辽宁后仙峪硼矿区古元古代电气石岩: 锆石特征及SHRIMP定年

张艳飞; 刘敬党; 肖荣阁; 王生志; 王瑾; 包德军

doi:10.3799/dqkx.2010.112

辽宁后仙峪硼矿区古元古代电气石岩: 锆石特征及SHRIMP定年

doi: 10.3799/dqkx.2010.112

张艳飞^{1, 2,},
刘敬党^{1, 2},
肖荣阁³,
王生志²,
王瑾²,
包德军²

1.
辽宁工程技术大学, 辽宁阜新 123000
2.
辽宁省化工地质勘查院, 辽宁锦州 121000
3.
中国地质大学地球科学与资源学院, 北京 100083

基金项目:

国家自然科学基金项目 40073013

辽宁省国土资源厅基金项目 20050142

详细信息

作者简介:
张艳飞(1982-), 男, 在读博士生, 主要从事矿床地球化学研究.E-mail: zhangyanfei1234@163.com

中图分类号: P597
计量
- 文章访问数: 3097
- HTML全文浏览量: 172
- PDF下载量: 64
- 被引次数: 0
出版历程
- 收稿日期: 2010-05-15
- 刊出日期: 2010-11-01

The Hyalotourmalites of Houxianyu Borate Deposit in Eastern Liaoning: Zircon Features and SHRIMP Dating

1.
Liaoning Technical University, Fuxin 123000, China
2.
Liaoning Geological Survey for Chemical Industry, Jinzhou 121000, China
3.
School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China

摘要

摘要: 为了确定辽东硼矿含硼岩系中电气石岩的形成时代, 对后仙峪硼矿区电气石岩首次进行了锆石SHRIMP U-Pb年龄测定.阴极发光图像显示, 锆石具核-边结构, 锆石核部多具振荡环带, 为高Th/U值的岩浆碎屑锆石; 锆石边部无明显结构变化, 为变质成因.岩浆碎屑锆石和变质锆石的年龄分别为2 171~2 175 Ma和1 894~1 906 Ma.结合野外地质和岩相学研究, 认为后仙峪硼矿区电气石岩原岩为古元古代克拉通裂谷环境中源于地壳再循环组分混染的亏损地幔的中酸性岩浆活动引发海底喷流作用的产物, 其原岩形成时代为古元古代中期(2 171~2 175 Ma), 并在稍后(1 894~1 906 Ma)遭受变质作用叠加改造.
- 电气石岩 /
- SHRIMP /
- 后仙峪硼矿区 /
- 古元古代 /
- 地质年代
Abstract: SHRIMP zircon U-Pb dating results are firstly reported for the hyalotourmalites in Houxianyu borate deposit in order to determine its formation time. The zircons commonly have core-rim structures. Most cores show oscillatory zoning in CL and plane polarized light images, suggesting a magmatic detrital origin. The zircon without distinct structural change may represent a metamorphic origin. Magmatic detrital zircons and metamorphic zircons from three samples yield ages of 2 171-2 175 Ma and 1 894-1 906 Ma, respectively. Combined with geology and lithology, the protolith of hyalotourmalite is concluded to be the product of exhalation of submarine hot water caused by the magmatic activity with the magma derived from the depleted mantle source with crustal contamination in the cratonic rift environment, which occurred in the middle Palaeoproterozoic (2 171-2 175 Ma) and underwent the late metamorphism during a period of 1 894-1 906 Ma.
- hyalotourmalite /
- SHRIMP dating /
- Houxianyu boron deposit /
- Palaeoproterozoic /
- geochronology

HTML全文

图 1 后仙峪硼矿床地质略图(据黄作良等(1996)修改)

1.古元古界电气石变粒岩夹黑云变粒岩；2.古元古界黑云变粒岩；3.古元古界蛇纹石化镁橄榄岩及镁质大理岩；4.古元古界电英岩；5.硼矿体；6.片麻状花岗岩；7.伟晶岩；8.闪长玢岩；9.斜长煌斑岩；10.闪长岩；11.推测断层；12.地层产状；13.第四系；14.太古宙古陆；15.裂谷斜坡区；16.裂谷中央凹陷区；17.控制裂谷的深大断裂；18.古断裂；19.地质界线；20.取样位置

Fig. 1. Geological map of the Houxianyu boron deposit

下载: 全尺寸图片幻灯片

图 2 电气石岩的宏观和微观构造特点

a.条带(纹)状电气石岩；b.厚层状电气石岩被石英细脉切割；c.电气石岩中较自形的电气石颗粒；d.电气石岩中电气石的筛状结构；Tou.电气石；Q.石英

Fig. 2. Tectonites in the hyalotourmalites at different scales

下载: 全尺寸图片幻灯片

图 3 后仙峪硼矿区电气石岩(N13、N14、N02)的锆石阴极发光照片

图中椭圆(~30 μm)为锆石SHRIMP U-Pb测年位置，其编号与表 1中一致

Fig. 3. Cathodoluminescence images of zircons from hyalotourmalite(N13, N14, N02) in Houxianyu borate deposit

下载: 全尺寸图片幻灯片

图 4 后仙峪硼矿区电气石岩锆石SHRIMP U-Pb年龄谐和图

Fig. 4. Concordia diagrams of SHRIMP U-Pb data for zircons from hyalotourmalites in Houxianyu borate deposit

下载: 全尺寸图片幻灯片

表 1 后仙峪硼矿区电气石岩锆石SHRIMP U-Pb年龄测定结果

Table 1. SHRIMP U-Pb isotope data for zircons from hyalotourmalite in Houxianyu borate deposit

