Geological Features and Favorable Area Prediction of Shale Gas in Lower Cambrian Niutitang Formation of Xuefeng Ancient Uplift and Its Periphery
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摘要: 雪峰古隆起边缘下寒武统牛蹄塘组页岩具有良好的生烃和储集条件,是重要的页岩气勘探层位,但受多期构造运动改造,页岩气保存条件复杂,页岩气勘探一直未获突破.基于野外地质调查、钻探资料,结合有机地化分析测试等手段,对雪峰古隆起边缘即沅麻盆地及周缘下寒武统牛蹄塘组页岩气地质条件和勘探前景进行综合评价.研究表明:牛蹄塘组沉积于深水陆棚相,页岩有机碳含量TOC值普遍大于2.0%,一般在3.0%~5.0%之间;有机质类型为Ⅰ型;有机质成熟度2.17%~3.38%之间,平均为2.79%;页岩碎屑矿物平均含量77.25%;粘土矿物平均含量22.71%,硅质含量高,脆性较大,易于储层改造.综合地化、储层物性及保存条件等评价指标,提出沅麻盆地草堂凹陷及古隆起北缘凤凰-吉首-张家界一带为牛蹄塘组页岩气勘探有利区带.Abstract: The Lower Cambrian Niutitang Formation shale at the edge of Xuefeng ancient uplift is favorable for hydrocarbon generation and accumulation, and it is an important shale gas exploration target bed. But the preservation conditions of shale gas are very complex due to multistage tectonic activities, and no breakthrough has been made in shale gas exploration. Based on field geological survey and drilling data, combined with organic geochemistry analysis and test, it made a comprehensive evaluation of shale gas geological conditions and exploration prospect of the Lower Cambrian Niutitang Formation at the edge of the Xuefeng ancient uplift, namely the Yuanma basin. Results show that the Niutitang Formation is mainly composed of deep-shelf deposits, the organic carbon content is generally more than 2.0% and between 3.0% and 5.0%, and the organic matter type is type Ⅰ. The maturity of organic matter is 2.17% to 3.38%, with an average of 2.79%. The average content of shale debris minerals is 77.25%, and the average clay mineral content is 22.71%. Due to the high silicon content and brittleness, the reservoir reformation is easy. Based on comprehensive evaluation indexes such as geochemistry, reservoir property and preservation conditions, it is proposed that the Caotang sag and Fenghuang-Jishou-Zhangjiajie belt at the northwestern edge of the ancient uplift are favorable for Niutitang Formation shale gas exploration.
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Key words:
- Xuefeng uplift /
- shale gas /
- Niutitang Formation /
- Lower Cambrian /
- geological features
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图 1 雪峰隆起大地构造位置及构造单元划分
据Li et al.(2014); Chu and Lin(2018)修改
Fig. 1. Geotectonic position and subdivision of tectonic units of the Xuefeng uplift
图 3 雪峰古隆起边缘下寒武统牛蹄塘组富有机质页岩分布特征
井位、剖面见图 1中ABC
Fig. 3. Distribution characteristics of rich organic shale in the Lower Cambrian Niutitang Formation at the edge of the Xuefeng ancient uplift
图 5 雪峰古隆起边缘下寒武统牛蹄塘组泥页岩孔隙类型
a.沥青质体表面球粒孔,湘张地1井1 950 m;b.有机质表面孔隙,孔径最大达80 nm,2015H-D5井1 620.7 m;c.粒间孔,湘吉地1井1 987.0 m;d.溶蚀孔,湘张地1井1 856.0 m;e.有机质内的矿物铸模孔,湘张地1井1 843.0 m;f.黄铁矿内的晶间孔,吉浅1井453.4 m;g.挤压碎粒孔,湘张地1井1 974.6 m;h.层间微裂缝,湘张地1井1 905.5 m
Fig. 5. Pore types of Niutitang Formation shale in the edge of the Xuefeng ancient uplift
图 7 沅麻盆地过草堂凹陷和辰溪凹陷地层结构特征
剖面位置见图 1中DD′和EE′
Fig. 7. The stratigraphic architecture of the Caotang sag and Chenxi sag
