Pb同位素对努日铜钼钨多金属矿床成矿物源的制约

闫国强; 王欣欣; 黄勇; 李光明; 刘洪; 黄瀚霄; 张志; 田恩源; 赖杨

doi:10.3799/dqkx.2019.191

Pb同位素对努日铜钼钨多金属矿床成矿物源的制约

doi: 10.3799/dqkx.2019.191

闫国强^1,2, ,,
王欣欣^3, ,,
黄勇⁴,
李光明⁴,
刘洪⁴,
黄瀚霄⁴,
张志⁴,
田恩源⁵,
赖杨⁵

1.
中国地质调查局天津地质调查中心, 天津 300170
2.
中国地质调查局铀矿地质重点实验室, 天津 300170
3.
山西大同大学煤炭工程学院, 山西大同 037003
4.
中国地质调查局成都地质调查中心, 四川成都 610081
5.
中国地质调查局成都矿产综合利用研究所, 四川成都 610061

基金项目:

国家自然科学基金项目 41702080

国家重点研发计划 2016YFC0600308

国家重点研发计划 SQ2018YFC060162

中国地质调查项目 DD20190813

详细信息

作者简介:
闫国强(1985-), 男, 工程师, 博士, 从事矿床成因、矿床地球化学研究

通讯作者:
王欣欣

中图分类号: P597
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出版历程
- 收稿日期: 2019-08-02
- 刊出日期: 2020-01-15

Constraint of Pb Isotope on Ore-Forming Source Origin of Nuri Polymetallic Deposit, Tibet

Yan Guoqiang^{1,2
,
,},
Wang Xinxin^{3
, ,},
Huang Yong⁴,
Li Guangming⁴,
Liu Hong⁴,
Huang Hanxiao⁴,
Zhang Zhi⁴,
Tian Enyuan⁵,
Lai Yang⁵

1.
Tianjin Center, China Geological Survey, Tianjin 300170, China
2.
Key Laboratory of Uranium Geology, China Geological Survey, Tianjin 300170, China
3.
Institute of Coal Engineering, Shanxi Datong University, Datong 037003, China
4.
Chengdu Center, China Geological Survey, Chengdu 610081, China
5.
Institute of Mineral Resources Multi-Utilization, China Geological Survey, Chengdu 610061, China

摘要

摘要: 西藏努日铜钼钨矿是冈底斯成矿带规模最大的首例含白钨矿多金属矿床，对于矿床的成矿物质来源还存在较大的争议.为厘定努日铜钼钨矿的成矿物质来源，对矿区的侵入岩和各类硫化物进行了Pb同位素研究，研究结果表明，矿区各类辉钼矿、黄铁矿具有较为一致的Pb同位素组成：²⁰⁶Pb/²⁰⁴Pb比值为17.525~18.581；²⁰⁷Pb/²⁰⁴Pb比值为15.621~15.661；²⁰⁸Pb/²⁰⁴Pb比值为37.524~38.929.黄铜矿的²⁰⁶Pb/²⁰⁴Pb比值为18.414~18.578；²⁰⁷Pb/²⁰⁴Pb比值为15.619~15.642；²⁰⁸Pb/²⁰⁴Pb比值为38.617~38.863，且黄铜矿存在明显的分组特征.S-Pb同位素特征表明：努日铜钼钨矿的成矿物质主要来源于地幔，矿床的辉钼矿Re-Os同位素特征也暗示其成矿物质主要来源于地幔.该矿床可能是在印度板块向欧亚板块俯冲-碰撞-伸展构造环境下，印度陆块下地壳部分熔融形成的熔体在其向上运移过程中与俯冲洋壳释放出的富含Fe³⁺的流体发生混合后，与雅鲁藏布江MORB亏损地幔橄榄岩发生交代作用，Fe³⁺氧化地幔中赋存的各类硫化物后，使得成矿物质Cu、Mo等被释放进入岩浆系统；并在上升过程中萃取了部分加厚下地壳部分熔融形成黑云母花岗岩中的Cu等，最终在浅部与围岩发生接触交代形成努日铜钼钨多金属矿床.
- 努日铜钼钨矿床 /
- Pb同位素 /
- 成矿物源 /
- 冈底斯 /
- 埃达克质斑岩 /
- 地球化学
Abstract: The Nuri Polymetallic Deposit,Tibet,is the largest and first scheelite deposit in Gangdese,and there have been some controversies on the ore-forming source of this deposit. The Pb isotope analyses of molybdenite,chalcopyrite,and pyrites from the mine have been carried out to determine the source. The results show that the molybdenite and pyrites have the consistent Pb isotopes,with ²⁰⁶Pb/²⁰⁴Pb ratios ranging from 17.525-18.581,²⁰⁷Pb/²⁰⁴Pb ratios ranging from 15.621-15.661,²⁰⁸Pb/²⁰⁴Pb ratios ranging from 37.524-38.929,and the chalcopyrite with ²⁰⁶Pb/²⁰⁴Pb ratios ranging from 18.414-18.578,²⁰⁷Pb/²⁰⁴Pb ratios ranging from 15.619-15.642,and ²⁰⁸Pb/²⁰⁴Pb ratios ranging from 38.617-38.863,respectively,which have obvious grouping characteristics. The S and Pb isotope features indicate that the ore-forming sources are mainly derived from the mantle,and the Re-Os isotope characteristics of molybdenite indicate that the minerals are mainly derived from mantle. The melt from the lower crust of India continent partial melting migrated upward and mixed with the Fe³⁺ enriched fluid derived from the subducted oceanic crust,which metasomatized with Yarlung Zangbo MORB peridotite,and the Cu,Mo were released into the magma system after oxidezed by Fe³⁺,thus,Cu and other elements in biotite granite which partially melted in the thickened lower crust were extracted in the rising process,finally formed the deposit by contact metasomatism with the wall rock.
- Nuri Polymetallic /
- Pb isotope /
- ore-forming source /
- Gangdese /
- adakite porphyry /
- geochemistry