样点	206Pb_c(%)	U(10^-6)	Th(10^-6)	²³²Th/²³⁸U	²⁰⁶Pb^* (10^-6)	²⁰⁶Pb/²³⁸U 年龄(Ma)	²⁰⁷Pb/²⁰⁶Pb 年龄(Ma)	不和谐度 (%)	²⁰⁷Pb^/²⁰⁶Pb^	±%	²⁰⁷Pb^*/²³⁵U	±%	²⁰⁶Pb^*/²³⁸U	±%	相关误差
中粗粒电气石岩(N13)
1.1C	0.08	138	77	0.57	47.1	2 152±28	2 154±13	0	0.134 25	0.73	7.340	1.7	0.396 3	1.5	0.899
2.1C	0.05	814	274	0.35	241.0	1 906±23	2 055± 5.7	7	0.126 88	0.32	6.017	1.4	0.343 9	1.4	0.974
2.2R	0.03	587	14	0.02	168.0	1 859±24	1 910±7.2	3	0.116 99	0.40	5.391	1.6	0.334 2	1.5	0.967
2.3R	0.01	496	25	0.05	148.0	1 921±25	1 902±12	-1	0.116 42	0.65	5.572	1.6	0.347 1	1.5	0.916
3.1C	0.17	167	84	0.52	57.8	2 177±28	2 163±13	-1	0.134 88	0.72	7.470	1.7	0.401 7	1.5	0.901
3.2R	0.01	492	18	0.04	132.0	1 756±22	1 902±8.2	8	0.116 45	0.45	5.028	1.5	0.313 1	1.4	0.953
4.1C	0.03	306	182	0.61	101.0	2 094±26	2 177±8.5	4	0.136 07	0.49	7.200	1.5	0.383 7	1.4	0.947
4.2R	0.05	474	23	0.05	139.0	1 895±23	1 893±8.3	0	0.115 86	0.46	5.460	1.5	0.341 8	1.4	0.951
5.1C	0.01	180	90	0.51	61.3	2 150±28	2 179±11	1	0.136 13	0.64	7.430	1.6	0.396 0	1.5	0.920
6.1C	0.07	944	123	0.13	145.0	1 060±21	1 541±10	31	0.095 65	0.54	2.357	2.2	0.178 7	2.2	0.970
7.1C	0.04	298	148	0.51	103.0	2 178±27	2 179±8.2	0	0.136 20	0.47	7.550	1.5	0.402 0	1.4	0.950
7.2R	0.04	602	17	0.03	185.0	1 973±24	1 918±7.0	-3	0.117 49	0.39	5.800	1.5	0.358 0	1.4	0.964
8.1C	0.06	129	86	0.69	45.9	2 230±29	2 173±13	-3	0.135 73	0.72	7.740	1.7	0.413 4	1.6	0.907
8.2R	0.01	537	29	0.06	155.0	1 873±23	1 897±7.5	1	0.116 13	0.42	5.400	1.5	0.337 2	1.4	0.959
9.1C	0.03	346	270	0.81	122.0	2 213±28	2 169±7.6	-2	0.135 43	0.43	7.650	1.6	0.409 5	1.5	0.960
9.2R	0.03	562	30	0.06	171.0	1 954±24	1 912±7.4	-2	0.117 08	0.41	5.717	1.5	0.354 1	1.4	0.960
10.1C	0.04	159	88	0.57	58.8	2 302±31	2 199±11	-5	0.137 76	0.63	8.150	1.7	0.429 3	1.6	0.929
10.2R	0.03	649	27	0.04	197.0	1 951±47	1 911±6.7	-2	0.117 01	0.37	5.700	2.8	0.353 3	2.8	0.991
11.1C	0.02	446	223	0.52	158.0	2 229±29	2 178±6.9	-2	0.136 11	0.40	7.750	1.6	0.413 1	1.5	0.968
11.2R	0.02	467	18	0.04	134.0	1 854±24	1 916±9.4	3	0.117 38	0.53	5.395	1.6	0.333 3	1.5	0.944
12.1C	0.07	216	125	0.60	73.2	2 142±27	2 163±9.4	1	0.134 95	0.54	7.330	1.6	0.394 1	1.5	0.939
12.2R	0.01	547	20	0.04	161.0	1 903±23	1 889±7.2	-1	0.115 58	0.40	5.472	1.5	0.343 4	1.4	0.963
13.1C	0.01	172	99	0.59	58.8	2 156±27	2 182±11	1	0.136 38	0.65	7.470	1.6	0.397 2	1.5	0.916
13.2R	0.03	475	22	0.05	136.0	1 857±23	1 899±8.2	2	0.116 26	0.46	5.353	1.5	0.333 9	1.4	0.951
14.1C	0.15	123	67	0.56	42.4	2 165±29	2 164±14	0	0.135 00	0.82	7.430	1.8	0.399 1	1.6	0.887
14.2R	0.02	534	23	0.04	145.0	1 766±22	1 904±7.6	7	0.116 57	0.42	5.065	1.5	0.315 1	1.4	0.958
15.1C	0.02	386	154	0.41	135.0	2 201±27	2 172±8.6	-1	0.135 66	0.50	7.610	1.5	0.407 0	1.4	0.944
16.1C	0.04	198	137	0.72	67.6	2 161±27	2 183±10	1	0.136 51	0.58	7.500	1.6	0.398 3	1.5	0.930
16.2R	0.01	714	27	0.04	213.0	1 922±23	1 919±6.3	0	0.117 59	0.35	5.633	1.5	0.347 4	1.4	0.971
17.1C	0.09	138	68	0.51	48.0	2 187±32	2 180±13	0	0.136 27	0.73	7.590	1.9	0.403 8	1.7	0.920
17.2R	-	484	21	0.05	146.0	1 938±24	1 905±7.6	-2	0.116 63	0.42	5.638	1.5	0.350 6	1.4	0.958
18.1C	0.00	149	134	0.93	49.6	2 111±30	2 197±13	4	0.137 60	0.74	7.350	1.8	0.387 5	1.7	0.912
18.2R	0.02	562	30	0.06	156.0	1 801±22	1 900±9.8	5	0.116 34	0.55	5.171	1.5	0.322 3	1.4	0.933