表 1 雪峰古隆起边缘牛蹄塘组储层物性特征
Table 1. Physical properties in Niutitang Formation at the edge of the Xuefeng ancient uplift
样品来源 孔隙度(%) 渗透率(10-3 μm2) 样品数(件) 备注 沅陵刀背溪 (0.66~17.70)/10.86 (0.002 10~0.005 40)/0.004 20 4 吉浅1井 (1.08~8.04)/4.71 (0.001 83~0.009 36)/0.004 00 10 围压3.71 MPa 2015H-D5井 (1.01~4.40)/2.24 (0.000 38~0.018 40)/0.004 36 18 围压2.87 MPa 湘张地1井 (1.39~4.48)/2.43 (0.004 60~0.014 90)/0.008 70 14 花垣 (0.40~2.60)/1.20 (0.005 20~0.008 80)/0.006 00 / 周庆华等,2014 2015H-D1 (0.70~5.05)/2.30 (0.000 28~0.023 90)/0.002 38 15 湘吉地1井 (0.56~4.10)/1.17 (0.000 21~0.036 00)/0.004 38 14 注:孔隙度=(最小值~最大值)/平均值;渗透率=(最小值~最大值)/平均值. 表 2 雪峰古隆起边缘牛蹄塘组黑色页岩主要实验测试项目结果
Table 2. Results of major test items for the black shale of Niutitang Formation in the edge of the Xuefeng ancient uplift
样品来源 层位 TOC(%) Ro(%) 解吸气含量
(m3/t)实测 张家界盐市 ∈1n 9(1.45~3.14)/2.10 / 实测 慈页1井 ∈1n 24(1.63~7.90)4.83 14(3.02~3.55)/3.28 0.01~0.13 孟凡洋,2018 沅陵军大坪 ∈1n 19(0.14~16.30)/7.50 (3.15~3.39)/3.23 实测 湘张地1井 ∈1n 29(1.19~10.50)/4.38 8(2.56~3.30)/3.00 0.12~1.59 实测 沅陵龙潭坪 ∈1n 14(1.31~12.36)/6.98 (2.23~2.68)/2.52 实测 桃源理公港 ∈1n 6(1.21~11.00)/5.30 / 实测 吉首龙鼻咀 ∈1n 16(1.58~8.99)/4.60 / 实测 古丈罗依溪 ∈1n 9(1.41~8.71)/3.60 / 实测 2015H-D5井 ∈1n 152(0.53~14.05)/3.06 2.06 0.05~0.51 实测 吉浅1井 ∈1n 52(1.26~9.34)/3.73 / 0.003~1.260 实测 吉首古者 ∈1n 6(0.12~13.95)/5.23 3(2.07~2.25)/2.17 实测 常页1井 ∈1n 32(0.06~17.60)/3.90 13(2.02~3.13)/2.60 0.5~2.1 林拓等,2014 四路溪 ∈1n (1.27~11.30)/4.91 / 实测 凤凰水打田 ∈1n 5.86 / 李启桂等,2016 2015H-D1 ∈1n 46(3.17~14.80)/7.60 / 0.002 3~1.056 7 实测 沅陵刀背溪 ∈1n 15(0.41~16.30)/5.90 / 实测 溆浦水隘 ∈1n 17(0.84~20.24)/7.47 (2.41~2.72)/2.62 实测 安化烟溪 ∈1n 12(3.55~18.16)/7.30 / 实测 注:TOC(%)=样品数(最大值~最小值)/平均值;Ro(%)=样品数(最大值~最小值)/平均值. 表 3 吉浅1井下寒武统牛蹄塘组有机质类型分布
Table 3. Organic matter types of Niutitang Formation shale in the edge of the Xuefeng ancient uplift
原编号 深度
(m)腐泥组(%) 镜质组(%) 惰质组(%) 类型指数 浮游藻类体 腐泥无定形体 小计 富氢镜质体 正常镜质体 小计 丝质体 15JSQ-8R 810.66 / 91 91 / 1 1 8 82.25 15JSQ-10R 500.38 / 93 93 / / / 7 86.00 15JSQ-12R 495.90 / 94 94 / / / 6 88.00 15JSQ-16R 484.25 / 96 96 / / / 4 92.00 15JSQ-17R 481.35 / 95 95 / / / 5 90.00 15JSQ-20R 472.95 / 97 97 / / / 3 94.00 15JSQ-23R 146.63 / 92 92 / / / 8 84.00 15JSQ-25R 453.40 / 93 93 / 1 1 6 86.25 15JSQ-30R 436.80 / 94 94 / / / 6 88.00 15JSQ-35R 416.80 / 91 91 / / / 9 82.00 15JSQ-39R 407.30 / 92 92 / 1 1 7 84.25 15JSQ-43R 394.40 / 90 90 / 1 1 9 80.25 15JSQ-46R 386.12 / 92 92 / / / 8 84.00 15JSQ-50R 372.90 / 92 92 / / / 8 84.00 15JSQ-55R 350.00 / 94 94 / / / 6 88.00 15JSQ-57R 346.10 / 92 92 / / / 8 84.00 15JSQ-59R 331.33 / 93 93 / / / 7 86.00 15JSQ-62R 323.93 / 93 93 / 1 1 6 86.25 15JSQ-71R 296.20 / 94 94 / / / 6 88.00 15JSQ-74R 288.15 / 92 92 / / / 8 84.00 15JSQ-78R 276.20 / 93 93 / 1 1 6 86.25 15JSQ-86R 239.30 / 94 94 / / / 6 88.00 15JSQ-90R 200.00 / 92 92 / 1 1 7 84.25 -
