 含量 2σ 霍吉河 HJH-21 0.006 37 57 491 398 0.001 6 0.055 0 36 134 250 110.00 0.70 182.4 2.5 Hu et al., 2019 HJH-22 0.006 54 45 262 370 0.576 1 0.023 0 28 448 233 86.40 0.56 181.9 2.6 HJH-23 0.006 63 19 515 131 0.118 1 0.037 0 12 266 82 37.10 0.22 181.4 2.4 HJH-24 0.025 58 45 338 663 0.809 0 0.020 0 28 496 417 85.20 0.62 179.2 3.4 TWH1-1 0.050 68 19 800 150 0.563 8 0.057 6 12 440 90 37.55 0.36 180.9 2.7 谭红艳等, 2013 TWH1-2 0.050 80 21 720 160 0.004 9 0.027 4 13 650 100 41.04 0.35 180.2 2.5 TWH1-4 0.050 99 17 330 140 0.052 1 0.021 1 10 890 90 33.30 0.30 183.3 2.7 TWH1-5 0.050 63 13 190 100 0.004 9 0.000 0 8 292 60 25.24 0.25 182.5 2.7 TWH1-3 0.030 89 20 090 160 0.089 6 0.018 1 12 630 100 37.89 0.30 179.8 2.5 090817-3 0.050 46 12 040 90 0.004 3 0.009 6 7 565 57 22.89 0.21 181.3 2.6 张琳琳等, 2014 090817-5 0.050 26 30 920 230 0.056 6 0.014 3 19 430 140 58.58 0.48 180.7 2.5 13HJH11 0.006 27 580 210 17 330 130 51.58 0.48 178.3 2.6 杜晓慧和张勇, 2015 13HJH13 0.030 18 910 140 11 880 90 35.44 0.28 178.7 2.4 13HJH20 0.030 17 920 140 11 260 90 33.27 0.27 177.1 2.5 13HJH22 0.030 36 500 280 22 940 180 67.72 0.54 176.9 2.4 13HJH25 0.031 31 050 230 19 510 150 57.70 0.46 177.2 2.4 平均值 0.032 27 166 225 0.207 4 0.026 17 073 141 51.30 0.40 180.1 2.6 翠宏山 CHS-10 0.100 52 789.3 7.0 0.001 0 0.004 6 496.1 4.4 1.639 0 0.016 0 198.0 3.1 Hu et al., 2014 CHS-12 0.100 63 1 055.0 9.0 0.000 8 0.002 7 663.2 5.5 2.236 0 0.023 0 202.1 3.1 CHS-13 0.100 38 773.2 7.1 0.433 4 0.508 9 485.9 4.5 1.623 0 0.023 0 200.1 3.7 CHS-4 0.100 48 72.1 0.2 0.002 1 0.000 2 45.3 0.13 0.155 4 0.000 7 205.4 2.3 陈贤等, 2017 CHS-5 0.019 91 581.0 13.4 0.005 0 0.314 3 365.2 8.40 1.253 2 0.013 6 205.6 5.5 CHS-6 0.097 23 42.8 0.9 0.002 5 0.024 9 26.9 0.54 0.091 8 0.000 7 204.6 4.7 CHS-7 0.202 34 39.4 0.9 0.000 9 0.002 1 24.7 0.59 0.083 4 0.001 0 202.0 5.7 CHS-8 0.152 15 36.1 0.1 0.002 0 0.000 1 22.7 0.07 0.077 6 0.000 3 205.2 2.3 CHS-9 0.197 14 130.4 1.6 0.000 9 0.001 0 82.0 0.99 0.279 4 0.002 5 204.3 3.5 CHS-10 0.102 19 188.3 4.1 0.001 1 0.004 4 118.3 2.60 0.401 4 0.003 6 203.3 5.1 CN3-1-2 0.050 31 614.3 7.8 0.004 2 0.014 2 386.1 4.9 1.302 0.030 202.1 5.6 郝宇杰等, 2013 CN3-1-1 0.300 32 1 074.0 15.0 0.002 0 0.000 6 674.8 9.4 2.264 0.023 201.1 3.8 CN3-1-2 0.302 03 599.7 7.5 0.006 0 0.000 9 376.9 4.7 1.272 0.015 202.2 3.9 CN3-1-3 0.191 44 1 549.0 15.0 0.000 3 0.001 5 973.7 9.4 3.234 0.030 199.0 3.1 CN3-1-4 0.301 25 763.3 10.1 0.000 2 0.001 1 479.7 6.3 1.633 0.017 203.9 3.8 CN3-1-5 0.300 42 1 290.0 15.0 0.001 1 0.000 4 810.9 9.7 2.742 0.023 202.6 3.4 CN3-1-6 0.300 26 1 043.0 16.0 0.000 2 0.000 9 655.4 10.3 2.201 0.022 201.2 4.1 翠中 ZK2032-6 0.200 31 1 118 9 0.002 7 0.002 0 702.6 5.4 2.374 0.018 202.5 2.9 杨健等, 2020 CZ-94 0.200 72 1 758 14 0.007 1 0.006 3 1 105 9 3.779 0.030 204.9 2.9 陈贤等, 2017 CZ-89C 0.093 19 259 3 0.001 8 0.004 0 163 2.1 0.545 0.006 200.9 3.8 CZ-90 0.061 73 2 402 17 0.001 8 0.013 8 1 510 11 5.175 0.045 205.4 2.9 CZ-93 0.022 62 1 962 17 0.001 7 0.020 3 1 233 10 4.254 0.041 206.7 3.1 CZ-119 0.012 62 1 117 10 0.002 4 0.013 2 702 6.5 2.358 0.039 201.3 4.2 平均值 0.152 62 837 9 0.020 9 0.041 0 526 5 1.781 0.018 202.8 3.8 宏铁山 HTS-5A 0.200 43 669.2 5.3 0.005 4 0.001 0 420.6 3.3 1.399 0.010 199.3 2.9 本次研究 
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