19.1C	0.06	135	147	1.13	44.1	2 084±28	2 142±13	3	0.133 33	0.73	7.020	1.7	0.381 6	1.6	0.905
19.2R	0.02	541	18	0.03	147.0	1 776±22	1 897±8.1	6	0.116 10	0.45	5.076	1.5	0.317 1	1.4	0.953
细粒电气石岩(N14)
1.1	0.01	397	295	0.77	138.0	2 190±27	2 183±8.1	0	0.136 50	0.46	7.61	1.5	0.404 5	1.4	0.952
2.1	--	387	217	0.58	135.0	2 194±27	2 142±8.5	-2	0.133 32	0.48	7.45	1.5	0.405 3	1.4	0.947
3.1	0.04	132	81	0.64	45.6	2 175±31	2 182±13	0	0.136 38	0.73	7.55	1.8	0.401 4	1.7	0.916
4.1	0.01	314	176	0.58	110.0	2 198±27	2 167±8.2	-1	0.135 24	0.47	7.58	1.5	0.406 4	1.4	0.950
5.1	0.09	257	174	0.70	83.0	2 054±27	2 153±10	5	0.134 12	0.58	6.94	1.7	0.375 3	1.6	0.937
6.1	0.01	133	65	0.51	45.2	2 147±28	2 166±13	1	0.135 14	0.73	7.36	1.7	0.395 2	1.5	0.901
中细粒电气石岩(N02)
1.1C	0.08	200	81	0.42	65.7	2 081±26	2 166±11	4	0.135 14	0.62	7.10	1.6	0.381 0	1.5	0.921
2.1C	0.13	151	71	0.49	48.7	2 058±26	2 137±12	4	0.132 93	0.69	6.89	1.6	0.376 0	1.5	0.906
3.1C	0.04	354	199	0.58	124.0	2 204±27	2 168±7.5	-2	0.135 32	0.43	7.61	1.5	0.407 6	1.4	0.957
3.2R	0.03	1 002	70	0.07	265.0	1 732±23	1 855±13	7	0.113 44	0.70	4.821	1.7	0.308 2	1.5	0.909
4.1C	0.02	2 211	683	0.32	755.0	2 158±26	2 162±3.2	0	0.134 89	0.18	7.39	1.4	0.397 5	1.4	0.992
5.1C	0.01	533	306	0.59	185.0	2 189±26	2 177±6.1	-1	0.136 05	0.35	7.59	1.4	0.404 4	1.4	0.970
6.1C	0.00	166	77	0.48	55.7	2 121±27	2 123±12	0	0.131 87	0.66	7.08	1.6	0.389 6	1.5	0.914
7.1C	0.04	407	108	0.27	115.0	1 838±23	1 970±8.9	7	0.120 95	0.50	5.503	1.5	0.330 0	1.4	0.944
6.2R	0.08	667	76	0.12	189.0	1 834±22	1 888±7.2	3	0.115 54	0.40	5.242	1.5	0.329 0	1.4	0.961
7.2R	0.01	1 191	61	0.05	349.0	1 891±28	1 846±13	-2	0.112 84	0.73	5.303	1.9	0.340 9	1.7	0.921
8.1C	0.09	166	74	0.46	56.7	2 158±35	2 184±12	1	0.136 53	0.68	7.49	2.0	0.397 7	1.9	0.940
9.1C	0.01	4 028	1 543	0.40	1 280.0	2 035±29	2 112±2.3	4	0.131 10	0.13	6.71	1.7	0.371 1	1.7	0.997
10.1C	0.01	335	242	0.75	120.0	2 249±27	2 181±7.6	-3	0.136 38	0.44	7.85	1.5	0.417 5	1.4	0.956
11.1C	0.02	359	159	0.46	112.0	1 997±26	2 077±8.1	4	0.128 50	0.46	6.43	1.6	0.363 0	1.5	0.956
12.1C	0.02	514	366	0.74	178.0	2 181±27	2 165±6.3	-1	0.135 11	0.36	7.50	1.5	0.402 5	1.5	0.971
13.1C	0.06	268	136	0.52	86.2	2 049±26	2 062±9.6	1	0.127 37	0.54	6.57	1.6	0.374 2	1.5	0.937
14.1C	0.01	911	926	1.05	329.0	2 261±27	2 185±4.7	-3	0.136 67	0.27	7.92	1.5	0.420 1	1.4	0.982
15.1C	0.07	369	197	0.55	127.0	2 178±27	2 172±7.7	0	0.135 67	0.44	7.52	1.5	0.402 0	1.5	0.958
16.1C	0.02	418	203	0.50	126.0	1 942±26	2 157±10	10	0.134 43	0.59	6.51	1.6	0.351 5	1.5	0.933
17.1C	0.08	249	136	0.56	84.3	2 142±30	2 177±9.5	2	0.136 06	0.55	7.39	1.7	0.394 1	1.7	0.950
18.1C	0.02	744	374	0.52	253.0	2 153±26	2 171±5.4	1	0.135 54	0.31	7.41	1.4	0.396 5	1.4	0.976
19.1C	0.12	221	77	0.36	60.8	1 791±23	2 049±12	13	0.126 44	0.68	5.583	1.6	0.320 2	1.5	0.905
19.2R	0.01	525	31	0.06	159.0	1 945±24	1 901±7.8	-2	0.116 36	0.43	5.649	1.5	0.352 1	1.4	0.956
20.1C	0.07	200	93	0.48	62.0	1 986±25	2 098±11	5	0.129 97	0.62	6.47	1.6	0.360 8	1.5	0.920
20.2R	0.08	796	297	0.39	179.0	1 500±21	1 889±7.6	21	0.115 63	0.42	4.175	1.6	0.261 9	1.6	0.966
21.1C	0.03	215	118	0.57	68.2	2 028±29	2 188±11	7	0.136 86	0.62	6.98	1.8	0.369 8	1.7	0.937
注：Pb^*代表放射性成因铅，对样品N13和N02；C和R分别代表锆石的核部和边部.