[1] Bai, D.Y., Jiang, W., Xiong, X., et al., 2015.Control of Tectonic Evolution and Tectonic Framework on the Hydrocarbon Accumulation in the Western Side of the Xuefeng Mountain. Geology and Mineral Resources of South China, 31(2):199-209(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hndzykc201502012 [2] Bai, Y.S., Xiong, C.Y., Wang, C.S., et al., 2010.Tectonic Evolution of North Area of Xuefengshan Uplift and Its Relation to Marine Hydrocarbon Formation. Geology and Mineral Resources of South China, 26(1):68-75(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hndzykc201001012 [3] Chen, X., Chen, Q., Zhen, Y.Y., et al., 2018. Circumjacent Distribution Pattern of the Lungmachian Graptolitic Black Shale (Early Silurian) on the Yichang Uplift and Its Peripheral Region. Science China Earth Sciences, 48(9):1198-1206(in Chinese). http://en.cnki.com.cn/Article_en/CJFDTotal-JDXG201809004.htm [4] Chen, X., Fan, J.X., Chen, Q., et al., 2014. Toward a Stepwise Kwangsian Orogeny. Science China Earth Sciences, 44(5):842-850(in Chinese). http://www.cnki.com.cn/Article/CJFDTotal-JDXG201403001.htm [5] Chen, X., Rong, J.Y., Zhou, Z.Y., et al., 2001. Middle Guizhou Uplift and Yichang Uplift through the Ordovician and Silurian Transition. Chinese Science Bulletin, 46(12): 1052-1056(in Chinese). doi: 10.1360/csb2001-46-12-1052 [6] Chen, X.H., Wang, C.S., Liu, A., et al., 2017.The Discovery of the Shale Gas in the Cambrian Shuijingtuo Formation of Yichang Area, Hubei Province.Geology in China, 44(1):188-189(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgdizhi201701013 [7] Chen, X.H., Wei, K., Zhang, B.M., et al., 2018a.Main Geological Factors Controlling Shale Gas Reservior in the Cambrian Shuijingtuo Formation in Yichang of Hubei Province as Well as Its and Enrichment Patterns.Geology in China, 45(2):207-226(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201802001 [8] Chen, X.H., Zhang, B.M., Zhang, G.T., et al., 2018b.High Shale Gas Industry Flow Obtained from the Ordovician Wufeng Formation and the Silurian Longmaxi Formation of Yichang Area, Hubei Province.Geology in China, 45(1):199-200(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgdizhi201801019 [9] Cheng, K.M., Wang, Z.Y., Zhong, N.N., et al., 1996. Theory and Its Experience of the Oil & Gas Formation of Carbonate Rock. Petroleum Industry Press, Beijing(in Chinese). [10] Chu, Y., Lin, W., 2018. Strain Analysis of the Xuefengshan Belt, South China: From Internal Strain Variation to Formation of the Orogenic Curvature. Journal of Structural Geology, 116: 131-145. doi: 10.1016/j.jsg.2018.08.002 [11] Dai, F.Y., Hao, F., Hu, H.Y., et al., 2017.Occurrence Mechanism and Key Controlling Factors of Wufeng-Longmaxi Shale Gas, Eastern Sichuan Basin. Earth Science, 42(7):1185-1194(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201707014 [12] Deng, Y.N., Guo, Q.J., Zhu, M.Y., et al., 2014.REE Geochemistry of Kerogen from Early Cambrian Black Rock Series in Western Hunan. Earth Science, 39(3):283-292(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201403004 [13] Dong, D.Z., Zou, C.N., Yang, H., et al., 2012.Progress and Prospects of Shale