HTML全文

图 1 西藏山南区域地质图及努日矿区地质简图

Fig. 1. The regional geological map and sketch map of Nuri deposit

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图 2 西藏山南努日矿区各类岩浆岩的岩石学特征

a.石英闪长玢岩及镜下角闪石斑晶；b.黑云母花岗岩及镜下见黑云母；c.花岗闪长斑岩及镜下半自形角闪石；d.安山岩及镜下隐晶质基质. Hbl.普通角闪石；Bit.黑云母；Pl.斜长石；Q.石英

Fig. 2. The characteristics of various magmatic rocks in Nuri deposit

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图 3 努日铜钼钨多金属矿床矿石特征及显微镜下照片

FI.萤石；Sch.白钨矿；Mo.辉钼矿；Cp.黄铜矿；Dg.蓝辉铜矿；Py.黄铁矿

Fig. 3. Photomicrographs showing ore minerals from the Nrui deposit

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图 4 西藏努日铜钼钨多金属矿床中矿石的Pb同位素来源判别图解

数据来自表 1

Fig. 4. Discrimination diagram for lead isotopic sources of ores from the Nuri polymetallic deposit

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图 5 西藏山南努日矿床中辉钼矿、黄铜矿、黄铁矿的Pb同位素构造环境判别图解

数据来源于表 1；底图据Zartman et al. (1981)；1.地幔源铅；2.上地壳铅；3.上地壳与地幔混合的俯冲带铅，3a.岩浆作用，3b.沉积作用；4.化学沉积型铅；5.海底热水作用铅；6.中深变质作用铅；7.深变质下地壳铅；8.造山带铅；9.古老页岩上地壳铅；10.退变质铅；A.地幔(Mantle)；B.造山带(Orogene)；C.上地壳(Upper Crust)；D.下地壳(Lower Crust)

Fig. 5. Plumbotectonic framework diagrams of molybdenite, chalcopyrite and pyrites from the Nuri polymetallic deposit

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图 6 西藏山南努日矿床辉钼¹⁸⁷Re同位素物源判别图解

底图据Zhou et al. (2013)；数据来源于张松等(2012b)、闫学义等(2010)

Fig. 6. The discriminant diagram of molybdenum ¹⁸⁷Re isotope from the Nuri polymetallic deposit

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表 1 西藏努日铜钼钨多金属矿床侵入岩、矿石硫化物的Pb同位素数据

Table 1. Pb isotope analysis data for instrusive rock and sulfide minerals in the Nuri polymetallic deposit