下载: 导出CSV

参考文献(105)

[1]	Anthi, L., Dieter, G., 1999. Constraining the prograde and retrograde P-T-t path of Eocene HP rocks by SHRIMP dating of different zircon domains: inferred rated of heating, burial, cooling and exhumation for central Rhodope, northern Greece. Contributions to Mineralogy Petrology, 135(4): 340-354. doi: 10.1007/s004100050516
[2]	Compston, W., Williams, I.S., Mayer, C., 1984. U-Pb geochronology of zircons from Lunar Breccia 73217 using a sensitive high mass-resolution ion microprobe. Proceedings of XIV Lunar and Planetary Science Conference, Part 2 Journal of Geophysical Research, 89(Suppl. ): B525-B534. doi: 0148-0227/84/003B-5045
[3]	Condie, K.C., 2002. Breakup of a Paleoproterozoic supercontinent. Gondwana Research, 5(1): 41-43. doi: 10.1016/S1342-937X(05)70886-8
[4]	Faure, M.W., Lin, W., Monie, P., et al., 2004. Palaeoproterozoic arc magmatism and collision in Liaodong Peninsula (North-East China). Terra Nova, 16(2): 75-80. doi: 10.1111/j.1365-3121.2004.00533.x
[5]	Geng, Y.S., Wan, Y.S., Shen, Q.H., et al., 2000. Chronological framework of the Early Precambrian important events in the Luliang area, Shanxi Province. Acta Geologica Sinica, 74(3): 216-223 (in Chinese with English abstract). http://www.researchgate.net/publication/279587613_Chronological_framework_of_the_early_Precambrian_important_events_in_the_Luliang_area_Shanxi_Province
[6]	Geng, Y.S., Wan, Y.S., Yang, C.H., 2003. The Palaoproterozoic rift-type volcanism in Luliangshan area, Shanxi Province, and its geological significance. Acta Geoscientia Sinica, 24(2): 97-104 (in Chinese with English abstract). http://www.researchgate.net/publication/313191882_The_Paleoproterozoic_rift-type_volcanism_in_Luliangshan_area_Shanxi_Province_and_its_geological_significance
[7]	Gerhard, V., Rolf, S., Dieter, G., 1999. Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea zone (southern Alps). Conributions to Mineralogy Petrology, 134(4): 380-404. doi: 10.1007/s004100050492
[8]	Guan, H., Sun, M., Wilde, S.A., et al., 2002. SHRIMP U-Pb zircon geochronology of the Fuping complex: implications for formation and assembly of the North China craton. Precambrian Research, 113(1-2): 1-18. doi: 10.1016/S0301-9268(01)00197-8
[9]	Guan, H., Sun, M., Xu, P., 1998. Geochronological study of zircons from high grade gneisses of Fuping complex by LP ICPMS technique. Acta Petrologica Sinica, 14(4): 460-470 (in Chinese with English abstract).
[10]	Hao, D.F., Li, S.Z., Zhao, G.C., et al., 2004. Origin and its constraint to tectonic evolution of Paleoproterozoic granitoids in the eastern Liaoning and Jilin Province, North China. Acta Petrologica Sinica, 20(6): 1409-1416 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-YSXB200406009.htm
[11]	Hoskin, P.W.O., Black, L.P., 2000. Metamorphic zircon formation by solid-state recrystallization of protolith igneous zircon. Journal of Metamorphic Geology, 18(4): 423-439. doi: 10.1046/j.1525-1314.2000.00266.x
[12]	Hu, S.X., 1988. Geology and metallogeny of the collision belts between the southern and the northern China plate. Nanjing University Press, Nanjing, 1-558 (in Chinese).
[13]	Huang, Z.L., Mo, M., Zu, E.D., 1996. Mineralogical features and genetic significance of tourmalines from boron deposits in eastern Liaoning. Acta Petrologica et Mineralogica, 15(4): 365-378 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-YSKW604.009.htm
[14]	Jiang, C.C., 1987. Precambrian geology of eastern part of Liaoning and Jilin. Liaoning Science and Technology Publishing House, Shenyang, 184-229 (in Chinese).
[15]	Jiang, S.Y., Palmer, M.R., Peng, Q.M., et al., 1997. Chemical and stable isotopic compositions of Proterozoic metamorphosed evaporites and associated tourmalines from the Houxianyu borate deposit, eastern Liaoning, China. Chemical Geology, 135(3-4): 189-211. doi: 10.1016/S0009-2541(96)00115-5
[16]	Li, J.H., Hou, G.T., Huang, X.N., et al., 2001. The constraint for the supercontinental cycles: evidence from Precambrian geology of North China block. Acta Petrologica Sinica, 17(2): 177-186 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-YSXB200102000.htm