Gas Exploration and Development in China.Acta Petrolei Sinica, 33(Suppl.1):107-114(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SYXB2012S1015.htm [14] Fan, X.L., 1996.The Geological Structure of the Xuefeng Mountains-Yuanma Basin and Its Significance to Oil Exploration.Experimental Petroleum Geology, 18(1) :64-70(in Chinese with English abstract). http://en.cnki.com.cn/CJFD_en_New/Detail.ashx?t=e&url=/Article_en/CJFDTOTAL-SYSD601.005.htm [15] Guo, T.L., Liu, R.B., 2013.Implications from Marine Shale Gas Exploration Breakthrough in Complicated Structural Area at High Thermal Stage: Taking Longmaxi Formation in Well JY1 as an Example. Natural Gas Geoscience, 24(4):643-651(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201304001 [16] Jacob, H., 1985. Disperse Solid Bitumens as an Indicator for Migration and Maturity in Prospecting for Oil and Gas. Erdoland Kohle Erdgas Petrochemie, 38(8):365. [17] Jiang, Y.Q., Dong, D.Z., Qi, L., et al., 2010.Basic Features and Evaluation of Shale Gas Reservoirs. Natural Gas Industry, 30(10):7-12, 113-114(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqgy201010002 [18] Jiao, P., Guo, J.H., Wang, X.K., et al., 2018.Characteristics and Significance of Petrological-Mineralogical of Lower Cambrian Niutitang Formation Shale Gas Reservoir in Northwest Hunan. Journal of Central South University(Science and Technology), 49(6):1447-1458(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/zngydxxb201806018 [19] Jin, Z.J., Hu, Z.Q., Gao, B., et al., 2016.Controlling Factors on the Enrichment and High Productivity of Shale Gas in the Wufeng-Longmaxi Formations, Southeastern Sichuan Basin. Earth Science Frontiers, 23(1):1-10(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/dxqy201601001 [20] Ju, Y.W., Bu, H.L., Wang, G.C., 2014.Main Characteristics of Shale Gas Reservoir and Its Effect on the Reservoir Reconstruction. Advances in Earth Science, 29(4):492-506(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/dqkxjz201404008 [21] Leng, J.G., Gong, D.J., Li, F., et al., 2016.Analyses on the Shale Gas Exploration Prospect of the Niutitang Formation in Northeastern Guizhou Area. Earth Science Frontiers, 23(2):29-38(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/dxqy201602004 [22] Li, J. H., Zhang, Y. Q., Dong, S. W., et al., 2014. Cretaceous Tectonic Evolution of South China: A Preliminary Synthesis. Earth-Science Reviews, 134: 98-136. https://doi.org/10.1016/j.earscirev.2014.03.008 [23] Li, Q.G., Yan, J.H., Wen, T., et al., 2016.Shale Gas Exploration Prospect of Niutitang Formation in Yuanma Basin.Petroleum Geology and Engineering, 30(5):6-11, 138(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-SYHN201605002.htm [24] Li, X.J., Lu, Z.G., Dong, D.Z., et al., 2009.Geologic Controls on Accumulation of Shale Gas in North America. Natural Gas Industry, 29(5):27-32, 135-136(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqgy200905006 [25] Li, Y.X., Zhong, N.N., Lin, J.H., et al., 2011.Accumulation of Upper Cambrian Ancient Reservoir in Wangcun, Southern Margin of Middle Yangtze Region. Petroleum Geology & Experiment, 33(4):408-413(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sysydz201104015 [26] Lin, J.F., Hu, H.Y., Li, Q., 2017.Geochemical Characteristics and Implications of Shale Gas in Jiaoshiba, Eastern Sichuan, China. Earth Science, 42(7):1124-1133(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201707009 [27] Lin, T., Zhang, J.C., Li, B., et al., 2014.Shale Gas Accumulation Conditions and Gas-Bearing Properties of the Lower Cambrian Niutitang Formation in Well Changye 1, Northwestern Hunan. Acta Petrolei Sinica, 35(5):839-846(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syxb201405003 [28] Liu, J.H., Yang, P., Xie, Y., et al., 2012.Characteristics and Hydrocarbon Significance of the Source Rocks of Lower Cambrian Niutitang Formation on the Western Side of the Xuefeng Mountain. Geological Bullet in of China, 31(11):1886-1893(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgqydz201211013 [29] Ma, Z.L., Zheng, L.J., Xu, X.H., et al., 2017.Thermal Simulation Experiment on the Formation and Evolution of Organic Pores in Organic-Rich Shale. Acta Petrolei Sinica, 38(1):23-30(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syxb201701003 [30] Meng, F.Y., Chen, K., Bao, S.J., et al., 2018.Gas-Bearing Property and Main Controlling Factors of Lower Cambrian Shale in Complex Tectonic Area of Northwestern Hunan Province:A Case of Well Ciye 1. Lithologic Reservoirs, 30(5):29-39(in Chinese with English abstract). [31] Miao, F.B., Wang, Q., Bai, Y.S., et al., 2016.Shale Reservoir Characteristics of Ceshui Formation in Lianyuan Depression in the Middle of Hunan Province. Geology and Mineral Resources of South China, 32(2):172-179(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hndzykc201602010 [32] Montgomery, S. L., Jarvie, D. M., Bowker, K. A., et al., 2006. Mississippian Barnett Shale, Fort Worth Basin, North-Central Texas: Gas-Shale Play with Multi–Trillion Cubic Foot Potential: Reply. AAPG Bulletin, 89(2):155-175. https://doi.org/10.1306/09170404042 [33] Nie, H.K., Zhang, J.C., Li, Y.X., 2011.Accumulation Conditions of the Lower Cambrian Shale Gas in the Sichuan Basin and Its Periphery. Acta Petrolei Sinica, 32(6):959-967(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SYXB201106006.htm [34] Robert, G., Stephen, C., 2007. Mississippian Barnett Shale: Lithofacies and Depositional Setting of a Deepwater Shale-Gas Succession in the Fort Worth Basin, Texas. AAPG Bulletin, 91(4):579-601. doi: 10.1306/11020606059 [35] Schettler, P. D. Jr, Parmely, C. R., 1989. Gas Composition Shifts in Devonian Shales. SPE Reservoir Engineering, 4(3): 283-287. https://doi.org/10.2118/17033-pa [36] Sweeney, J.J., Burnham, A.K., 1990. Evaluation of a Simple Model of Vitrinite Reflectance Based on Chemical Kinetics. AAPG Bulletin, 74: 