样品编号	测试对象	²⁰⁶Pb/²⁰⁴Pb	²⁰⁷Pb/²⁰⁴Pb	²⁰⁸Pb/²⁰⁴Pb	数据来源
NR-1	花岗闪长斑岩	18.597	15.697	38.973	王勤等，2018
NR-2		18.572	15.696	38.871
NR-3		18.597	15.744	39.029
NR-5		18.625	15.667	38.952
NR-6		18.579	15.687	38.848
ZK1005-384.12 m	花岗闪长斑岩	18.589	15.655	38.984	来自本文
ZK1005-379.57 m		18.571	15.641	38.912
ZK1005-394 m		18.591	15.654	38.981
005-R-1	黑云母花岗岩	18.541	15.587	38.625
005-R-2		18.565	15.601	38.678
005-R-3		18.55	15.597	38.653
ZK4501-124.8	黄铜矿	18.441	15.619	38.617	王立强等，2014
ZK4103-258.6	辉钼矿	18.513	15.629	38.839
ZK4103-310.4	黄铁矿	17.525	15.549	37.524
ZK4103-310.6	黄铜矿	18.578	15.633	38.836
ZK4103-311.4	辉钼矿	18.533	15.635	38.871
ZK4103-317.4	辉钼矿	18.555	15.621	38.827
ZK4103-473.8	黄铜矿	18.568	15.642	38.863
ZK4103-474.9	黄铁矿	18.555	15.642	38.909
ZK4901-130.9	黄铁矿	18.539	15.63	38.871
ZK4901-153.35	黄铜矿	18.518	15.624	38.811
ZK3701-213.5	黄铜矿	18.414	15.619	38.695
ZK3701-355.2	黄铁矿	18.548	15.643	38.916
ZK3701-358.31	辉钼矿	18.539	15.631	38.879
ZK3701-399.2	辉钼矿	18.555	15.643	38.918
ZK3701-447.7	辉钼矿	18.581	15.661	38.929
ZK3701-513	黄铜矿	18.499	15.63	38.802
ZK3701-513.4	黄铁矿	18.545	15.64	38.895

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表 2 西藏努日铜钼钨矿床硫化物矿石硫同位素组成

Table 2. S isotope compositons of the sulfide minerals from the Nuri polymetallic deposit

样品编号	测试对象	δ³⁴S (‰)	数据来源
ZK4501-124.8	黄铜矿	-1.2	王立强等，2014
ZK4103-258.6	辉钼矿	-0.3
ZK4103-310.4	黄铁矿	-0.5
ZK4103-310.6	黄铜矿	-1.2
ZK4103-311.4	辉钼矿	0.6
ZK4103-317.4	辉钼矿	0.3
ZK4103-473.8	黄铜矿	-0.6
ZK4103-474.9	黄铁矿	0.1
ZK4901-130.9	黄铁矿	-0.1
ZK4901-153.35	黄铜矿	-0.8
ZK3701-213.5	黄铜矿	-2.9
ZK3701-355.2	黄铁矿	-1.0
ZK3701-358.31	辉钼矿	-0.1
ZK3701-399.2	辉钼矿	0.0
ZK3701-447.7	辉钼矿	-0.1
ZK3701-513	黄铜矿	-1.4
ZK3701-513.4	黄铁矿	-0.3
ZK4103-506	黄铁矿	0.8	Chen et al., 2012
ZK4103-461	黄铁矿	0.9
ZK4103-254	黄铁矿	0.7
ZK4103-304	黄铁矿	-0.3
ZK4103-471	黄铁矿	0.8
ZK1203-198	黄铁矿	1.1
ZK4501-194	黄铁矿	0.7
ZK1203-258	黄铜矿	-0.3
ZK4501-215	黄铜矿	0.6
ZK4103-306	黄铜矿	-0.2
ZK4501-126	黄铜矿	-0.3
ZK4502-306	辉钼矿	0.4
ZK4501-194	辉钼矿	-0.4
ZK1203-362	辉钼矿	0.3
LB4101-194	黄铜矿	1.0	Li et al., 2006
LB4101-194-1	黄铁矿	1.8
LB4101-67.6	黄铁矿	1.3
LB4101-159	黄铁矿	1.7

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