[17]	Li, S.Z., Zhao, G.C., 2007. SHRIMP U-Pb zircon geochronology of the Liaoji granitoids: constraints on the evolution of the Paleoproterozoic Jiao-Liao-Ji belt in the eastern block of the North China craton. Precambrian Research, 158(1-2): 1-16. doi: 10.1016/j.precamres.2007.04.001
[18]	Li, X.M., 2009. Metallogenesis and mineral prospecting assessment of borate deposits in eastern Liaoning-southern Jilin borate ore belt, Northeast China (Dissertation). Jilin University, Jilin, 1-158 (in Chinese with English abstract).
[19]	Li, X.M., Sun, F.Y., Li, B.L., et al., 2008. Geochemistry and origin of tourmalite from boron-bearing rock series of Houxianyu borate deposit in eastern Liaoning. Global. Geology, 27(3): 260-266 (in Chinese with English abstract). http://epub.cnki.net/grid2008/docdown/docdownload.aspx?filename=SJDZ200803004&dbcode=CJFD&year=2008&dflag=pdfdown
[20]	Liu, J.D., Xiao, R.G., Wang, W.W., et al., 2007. Regional metallogenesis of borate deposit in eastern Liaoning, China. Geological Publishing House, Beijing, 122-138 (in Chinese).
[21]	Lu, S.N., Yang, C.L., Li, H.K., et al., 2002. North China continent and Columbia supercontinent. Earth Science Frontiers, 9(4): 225-233 (in Chinese with English abstract).
[22]	Lu, X.P., Wu, F.Y., Lin, J.Q., et al., 2004a. Geochronological successions of the Early Precambrian granitic magmatism in southern Liaodong peninsula and its constraints on tectonic evolution of the North China craton. Chinese Journal of Geology, 39(1): 123-138 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZKX200401013.htm
[23]	Lu, X.P., Wu, F, Y., Zhang, Y.B., et al., 2004b. Emplacement age and tectonic setting of the Paleoproterozoic Liaoji granites in Tonghua area, southern Jilin Province. Acta Petrologica Sinica, 20(3): 381-392 (in Chinese with English abstract).
[24]	Lu, Y.F., Cheng, Y.C., Li, H, Q., et al., 2005. Metallogenic chronology of boron deposits in the eastern Liaoning Paleoproterozoic rift zone. Acta Geologica Sinica, 79(3): 414-425. doi: 10.1111/j.1755-6724.2005.tb00907.x
[25]	Ludwig, K.R., 2001. SQUID 1.02: a user's manual. Berkeley Geochronology Center Special Publication. No. 2: 19.
[26]	Ludwig, K.R., 2003. User's Manual for Isoplot/Ex rev. 3.00: a geochronological toolkit for Microsoft Excel. Berkeley Geochronology Center, Special Publication No. 4: 70.
[27]	Luo, Y., Sun, M., Zhao, G.C., et al., 2004. LA-ICP-MS U-Pb zircon ages of the Liaohe Group in the eastern block of the North China craton: constraints on the evolution of the Jiao-Liao-Ji belt. Precambrian Research, 134(3-4): 349-371. doi: 10.1016/j.precamres.2004.07.002
[28]	Nasdala, L., Hofmeister, W., Norberg, N., et al., 2008. Zircon M257—a homogeneous natural reference material for the ion microprobe U-Pb analysis of zircon. Geostandards and Geoanalytical Research, 32(3): 247-265. doi: 10.1111/j.1751-908X.2008.00914.x
[29]	Paterson, B.A., Stephens, W.E., Rogers, G., et al., 1992. The nature of zircon inheritance in two granite plutons. Transactions of the Royal Society of Edinburgh (Earth Sciences), 83(1-2): 459-471. doi: 167.35400003009017.0420
[30]	Peng, Q.M., Xu, H., 1994. The Paleoproterozoic metaevaporitic and boron deposits in eastern Liaoning and southern Jilin. Northeast Normal University Press, Changchun, 1-120 (in Chinese).
[31]	Pidgeon, R.T., Nemchin, A.A., Hitchen, G.J., 1998. Internal structures of zircons from Archaean granites from the Darling Range batholith: implications for zircon stability and the interpretation of zircon U-Pb ages. Contributions to Mineralogy and Petrology, 132(3): 288-299. doi: 10.1007/s004100050422
[32]	Rogers, J.J.W., Santosh, M., 2002. Configuration of Columbia, a Mesoproterozoic supercontinent. Gondwana Research, 5(1): 5-22. doi: 10.1016/S1342-937X(05)70883-2
[33]	Shaw, D.M., 1972. The origin of the Apsley gneiss, Ontario. Canadian Journal of Earth Science, 9(1): 18-35. doi: 10.1139/e72-002