1559-1570. https://doi.org/10.1306/0c9b251f-1710-11d7-8645000102c1865d [37] Wang, C.S., Li, X.B., Li, Z.H., et al., 2012.Cambrian Sequence-Stratigraphy in the Middle and Upper Yangtze Platform. Journal of Stratigraphy, 36(4):773-783(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DCXZ201204017.htm [38] Wang, Y.M., Huang, J.L., Wang, S.F., et al., 2016.Dissection of Two Calibrated Areas of the Silurian Longmaxi Formation, Changning and Jiaoshiba, Sichuan Basin. Natural Gas Geoscience, 27(3):423-432(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201603004 [39] Wang, Z.J., Xie, Y., Yang, P., et al., 2012.Marine Basin Evolution and Oil and Gas Geology of Sinian-Early Paleozoic Period on the Western Side of the Xuefeng Mountain. Geological Bulletin of China, 31(11):1795-1811(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgqydz201211005 [40] Wu, K.Y., Zhang, T.S., Yang, Y., et al., 2016.Geological Characteristics of Wufeng-Longmaxi Shale-Gas Reservoir in the Huangjinba Gas Field, Zhaotong National Shale Gas Demonstration Area. Geology in China, 43(1):275-287(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgdizhi201601020 [41] Xiao, Z.H., Wang, Z.H., Yang, R.F., et al., 2013.Reservoir Conditions of Shale Gas in the Lower Cambrian Niutitang Formation, Northwestern Hunan. Acta Geologica Sinica, 87(10):1612-1623(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/zngydxxb201805018 [42] Xie, X.N., Hao, F., Lu, Y.C., et al., 2017.Differential Enrichment Mechanism and Key Technology of Shale Gas in Complex Areas of South China. Earth Science, 42(7):1045-1056(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201707002 [43] Zhai, G.Y., Bao, S.J., Wang, Y.F., et al., 2017.Reservoir Accumulation Model at the Edge of Palaeohigh and Significant Discovery of Shale Gas in Yichang Area, Hubei Province. Acta Geoscientica Sinica, 38(4):441-447(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqxb201704001 [44] Zhang, J., Wang, L.S., Yang, Y.M., et al., 2016.The Development and Application of the Evaluation Method of Marine Shale Gas in Sichuan Basin. Natural Gas Geoscience, 27(3):433-441(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201603005 [45] Zhang, J.C., Jin, Z.J., Yuan, M.S., 2004.Reservoiring Mechanism of Shale Gas and Its Distribution. Natural Gas Industry, 24(7):15-18, 131-132(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqgy200407005 [46] Zhang, J.C., Xu, B., Nie, H.K., et al., 2008.Exploration Potential of Shale Gas Resources in China. Natural Gas Industry, 28(6):136-140, 159-160(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/qdhydxxb-e201804008 [47] Zhang, Z.P., Cheng, L.J., Liu, J.F., et al., 2013. Reservoirs Forming Conditions to from Shale-Gas Reservoirs of Lower Silurian Longmaxi Formation, Baojing Area, Hunan Province. Natural Gas Exploration & Development, 36(3):4-6(in Chinese with English abstract). [48] Zhou, P., Peng, Z.Q, Luo, S.Y., 2018. Sequence Stratigraphy and Organic