[34]	Shen, Q.H., Xu, H.F., Zhang, Z.Q., et al., 1992. Granulites of Early Precambrian in China. Geological Publishing House, Beijing, 389-400 (in Chinese).
[35]	Simonen, A., 1953. Stratigraphy and sedimentation of the Svecofennidic, Early Archean supracrustal rocks in southwestern Finland. Bull. Comm. Geol. Finland, 160: 1-64. http://www.researchgate.net/publication/284053923_Stratigraphy_and_sedimentation_of_the_Svecofennidic_early_Archean_supracrustal_rocks_in_southwestern_Finland
[36]	Song, B., Zhang, Y.H., Wan, Y.S., et al., 2002. Mount making and procedure of the SHRIMP dating. Geological Review, 48(Suppl. ): 26-30 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZLP2002S1006.htm
[37]	Sun, D.Z., Hu, W.X., 1993. The tectonic framework of Precambrian in Zhongtiao Mountains. Geological Publishing House, Beijing, 165-167 (in Chinese).
[38]	Sun, J.Y., Ji, S.K., Zhen, Y.Q., 1995. The copper ores in the Zhongtiao rift zone. Geological Publishing House, Beijing, 1-190 (in Chinese).
[39]	Sun, M., Armstrong, R.L., Lambert, R.S.J., et al., 1993. Petrochemistry and Sr, Pb and Nd isotopic geochemistry of the Paleoproterozoic Kuandian complex, the eastern Liaoning Province, China. Precambrian Research, 62(1-2): 171-190. doi: 10.1016/0301-9268(93)90099-N
[40]	Sun, M., Zhang, L.F., Wu, J.H., 1996. The origin of the Early Proterozoic Kuandian complex: evidence from geochemistry. Acta Geologica Sinica, 70(3): 207-222 (in Chinese with English abstract). doi: 10.1111/j.1755-6724.1997.tb00342.x/abstract
[41]	Wan, Y.S., Liu, D.Y., Jian, P., 2004. Comparison of SHRIMP U-Pb dating of monazite and zircon. Chinese Science Bulletin, 49(14): 1501-1506. doi: 10.1360/03wd0638
[42]	Wan, Y.S., Zhang, D.Q., Song, T.R., 2003. Detrital zircon SHRIMP dating for the Changzhougou Formation in the Changcheng System in Shisanling, Beijing: constrain to material source of cover of the North China craton and sedimentation time. Chinese Science Bulletin, 48(18): 1970-1975 (in Chinese). doi: 10.1360/csb2003-48-18-1970
[43]	Wang, C.Z., Xiao, R.G., Liu, J.D., et al., 2006. Ore-control role of ultra-magnesium peridotite in Houxianyu boron ore district, Yingkou, Liaoning Province. Mineral Deposits, 25(6): 683-692 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-KCDZ200606004.htm
[44]	Wang, C.Z., Xiao, R.G., Liu, J.D., 2008a. Ore-forming genesis and model of eastern Liaoning borate deposits. Earth Science—Journal of China University of Geosciences, 33(6): 813-824 (in Chinese with English abstract). doi: 10.3799/dqkx.2008.098
[45]	Wang, C.Z., Xiao, R.G., Liu, J.D., 2008b. Geological and geochemical characteristics and formation environment of the Wenquangou olivine basalt in Liaoning Province. Acta Geoscientica Sinica, 29(5): 542-552 (in Chinese with English abstract).
[46]	Wang, J.Y., Xi, N.C., 1982. The evaluation on the K-Ar ages of Northeast China. The Science and Technology Information of Northeast China, 2: 22-40 (in Chinese).
[47]	Williams, I.S., 1998. U-Th-Pb geochronology by ion microprobe. In: Mc Kibben, M.A., Shanks, W.C., Ridley, W.I., eds., Applications of microanalytical techniques to understanding mineralizing process. Reviews in Economic Geology, 7: 1-35.
[48]	Wu, J.S., Liu, D.Y., Jin, L.G., 1986. The zircon U-Pb age of metamorphosed basic volcanic lavas from the Hutuo Group in the Wutai Mountain area, Shanxi Province. Geological Review, 32(2): 178-184 (in Chinese with English abstract). http://www.researchgate.net/publication/313695638_The_zircon_U-Pb_age_of_metamorphosed_basic_volcanic_lavas_from_the_Hutuo_Group_in_the_Wutai_Mt_area_Shanxi_Province
[49]	Wu, Y.B., Zheng, Y.F., 2004. Genesis of zircon and its constrains on interpretation of U-Pb age. Chinese Science Bulletin, 49(15): 1554-1569. doi: 10.1007/BF03184122
[50]	Xiao, R.G., Takao, O., Fei, H.C., et al., 2003. Sedimentary-metamorphic boron deposits and their boron isotopic compositions in eastern Liaoning Province. Geoscience, 17(2): 137-142 (in Chinese with English abstract). http://www.zhangqiaokeyan.com/academic-journal-cn_geoscience_thesis/0201254379380.html
[51]	Xu, H., Peng, Q.M., Palmer, M.R., 2004. Origin of tourmaline-rich rocks in a Paleoproterozoic terrene (N.E. China): evidence for evaporite-derived boron. Geology in China, 31(3): 240-253. http://www.researchgate.net/publication/285717759_Origin_of_tourmaline-rich_rocks_in_a_Paleoproterozoie_terreneN_E_China_Evidence_for_evaporatederived_boron
[52]	Xue, J.L., Xu, H., Gao, Y.M., et al., 2006. Mineralogical characteristics of tourmaline in the Houxianyu boron deposit in Liaoning and their significance for rock and ore formation. Geology in China, 33(6): 1386-1392 (in Chinese with English abstract). http://www.researchgate.net/publication/289701779_Mineralogical_characteristics_of_tourmaline_in_the_Houxianyu_boron_deposit_in_Liaoning_and_their_significance_for_rock_and_ore_formation
[53]	Yin, A., Nie, S.Y., 1996. A Phanerozoic palinspastic reconstruction of China and its neighboring regions. In: Yin, A., Harrison, T.M., eds., The tectonic evolution of Asia. Cambridge University Press, New York, 285-442.
[54]	Zhai, M.G., 2004.2.1~1.7 Ga geological event group and its geotectonic significance. Acta Petrologica Sinica, 20(6): 1343-1354 (in Chinese with English abstract).
[55]	Zhai, M.G., 2010. Tectonic evolution and metallogenesis of North China Craton. Mineral Deposits, 29(1): 24-36 (in Chinese with English abstract). http://www.cqvip.com/QK/93610X/201001/33117123.html
[56]	Zhai, M.G., Liu, W.J., 2003. Paleoproterozoic tectonic history of the North China craton: a review. Precambrian Research, 122(1-4): 183-199. doi: 10.1016/S0301-9268(02)00211-5
[57]	Zhai, M.G., Peng, P., 2007. Paleoproterozoic events in the North China craton. Acta Pretrologica Scinica, 23(11): 2665-2682 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-YSXB200711002.htm
[58]	Zhang, C., Hou, G.T., Qian, X.L., 1994. Magnetic fabric evidence of the style of emplacement of Late Precambrian mafic dyke swarms in the Luliang-northern Shanxi region, North China. Geological Review, 40(3): 245-251 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZLP199403007.htm
[59]	Zhang, Q.S., 1988. Early crust and mineral deposits of Liaodong Peninsula. Geological Publishing House, Beijing, 218-450 (in Chinese).
[60]	Zhang, Y.F., Liu, J.D., Fu, Y.C., et al., 2009. Study on the genesis and geological and geochemical characteristics of layered migmatites in East Liaoning, China. Geology and Exploration, 45(5): 549-557 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZKT200905009.htm
[61]	Zhao, G.C., Cawood, P.A., Wilde, S.A., et al., 2002. Review of global 2.1-1.8 Ga orogens: implications for a pre-Rodinia supercontinent. Earth-Science Reviews, 59(1-4): 125-162. doi: 10.1016/s0012-8252(02)00073-9
[62]	Zhao, G.C., Sun, M., Wilde, S.A., et al., 2004. A paleo-Mesoproterozoic supercontinent: assembly, growth and breakup. Earth-Science Reviews, 67(1-2): 91-123. doi: 10.1016/j.earscirev.2004.02.003
[63]	Zhao, G.C., Sun, M., Wide, S.A. et al., 2005. Late Archean to Paleoproterozoic evolution of the North China Craton: key issues revisited. Precambrian Research, 136(2): 177-202. doi: 10.1016/j.precamres.2004.10.002
[64]	Zhao, Z.P., Zhai, M.G., Wang, K.Y., et al., 1993. Precambrian crustal evolution of the Sino-Korean paraplatform. Science Press, Beijing, 389-390 (in Chinese).
[65]	Zou, R., Feng, B.Z., 1993. Geology and origin of the tourmalites in the Early Proterozoic boron-bearing sequence in Liaoning-Jilin. Journal of Changchun University of Earth Sciences, 23(4): 373-379 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-CCDZ199304002.htm
[66]	Zou, R., Feng, B.Z., 1995. The features of ore-hosting volcanic-hydrothermal sedimentary series in Houxianyu boron deposits, Yingkou, Liaoning. Geochimica, 24: 46-54 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DQHX5S1.005.htm
[67]	耿元生, 万渝生, 沈其韩, 等, 2000. 吕梁地区的早前寒武纪主要地质事件的年代框架. 地质学报, 74(3): 216-223. doi: 10.3321/j.issn:0001-5717.2000.03.003
[68]	耿元生, 万渝生, 杨崇辉, 2003. 吕梁地区古元古代的裂陷型火山作用及其地质意义. 地球学报, 24(2): 97-104. doi: 10.3321/j.issn:1006-3021.2003.02.001