Carbon Contents of the Cambrian Niutitang Formation in the Jishou Area, Hunan Province. Journal of Stratigraphy, 42(1):9-17(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dcxzz201801003 [49] Zhou, Q.H., Song, N., Wang, C.Z., et al., 2014.Geological Evaluation and Exploration Prospect of Huayuan Shale Gas Block in Hunan Province. Natural Gas Geoscience, 25(1):130-140(in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201401015 [50] Zou, C.N., Dong, D.Z., Wang, S.J., et al., 2010.Geological Characteristics, Formation Mechanism and Resource Potential of Shale Gas in China. Petroleum Exploration and Development, 37(6):641-653(in Chinese with English abstract). doi: 10.1016/S1876-3804(11)60001-3 [51] 柏道远, 姜文, 熊雄, 等, 2015.雪峰山西侧构造演化和构造格局对区域油气成藏条件的控制.华南地质与矿产, 31(2):199-209. doi: 10.3969/j.issn.1007-3701.2015.02.011 [52] 白云山, 熊成云, 王传尚, 等, 2010.雪峰隆起北部地区构造基本特征及与海相油气关系.华南地质与矿产, 26(1):68-75. doi: 10.3969/j.issn.1007-3701.2010.01.012 [53] 陈孝红, 王传尚, 刘安, 等, 2017.湖北宜昌地区寒武系水井沱组探获页岩气.中国地质, 44(1):188-189. http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201701013 [54] 陈孝红, 危凯, 张保民, 等, 2018a.湖北宜昌寒武系水井沱组页岩气藏主控地质因素和富集模式.中国地质, 45(2):207-226. http://d.old.wanfangdata.com.cn/Periodical/zgdizhi201802001 [55] 陈孝红, 张保民, 张国涛, 等, 2018b.湖北宜昌地区奥陶系五峰组-志留系龙马溪组获页岩气高产工业气流.中国地质, 45(1):199-200. http://www.cnki.com.cn/Article/CJFDTotal-DIZI201801021.htm [56] 陈旭, 陈清, 甄勇毅, 等, 2018.志留纪初宜昌上升及其周缘龙马溪组黑色笔石页岩的圈层展布模式.中国科学:地球科学, 48(9):1198-1206. http://www.cnki.com.cn/Article/CJFDTotal-JDXK201809006.htm [57] 陈旭, 樊隽轩, 陈清, 等, 2014.论广西运动的阶段性.中国科学:地球科学, 44(5):842-850. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd201405002 [58] 陈旭, 戎嘉余, 周志毅, 等, 2001.上扬子区奥陶-志留纪之交的黔中隆起和宜昌上升.科学通报, 46(12):1052-1056. doi: 10.3321/j.issn:0023-074X.2001.12.021 [59] 程克明, 王兆云, 钟宁宁, 等, 1996.碳酸盐岩油气生成理论与实践.北京:石油工业出版社. [60] 戴方尧, 郝芳, 胡海燕, 等, 2017.川东焦石坝五峰-龙马溪组页岩气赋存机理及其主控因素.地球科学, 42(7):1185-1194. doi: 10.3799/dqkx.2017.096 [61] 邓义楠, 郭庆军, 朱茂炎, 等, 2014.湘西寒武纪早期黑色岩系中干酪根的稀土元素地球化学特征.地球科学, 39(3):283-292. doi: 10.3799/dqkx.2014.027 [62] 董大忠, 邹才能, 杨桦, 等, 2012.中国页岩气勘探开发进展与发展前景.石油学报, 33(S1):107-114. doi: 10.7623/syxb2012S1013 [63] 范小林, 1996.雪峰山系-沅麻盆地地质结构及找油意义.石油实验地质, 18(1) :64-70. http://www.cnki.com.cn/Article/CJFDTotal-SYSD601.005.htm [64] 郭彤楼, 刘若冰, 2013.复杂构造区高演化程度海相页岩气勘探突破的启示——以四川盆地东部盆缘JY1井为例.天然气地球科学, 24(4):643-651. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201304001 [65] 蒋裕强, 董大忠, 漆麟, 等, 2010.页岩气储层的基本特征及其评价.天然气工业, 30(10):7-12, 113-114. http://d.old.wanfangdata.com.cn/Periodical/trqgy201010002 [66] 焦鹏, 郭建华, 王玺凯, 等, 2018.湘西北牛蹄塘组页岩气储层岩矿特征及意义.中南大学学报(自然科学版), 49(6):1447-1458. http://d.old.wanfangdata.com.cn/Periodical/zngydxxb201806018 [67] 金之钧, 胡宗全, 高波, 等, 2016.川东南地区五峰组-龙马溪组页岩气富集与高产控制因素.地学前缘, 23(1):1-10. http://d.old.wanfangdata.com.cn/Periodical/dxqy201601001 [68] 琚宜文, 卜红玲, 王国昌, 2014.页岩气储层主要特征及其对储层改造的影响.地球科学进展, 29(4):492-506. http://d.old.wanfangdata.com.cn/Periodical/hggl201612125 [69] 冷济高, 龚大建, 李飞, 等, 2016.黔东北地区牛蹄塘组页岩气勘探前景分析.