[69]	关鸿, 孙敏, 徐平, 1998. 阜平杂岩中几种不同类型片麻岩的锆石激光探针等离子体质谱年代学研究. 岩石学报, 14(4): 460-470. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB804.004.htm
[70]	郝德峰, 李三忠, 赵国春, 等, 2004. 辽吉地区古元古代花岗岩成因及其对构造演化的制约. 岩石学报, 20(6): 1409-1416. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200406009.htm
[71]	胡受奚, 1988. 华北与华南古板块拼合带地质和成矿——以东秦岭-桐柏为例. 南京: 南京大学出版社, 1-558.
[72]	黄作良, 莫珉, 祖恩东, 1996. 辽东硼矿床中电气石的矿物学特征及成因意义. 岩石矿物学杂志, 15(4): 365-378. https://www.cnki.com.cn/Article/CJFDTOTAL-YSKW604.009.htm
[73]	姜春潮, 1987. 辽吉东部前寒武纪地质. 沈阳: 辽宁科学技术出版社, 184-229.
[74]	李江海, 侯贵廷, 黄雄南, 等, 2001. 华北克拉通对前寒武纪超大陆旋回的基本制约. 岩石学报, 17(2): 177-186. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200102000.htm
[75]	李雪梅, 2009. 辽东-吉南硼矿带硼矿成矿作用及成矿远景评价(博士论文). 长春: 吉林大学, 1-158.
[76]	李雪梅, 孙丰月, 李碧乐, 等, 2008. 辽东后仙峪硼矿床含硼岩系中电英岩的地球化学特征及其成因. 世界地质, 27(3): 260-266. doi: 10.3969/j.issn.1004-5589.2008.03.004
[77]	刘敬党, 肖荣阁, 王文武, 等, 2007. 辽东硼矿区域成矿模型. 北京: 地质出版社, 122-138.
[78]	陆松年, 杨春亮, 李怀坤, 等, 2002. 华北古大陆与哥伦比亚超大陆. 地学前缘, 9(4): 225-233. doi: 10.3321/j.issn:1005-2321.2002.04.002
[79]	路孝平, 吴福元, 林景仟, 等, 2004a. 辽东半岛南部早前寒武纪花岗质岩浆作用的年代学格架. 地质科学, 39(1): 123-138. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKX200401013.htm
[80]	路孝平, 吴福元, 张艳斌, 等, 2004b. 吉林南部通化地区古元古代辽吉花岗岩的侵位年代与形成构造背景. 岩石学报, 20(3): 381-392. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200403002.htm
[81]	彭齐鸣, 许虹, 1994. 辽东-吉南地区早元古宙变质蒸发岩系及硼矿床. 长春: 东北师范大学出版社, 1-120.
[82]	沈其韩, 许慧芬, 张宗清, 等, 1992. 中国早前寒武纪麻粒岩. 北京: 地质出版社, 389-400.
[83]	宋彪, 张玉海, 万渝生, 等, 2002. 锆石SHRIMP样品靶制作, 年龄测定及有关现象讨论. 地质论评, 48(增刊): 26-30. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP2002S1006.htm
[84]	孙大中, 胡维兴, 1993. 中条山前寒武纪年代构造格架和年代地壳结构. 北京: 地质出版社, 165-167.
[85]	孙继源, 冀树楷, 真允庆, 1995. 中条裂谷铜矿床. 北京: 地质出版社, 1-190. https://www.cnki.com.cn/Article/CJFDTOTAL-GLGX901.001.htm
[86]	孙敏, 张立飞, 吴家弘, 1996. 早元古代宽甸杂岩的成因: 地球化学证据. 地质学报, 70(3): 207-222. doi: 10.3321/j.issn:0001-5717.1996.03.001
[87]	万渝生, 刘敦一, 简平, 2004. 独居石和锆石SHRIMP U-Pb定年对比. 科学通报, 49(12): 1185-1190. doi: 10.3321/j.issn:0023-074X.2004.12.013
[88]	万渝生, 张巧大, 宋天锐, 2003. 北京十三陵长城系常州沟组碎屑锆石SHRIMP年龄: 华北克拉通盖层物源区及最大沉积年龄的限定. 科学通报, 48(18): 1970-1975. doi: 10.3321/j.issn:0023-074X.2003.18.014
[89]	王翠芝, 肖荣阁, 刘敬党, 等, 2006. 辽宁营口后仙峪硼矿区超镁橄榄岩的控矿作用. 矿床地质, 25(6): 683-692. doi: 10.3969/j.issn.0258-7106.2006.06.005
[90]	王翠芝, 肖荣阁, 刘敬党, 2008a. 辽东硼矿的成矿机制及成矿模式. 地球科学——中国地质大学学报, 33(6): 813-824. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200806010.htm
[91]	王翠芝, 肖荣阁, 刘敬党, 2008b. 辽宁翁泉沟橄榄玄武岩的地质地球化学特征及其形成环境. 地球学报, 29(5): 542-552. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200805003.htm
[92]	王集源, 习乃昌, 1982. 东北地区钾氩法年龄数据评述. 东北地质科技情报, 2: 22-40.
[93]	伍家善, 刘敦一, 金龙国, 1986. 五台山区滹沱群变质基性熔岩中锆石U-Pb年龄. 地质论评, 32(2): 178-184. doi: 10.3321/j.issn:0371-5736.1986.02.011
[94]	吴元保, 郑永飞, 2004. 锆石成因矿物学研究及其对U-Pb年龄解释的制约. 科学通报, 49(16): 1589-1604. doi: 10.3321/j.issn:0023-074X.2004.16.002
[95]	肖荣阁, 大井隆夫, 费红彩, 等, 2003. 辽东地区沉积变质硼矿床及硼同位素研究. 现代地质, 17(2): 137-142. https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ200302003.htm
[96]	薛建玲, 许虹, 高一鸣, 等, 2006. 辽宁后仙峪硼矿床中电气石的矿物学特征及其成岩成矿意义. 中国地质, 33(6): 1386-1392. doi: 10.3969/j.issn.1000-3657.2006.06.023
[97]	翟明国, 2004. 华北克拉通2.1~1.7 Ga地质事件群的分解和构造意义探讨. 岩石学报, 20(6): 1343-1354. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200406003.htm
[98]	翟明国, 2010. 华北克拉通的形成演化与成矿作用. 矿床地质, 29(1): 24-36. doi: 10.3969/j.issn.0258-7106.2010.01.004
[99]	翟明国, 彭澎, 2007. 华北克拉通古元古代构造事件. 岩石学报, 23(11): 2665-2682. doi: 10.3969/j.issn.1000-0569.2007.11.001
[100]	张臣, 侯贵廷, 钱祥麟, 1994. 吕梁-晋北地区晚前寒武纪镁铁质岩墙群侵位方式的磁组构证据. 地质论评, 40(3): 245-251. doi: 10.3321/j.issn:0371-5736.1994.03.008
[101]	张秋生, 1988. 辽东半岛早期地壳与矿床. 北京: 地质出版社, 218-450.
[102]	张艳飞, 刘敬党, 付艳春, 等, 2009. 辽东硼矿区层状混合岩的地质地球化学特征及其成因探讨. 地质与勘探, 45(5): 549-557. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKT200905009.htm
[103]	赵宗溥, 等, 1993. 中朝准地台前寒武纪地壳演化. 北京: 科学出版社, 389-390.
[104]	邹日, 冯本智, 1993. 辽吉地区早元古代含硼建造中电英岩的特征及成因. 长春地质学院学报, 23(4): 373-379. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ199304002.htm
[105]	邹日, 冯本智, 1995. 营口后仙峪硼矿容矿火山-热水沉积岩系特征. 地球化学, 24: 46-54. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX5S1.005.htm