地学前缘, 23(2):29-38. http://d.old.wanfangdata.com.cn/Periodical/dxqy201602004 [70] 李启桂, 燕继红, 闻涛, 等, 2016.沅麻盆地牛蹄塘组页岩气勘探前景分析.石油地质与工程, 30(5):6-11, 138. doi: 10.3969/j.issn.1673-8217.2016.05.002 [71] 李新景, 吕宗刚, 董大忠, 等, 2009.北美页岩气资源形成的地质条件.天然气工业, 29(5):27-32, 135-136. doi: 10.3787/j.issn.1000-0976.2009.05.006 [72] 李艳霞, 钟宁宁, 林娟华, 等, 2011.中扬子南缘王村上寒武统古油藏成藏剖析.石油实验地质, 33(4):408-413. doi: 10.3969/j.issn.1001-6112.2011.04.015 [73] 林俊峰, 胡海燕, 黎祺, 2017.川东焦石坝地区页岩气特征及其意义.地球科学, 42(7):1124-1133. doi: 10.3799/dqkx.2017.091 [74] 林拓, 张金川, 李博, 等, 2014.湘西北常页1井下寒武统牛蹄塘组页岩气聚集条件及含气特征.石油学报, 35(5):839-846. http://d.old.wanfangdata.com.cn/Periodical/syxb201405003 [75] 刘家洪, 杨平, 谢渊, 等, 2012.雪峰山西侧地区下寒武统牛蹄塘组烃源岩特征与油气地质意义.地质通报, 31(11):1886-1893. doi: 10.3969/j.issn.1671-2552.2012.11.013 [76] 马中良, 郑伦举, 徐旭辉, 等, 2017.富有机质页岩有机孔隙形成与演化的热模拟实验.石油学报, 38(1):23-30. http://d.old.wanfangdata.com.cn/Periodical/syxb201701003 [77] 孟凡洋, 陈科, 包书景, 等, 2018.湘西北复杂构造区下寒武统页岩含气性及主控因素分析——以慈页1井为例.岩性油气藏, 30(5):29-39. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yxyqc201805004 [78] 苗凤彬, 王强, 白云山, 等, 2016.湘中地区涟源凹陷石炭系测水组泥页岩储层特征.华南地质与矿产, 32(2):172-179. doi: 10.3969/j.issn.1007-3701.2016.02.010 [79] 聂海宽, 张金川, 李玉喜, 2011.四川盆地及其周缘下寒武统页岩气聚集条件.石油学报, 32(6):959-967. doi: 10.3969/j.issn.1001-8719.2011.06.020 [80] 王传尚, 李旭兵, 李志宏, 等, 2012.中上扬子区寒武纪层序地层划分与对比.地层学杂志, 36(4):773-783. http://www.cnki.com.cn/Article/CJFDTotal-DCXZ201204017.htm [81] 王玉满, 黄金亮, 王淑芳, 等, 2016.四川盆地长宁、焦石坝志留系龙马溪组页岩气刻度区精细解剖.天然气地球科学, 27(3):423-432. http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201603004 [82] 汪正江, 谢渊, 杨平, 等, 2012.雪峰山西侧震旦纪-早古生代海相盆地演化与油气地质条件.地质通报, 31(11):1795-1811. doi: 10.3969/j.issn.1671-2552.2012.11.005 [83] 伍坤宇, 张廷山, 杨洋, 等, 2016.昭通示范区黄金坝气田五峰-龙马溪组页岩气储层地质特征.中国地质, 43(1):275-287. doi: 10.3969/j.issn.1000-3657.2016.01.020 [84] 肖正辉, 王朝晖, 杨荣丰, 等, 2013.湘西北下寒武统牛蹄塘组页岩气储集条件研究.地质学报, 87(10):1612-1623. http://d.old.wanfangdata.com.cn/Periodical/dizhixb201310010 [85] 解习农, 郝芳, 陆永潮, 等, 2017.南方复杂地区页岩气差异富集机理及其关键技术.地球科学, 42(7):1045-1056. doi: 10.3799/dqkx.2017.084 [86] 翟刚毅, 包书景, 王玉芳, 等, 2017.古隆起边缘成藏模式与湖北宜昌页岩气重大发现.地球学报, 38(4):441-447. http://d.old.wanfangdata.com.cn/Periodical/dqxb201704001 [87] 张鉴, 王兰生, 杨跃明, 等, 2016.四川盆地海相页岩气选区评价方法建立及应用.天然气地球科学, 27(3):433-441. http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201603005 [88] 张金川, 金之钧, 袁明生, 2004.页岩气成藏机理和分布.天然气工业, 24(7):15-18, 131-132. doi: 10.3321/j.issn:1000-0976.2004.07.005 [89] 张金川, 徐波, 聂海宽, 等, 2008.中国页岩气资源勘探潜力.天然气工业, 28(6):136-140, 159-160. doi: 10.3787/j.issn.1000-0976.2008.06.040 [90] 张志平, 程礼军, 刘俊峰, 等, 2013.湖南保靖下志留统龙马溪组页岩气成藏地质条件评价.天然气勘探与开发, 36(3): 4-6. doi: 10.3969/j.issn.1673-3177.2013.03.002 [91] 周鹏, 彭中勤, 罗胜元, 2018.吉首斜坡带寒武系牛蹄塘组层序地层划分对比及有机碳含量变化探讨.地层学杂志, 42(1):9-17. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dcxzz201801003 [92] 周庆华, 宋宁, 王成章, 等, 2014.湖南花垣页岩气区块地质评价与勘探展望.天然气地球科学, 25(1):130-140. http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201401015 [93] 邹才能, 董大忠, 王社教, 等, 2010.中国页岩气形成机理、地质特征及资源潜力.石油勘探与开发, 37(6):641-653. http://d.old.wanfangdata.com.cn/Periodical/syktykf201006001